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Molecular Mechanics of Polymer Nanocomposites

Enhancement of Macroscopic Properties

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Trends in Nanoscale Mechanics

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Abstract

Polymer nanocomposites have been a central theme in nanotechnology over the last decade. This activity was determined primarily by expectations generated by early experiments showing significant property enhancement associated with the addition of a small fraction of nano-fillers in thermoplastics. A large number of experimental, numerical and theoretical investigations of the physical basis of these enhancements followed. Today it is generally accepted that, while the fillers do not modify chemically the matrix material, the mechanical properties of the polymer are nevertheless altered. This chapter reviews some of the numerical and experimental works aimed at developing this basic understanding. We focus on modifications of the chain structure and relaxation time in the vicinity of impenetrable fillers, the residence time of polymeric chains on filler surfaces in melts, and the formation of a network of chains connecting fillers. This molecular-scale physics has been incorporated in rheological models aimed at predicting the macroscopic response of the composite. One such model is presented here. Despite not reviewing the entire, large literature produced to date on this subject, the discussion provides insight into the essential physics of these systems, and a starting point for future investigations.

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References

  1. A.M. Bueche, J. Poly. Sci. 25, 139 (1957)

    Article  Google Scholar 

  2. M. Sumita, T. Shizuma, K. Miyasaka, K. Shikawa, J. Sci. Macromolec. B22, 601 (1983)

    Article  Google Scholar 

  3. B. Kuriakose, S.K. De, S.S. Bhagawan, R. Sivaramkrishnan, S.K. Athithan, J. Appl. Poly. Sci. 32, 5509 (1986)

    Article  Google Scholar 

  4. P.M. Ajayan, L.S. Schadler, P.V. Braun (eds.), Nanocomposites Science and Technology (Wiley, New York, 2003)

    Google Scholar 

  5. E. Manias, Nat. Mater. 6, 9 (2007)

    Article  Google Scholar 

  6. P.B. Messersmith, E.P. Giannelis, Chem. Matls. 6, 1719 (1994)

    Article  Google Scholar 

  7. K.W. Putz, C. Mitchell, R. Krishnamoorti, P.F. Green, J. Sci. Poly. B42, 2286 (2004)

    Article  Google Scholar 

  8. B.J. Ash, R.W. Siegel, L.S. Schadler, Macromolecules 37, 1358 (2004)

    Article  Google Scholar 

  9. D. Hull and T.W. Clyne, An Introduction to Composite Materials (Cambridge University Press, Cambridge, 1996)

    Google Scholar 

  10. W. Zhang, R.C. Picu, N. Koratkar, Appl. Phys. Lett. 91, 193109 (2007)

    Article  Google Scholar 

  11. J.C. Radon, Int. J. Fract. 16, 553 (1980)

    Article  Google Scholar 

  12. M.D. Skibo, R.W. Hertzberg, J.A. Manson, S.L. Kim, J. Mater. Sci. 12, 531 (1977)

    Article  Google Scholar 

  13. L. Becu, A. Maazouz, H. Sautereau, J.F. Gerard, J. Appl. Polym. Sci. 65, 2419 (1997)

    Article  Google Scholar 

  14. L. Rey, N. Poisson, A. Maazouz, H. Sautereau, J. Mater. Sci. 34, 1775 (1999)

    Article  Google Scholar 

  15. H.R. Azimi, R.A. Pearson, R.W. Hertzberg, Polym. Eng. Sci. 36, 2352 (1996)

    Article  Google Scholar 

  16. B.B. Johnsen, A.J. Kinlock, R.D. Mohammed, A.C. Taylor, S. Sprenger, Polymer 48, 530 (2007)

    Article  Google Scholar 

  17. A.J. Kinlock, R.D. Mohammed, A.C. Taylor, C. Eger, S. Sprenger, D. Egan, J. Mater. Sci. 40, 5083 (2005)

    Article  Google Scholar 

  18. B. Wetzel, P. Rosso, F. Haupert, K. Friedrich, Eng. Fract. Mech. 73, 2375 (2006)

    Article  Google Scholar 

  19. W. Zhang, I. Srivastava, Y.-F. Zhu, R.C. Picu, N. Koratkar, Small 5, 1403 (2009)

    Article  Google Scholar 

  20. W. Zhang, R.C. Picu, N. Koratkar, Nanotechnology 19, 285709 (2008)

    Article  Google Scholar 

  21. N. Koratkar, J. Suhr, A. Joshi, R. Kane, L.S. Schadler, P.M. Ajayan, S. Bartolucci, Appl. Phys. Lett. 87, 063102 (2005)

    Article  Google Scholar 

  22. F. Erdogan, P.F. Joseph, J. Am. Ceram. Soc. 72, 262 (1989)

    Article  Google Scholar 

  23. A.K. Geim, K.S. Novoselov, Nat. Mater. 6, 183–191 (2007)

    Article  Google Scholar 

  24. C.O. Compton, S.T. Nguyen, Small 6, 711 (2010)

    Article  Google Scholar 

  25. M.J. McAllister, Chem. Mater. 19, 4396 (2007)

    Article  Google Scholar 

  26. A. Zandiatashbar, R.C. Picu and N. Koratkar, Small, DOI: 10.1002/smll.201102686 (2012) in press

  27. H.C. Schniepp, J.-L. Li, M.J. McAllister, H. Sai, M. Herrera-Alonso, D.H. Adamson, R.K. Prud’homme, R. Car, D.A. Saville, I.A. Aksay, J. Chem. Phys. B110, 8535 (2006)

    Article  Google Scholar 

  28. M.A. Rafiee, J. Rafiee, I. Srivastava, Z. Wang, H. Song, Z.-Z. Yu, N. Koratkar, Small 6, 179 (2010)

    Article  Google Scholar 

  29. K. Kremer, G. Grest, J. Chem. Phys. 92, 5057 (1990)

    Article  Google Scholar 

  30. R.C. Picu, M.C. Pavel, Macromolecules 36, 9205 (2003)

    Article  Google Scholar 

  31. F.W. Starr, T.B. Schroder, S.C. Glotzer, Macromolecules 35, 4481 (2002)

    Article  Google Scholar 

  32. M. Vacatello, Macromolecules 34, 1946 (2001)

    Article  Google Scholar 

  33. M. Goswami, B.G. Sumpter, J. Chem. Phys. 130, 134910 (2009)

    Article  Google Scholar 

  34. F.W. Starr, J.F. Douglas, S.C. Glotzer, J. Chem. Phys. 119, 1777 (2003)

    Article  Google Scholar 

  35. P.J. Dionne, R.C. Picu, R. Ozisik, Macromolecules 38, 9351 (2005)

    Article  Google Scholar 

  36. R.F. Rapold, W.L. Mattice, Macromolecules 29, 2457 (1996)

    Article  Google Scholar 

  37. J. Cho, W.L. Mattice, Macromolecules 30, 637 (1997)

    Article  Google Scholar 

  38. P. Doruker, W.L. Mattice, Macromol. Theor. Simul. 8, 463 (1999)

    Article  Google Scholar 

  39. R. Ozisik, P. Doruker, W.L. Mattice, E.D. von Meerwall, Comput. Theor. Polym. Sci. 10, 411 (2000)

    Article  Google Scholar 

  40. T.C. Clancy, M. Putz, J.D. Weinhold, J.G. Curro, W.L. Mattice, Macromolecules 9, 452 (2000)

    Google Scholar 

  41. S. Sen, J.M. Cohen, J.D. McCoy, J.G. Curro, J. Chem. Phys. 101, 9010 (1994)

    Article  Google Scholar 

  42. P.G. de Gennes, Adv. Colloid Interface Sci. 27, 189 (1987)

    Article  Google Scholar 

  43. J.M.H.M. Scheutjens, G.J. Fleer, J. Phys. Chem. 83, 1619 (1979)

    Article  Google Scholar 

  44. J.M.H.M. Scheutjens, G.J. Fleer, Macromolecules 18, 1882 (1985)

    Article  Google Scholar 

  45. Y. Zhan, W.L. Mattice, Macromolecules 27, 7056 (1994)

    Article  Google Scholar 

  46. K.F. Mansfield, D.N. Theodorou, Macromolecules 24, 6283 (1991)

    Article  Google Scholar 

  47. S.K. Kumar, M. Vacatello, D.Y. Yoon, Macromolecules 23, 2189 (1990)

    Article  Google Scholar 

  48. A. Yethiraj, J. Chem. Phys. 101, 2489 (1994)

    Article  Google Scholar 

  49. E. Eisenriegler, K. Kremer, K. Binder, J. Chem. Phys. 77, 6296 (1982)

    Article  Google Scholar 

  50. I.A. Bitanis, G. ten Brinke, J. Chem. Phys. 99, 3100 (1993)

    Article  Google Scholar 

  51. R.L. Jones, S.K. Kumar, D.L. Ho, R.M. Briber, T.P. Russell, Nature 400, 146 (1999)

    Article  Google Scholar 

  52. J. Kraus, P. Muller-Buschbaum, T. Kuhlman, D.W. Schubert, M. Stamm, Europhys. Lett. 49, 210 (2000)

    Article  Google Scholar 

  53. G. Allegra, G. Raos, M. Vacatello, Prog. Polym. Sci. 33, 683 (2008)

    Article  Google Scholar 

  54. A. Kloczkowski, M.A. Sharaf, J.E. Mark, Chem. Eng. Sci. 49, 2889 (1994)

    Article  Google Scholar 

  55. Q.W. Yuan, A. Kloczkowski, J.E. Mark and M.A. Sharaf, J. Poly. Sci. Poly. Phys. 34, 1647 (1996)

    Google Scholar 

  56. A.I. Nakatani, W. Chen, R.G. Schmidt, G.W. Gordon, C.C. Han, Polymer 42, 3713 (2001)

    Article  Google Scholar 

  57. M. Vacatello, Macromolecules 35, 8191 (2002)

    Article  Google Scholar 

  58. M.S. Ozmusul, R.C. Picu, Polymer 43, 4657 (2002)

    Article  Google Scholar 

  59. R.C. Picu, M.S. Ozmusul, J. Chem. Phys. 118, 11239 (2003)

    Article  Google Scholar 

  60. T. Pakula, J. Chem. Phys. 95, 4685 (1991)

    Article  Google Scholar 

  61. E.B. Zhulina, T. Pakula, Macromolecules 25, 754 (1992)

    Article  Google Scholar 

  62. T.C. Clancy, S.E. Webber, Macromolecules 26, 628 (1993)

    Article  Google Scholar 

  63. M.S. Ozmusul, R.C. Picu, S.S. Sternstein, S. Kumar, Macromolecules 38, 4495 (2005)

    Article  Google Scholar 

  64. S.S. Sternstein, A.J. Zhu, Macromolecules 35, 7262 (2002)

    Article  Google Scholar 

  65. A. Zhu, S.S. Sternstein, Compos. Sci. Technol. 63, 1113 (2003)

    Article  Google Scholar 

  66. P.J. Dionne, R.C. Picu, R. Ozisik, Macromolecules 39, 3089 (2006)

    Article  Google Scholar 

  67. R.C. Picu, A. Rakshit, J. Chem. Phys. 126, 144909 (2007)

    Article  Google Scholar 

  68. G.D. Smith, D. Bedrov, L. Li, O. Byutner, J. Chem. Phys. 117, 9478 (2002)

    Article  Google Scholar 

  69. V. Pryamitsyn, V. Ganesan, Macromolecules 39, 844 (2006)

    Article  Google Scholar 

  70. A.S. Sarvestani, R.C. Picu, Polymer 45, 7779 (2004)

    Article  Google Scholar 

  71. R.B. Bird, R.C. Armstrong, O. Hassager, Dynamics of Polymeric Liquids (Wiley, New York, 1987)

    Google Scholar 

  72. N. Phan Thien, R.I. Tanner, J. Non-Newtonian Fluid Mech. 2, 353 (1977)

    Google Scholar 

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Authors and Affiliations

  1. Department of Mechanical, Aerospace and Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, NY, 12180, USA

    R. Catalin Picu

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  1. R. Catalin Picu
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Correspondence to R. Catalin Picu .

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  1. Nanodesigns Consulting, Wilmington, Delaware, USA

    Vasyl Harik

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Picu, R.C. (2014). Molecular Mechanics of Polymer Nanocomposites. In: Harik, V. (eds) Trends in Nanoscale Mechanics. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9263-9_7

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  • DOI: https://doi.org/10.1007/978-94-017-9263-9_7

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