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Modification of Nanosilica Surfaces by Methyl Methacrylate Oligomers

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Book cover Nanoscience Advances in CBRN Agents Detection, Information and Energy Security

Abstract

Composites based on silica and methyl metacrylate silane coupling agents are promising materials for sensor technologies. The present study deals with a new method of covering silica nanoparticles by methyl methacrylate oligomers in the pseudo-liquid state. The adsorption process of metacrylate-containing oligomers on the surface of nanosized silica was studied by means of IR-spectroscopy and thermal analysis. The study confirmed the full modification of the silica surface with oligomers. The composites obtained in this study exhibited a greatly reduced degree of shrinkage and better mechanical and physical properties. The composites explored here will serve as an important contribution to the current ongoing research efforts in designing materials in the nano-scale capable of sensing and detecting metal ions in solutions with high selectivity.

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Correspondence to Igor Telegeev .

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© 2015 Springer Science+Business Media Dordrecht

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Telegeev, I., Voronin, E., Pakhlov, E., Kalibabchuk, V. (2015). Modification of Nanosilica Surfaces by Methyl Methacrylate Oligomers. In: Petkov, P., Tsiulyanu, D., Kulisch, W., Popov, C. (eds) Nanoscience Advances in CBRN Agents Detection, Information and Energy Security. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9697-2_19

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