Skip to main content

Properties of 1-butyl-3-methylimidazolium tetrafluoroborate mixtures

  • Chapter
Physicochemical Properties of Ionic Liquid Mixtures

Abstract

This chapter contains a tabular compilation of volumetric, transport, thermodynamic and other properties of 1-butyl-3-methylimidazolium tetrafluoroborate mixtures.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Ge Y, Zhang L, Yuan X, Geng W, Ji J (2008) Selection of ionic liquids as entrainers for separation of (water + ethanol). The Journal of Chemical Thermodynamics 40 (8): 1248–1252.

    Article  CAS  Google Scholar 

  2. Navia P, Troncoso J, Romaní L (2008) Viscosities for ionic liquid binary mixtures with a common ion. Journal of Solution Chemistry 37 (5): 677–688.

    Article  CAS  Google Scholar 

  3. Navia P, Troncoso J, Romaní L (2007) Excess magnitudes for ionic liquid binary mixtures with a common ion. Journal of Chemical & Engineering Data 52 (4): 1369–1374.

    Article  CAS  Google Scholar 

  4. Shiflett MB, Yokozeki A (2008) Phase equilibria of hydrofluorocarbon-4310mee mixtures with ionic liquids: miscibility of threo- and erythro-diastereomers in ionic liquids. Industrial & Engineering Chemistry Research 47 (3): 926–934.

    Article  CAS  Google Scholar 

  5. Shiflett MB, Yokozeki A (2007) Liquid-liquid equilibria in binary mixtures of 1,3-propanediol + ionic liquids [bmim][PF6], [bmim][BF4], and [emim][BF4]. Journal of Chemical & Engineering Data 52 (4): 1302–1306.

    Article  CAS  Google Scholar 

  6. Zhang L, Han J, Wang R, Qiu X, Ji J (2007) Isobaric vapor–liquid equilibria for three ternary systems: Water + 2-propanol + 1-ethyl-3-methylimidazolium tetrafluoroborate, water + 1-propanol + 1-ethyl-3-methylimidazolium tetrafluoroborate, and water + 1-propanol + 1-butyl-3-methylimidazolium tetrafluoroborate. Journal of Chemical & Engineering Data 52 (4): 1401–1407.

    Article  CAS  Google Scholar 

  7. Rilo E, Pico J, García-Garabal S, Varela LM, Cabeza O (2009) Density and surface tension in binary mixtures of CnMIM-BF4 ionic liquids with water and ethanol. Fluid Phase Equilibria 285 (1–2): 83–89.

    Article  CAS  Google Scholar 

  8. Stoppa A, Hunger J, Buchner R (2009) Conductivities of binary mixtures of ionic liquids with polar solvents. Journal of Chemical Engineering & Data 54 (2): 472–479.

    Article  CAS  Google Scholar 

  9. Jork C, Seiler M, Beste YA, Arlt W (2004) Influence of ionic liquids on the phase behavior of aqueous azeotropic systems. Journal of Chemical & Engineering Data 49 (4): 852–857.

    Article  CAS  Google Scholar 

  10. Wang S, Jacquemin J, Husson P, Hardacre C, Costa Gomes MF (2009) Liquid–liquid miscibility and volumetric properties of aqueous solutions of ionic liquids as a function of temperature. The Journal of Chemical Thermodynamics 41 (11): 1206–1214.

    Article  CAS  Google Scholar 

  11. Canongia Lopes JN, Cordeiro TC, Esperanca JM, Guedes HJ, Huq S, Rebelo LP, Seddon KR (2005) Deviations from ideality in mixtures of two ionic liquids containing a common ion. The Journal of Physical Chemistry B 109 (8): 3519–3525.

    Article  Google Scholar 

  12. Hernández-Fernández FJ, de los Ríos AP, Gómez D, Rubio M, Tomás-Alonso F, Víllora G (2008) Ternary liquid–liquid equilibria for mixtures of an ionic liquid + n-hexane + an organic compound involved in the kinetic resolution of rac-1-phenyl ethanol (rac-1-phenyl ethanol, vinyl propionate, rac-1-phenylethyl propionate or propionic acid) at 298.2 K and atmospheric pressure. Fluid Phase Equilibria 263 (2): 190–198.

    Google Scholar 

  13. Shekaari H, Mousavi SS (2009) Measurement and modeling of osmotic coefficients of aqueous solution of ionic liquids using vapor pressure osmometry method. Fluid Phase Equilibria 279 (1): 73–79.

    Article  CAS  Google Scholar 

  14. Shekaari H, Zafarani-Moattar MT (2007) Osmotic coefficients of some imidazolium based ionic liquids in water and acetonitrile at temperature 318.15 K. Fluid Phase Equilibria 254 (1–2): 198–203.

    Article  CAS  Google Scholar 

  15. Kim K-S, Park S-Y, Choi S, Lee H (2004) Vapor pressures of the 1-butyl-3-methylimidazolium bromide + water, 1-butyl-3-methylimidazolium tetrafluoroborate + water, and 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate + water systems. Journal of Chemical & Engineering Data 49 (6): 1550–1553.

    Article  CAS  Google Scholar 

  16. Kim K-S, Shin B-K, Lee H, Ziegler F (2004) Refractive index and heat capacity of 1-butyl-3-methylimidazolium bromide and 1-butyl-3-methylimidazolium tetrafluoroborate, and vapor pressure of binary systems for 1-butyl-3-methylimidazolium bromide + trifluoroethanol and 1-butyl-3-methylimidazolium tetrafluoroborate + trifluoroethanol. Fluid Phase Equilibria 218 (2): 215–220.

    Article  CAS  Google Scholar 

  17. Abdulagatov IM, Tekin A, Safarov J, Shahverdiyev A, Hassel E (2008) High-pressure densities and derived volumetric properties (excess, apparent, and partial molar volumes) of binary mixtures of {methanol (1) + [BMIM][BF4] (2)}. The Journal of Chemical Thermodynamics 40 (9): 1386–1401.

    Article  CAS  Google Scholar 

  18. Shekaari H, Zafarani-Moattar MT (2008) Volumetric properties of the ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate, in organic solvents at T = 298.15 K. International Journal of Thermophysics 29 (2): 534–545.

    Article  CAS  Google Scholar 

  19. Iglesias-Otero MÁ, Troncoso J, Carballo E, Romaní L (2007) Density and refractive index for binary systems of the ionic liquid [Bmim][BF4] with methanol, 1,3-dichloropropane, and dimethyl carbonate. Journal of Solution Chemistry 36 (10): 1219–1230.

    Article  CAS  Google Scholar 

  20. Zafarani-Moattar MT, Shekaari H (2006) Application of Prigogine–Flory–Patterson theory to excess molar volume and speed of sound of 1-n-butyl-3-methylimidazolium hexafluorophosphate or 1-n-butyl-3-methylimidazolium tetrafluoroborate in methanol and acetonitrile. The Journal of Chemical Thermodynamics 38 (11): 1377–1384.

    Article  CAS  Google Scholar 

  21. Iglesias-Otero MA, Troncoso J, Carballo E, Romaní L (2008) Density and refractive index in mixtures of ionic liquids and organic solvents: Correlations and predictions. The Journal of Chemical Thermodynamics 40 (6): 949–956.

    Article  CAS  Google Scholar 

  22. Iglesias-Otero MA, Troncoso J, Carballo E, Romani´ L (2008) Densities and excess enthalpies for ionic liquids + ethanol or + nitromethane. Journal of Chemical & Engineering Data 53 (6): 1298–1301.

    Google Scholar 

  23. Abdulagatov IM, Tekin A, Safarov J, Shahverdiyev A, Hassel E (2008) Densities and excess, apparent, and partial molar volumes of binary mixtures of BMIMBF4 + ethanol as a function of temperature, pressure, and concentration. International Journal of Thermophysics 29 (2): 505–533.

    Article  CAS  Google Scholar 

  24. Han C, Xia S, Ma P, Zeng F (2009) Densities of ionic liquid [BMIM][BF4] + ethanol, + benzene, and + acetonitrile at different temperature and pressure. Journal of Chemical & Engineering Data 54 (10): 2971–2977.

    Article  CAS  Google Scholar 

  25. Zhu A, Wang J, Han L, Fan M (2009) Measurements and correlation of viscosities and conductivities for the mixtures of imidazolium ionic liquids with molecular solutes. Chemical Engineering Journal 147 (1): 27–35.

    Article  CAS  Google Scholar 

  26. Singh T, Kumar A, Kaur M, Kaur G, Kumar H (2009) Non-ideal behaviour of imidazolium based room temperature ionic liquids in ethylene glycol at T = (298.15 to 318.15) K. The Journal of Chemical Thermodynamics 41 (6): 717–723.

    Article  CAS  Google Scholar 

  27. Tian Y, Wang X, Wang J (2008) Densities and viscosities of 1-butyl-3-methylimidazolium tetrafluoroborate + molecular solvent binary mixtures. Journal of Chemical & Engineering Data 53 (9): 2056–2059.

    Article  CAS  Google Scholar 

  28. Bou Malham I, Turmine M (2008) Viscosities and refractive indices of binary mixtures of 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate with water at 298 K. The Journal of Chemical Thermodynamics 40 (4): 718–723.

    Article  CAS  Google Scholar 

  29. Bou Malham I, Letellier P, Mayaffre A, Turmine M (2007) Part I: Thermodynamic analysis of volumetric properties of concentrated aqueous solutions of 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-2,3-dimethylimidazolium tetrafluoroborate, and ethylammonium nitrate based on pseudo-lattice theory. The Journal of Chemical Thermodynamics 39 (8): 1132–1143.

    Article  CAS  Google Scholar 

  30. Zhou Q, Wang L-S, Chen H-P (2006) Densities and viscosities of 1-butyl-3-methylimidazolium tetrafluoroborate + H2O binary mixtures from (303.15 to 353.15) K. Journal of Chemical & Engineering Data 51 (3): 905–908.

    Article  CAS  Google Scholar 

  31. Yu Y-H, Soriano AN, Li M-H (2009) Heat capacity and electrical conductivity of aqueous mixtures of [Bmim][BF4] and [Bmim][PF6]. Journal of the Taiwan Institute of Chemical Engineers 40 (2): 205–212.

    Article  CAS  Google Scholar 

  32. Lin HM, Tien HY, Hone YT, Lee MJ (2007) Solubility of selected dibasic carboxylic acids in water, in ionic liquid of [Bmim][BF4], and in aqueous [Bmim][BF4] solutions. Fluid Phase Equilibria 253 (2): 130–136.

    Article  CAS  Google Scholar 

  33. Huo Y, Xia S, Ma P (2007) Densities of ionic liquids, 1-butyl-3-methylimidazolium hexafluorophosphate and 1-butyl-3-methylimidazolium tetrafluoroborate, with benzene, acetonitrile, and 1-propanol at T = (293.15 to 343.15) K. Journal of Chemical & Engineering Data 52 (5): 2077–2082.

    Article  CAS  Google Scholar 

  34. Huo Y, Xia S, Yi S, Ma P (2009) Measurement and correlation of vapor pressure of benzene and thiophene with [BMIM][PF6] and [BMIM][BF4] ionic liquids. Fluid Phase Equilibria 276 (1): 46–52.

    Article  CAS  Google Scholar 

  35. Makowska A, Siporska A, Szydlowski J (2006) Isotope effects on miscibility of 1-butyl-3-methylimidazolium tetrafluoroborate with butanols. The Journal of Physical Chemistry B 110 (34): 17195–17199.

    Article  CAS  Google Scholar 

  36. Comminges C, Barhdadi R, Laurent M, Troupel M (2006) Determination of viscosity, ionic conductivity, and diffusion coefficients in some binary systems: ionic liquids + molecular solvents. Journal of Chemical & Engineering Data 51 (2): 680–685.

    Article  CAS  Google Scholar 

  37. Chen Y, Zhang S, Yuan X, Zhang Y, Zhang X, Dai W, Mori R (2006) Solubility of CO2 in imidazolium-based tetrafluoroborate ionic liquids. Thermochimica Acta 441 (1): 42–44.

    Article  CAS  Google Scholar 

  38. Shiflett MB, Yokozeki A (2005) Solubilities and diffusivities of carbon dioxide in ionic liquids: [bmim][PF6] and [bmim][BF4]. Industrial & Engineering Chemistry Research 44 (12): 4453–4464.

    Article  CAS  Google Scholar 

  39. Kroon MC, Shariati A, Costantini M, van Spronsen J, Witkamp G-J, Sheldon RA, Peters CJ (2005) High-pressure phase behavior of systems with ionic liquids: Part V. The binary system carbon dioxide + 1-butyl-3-methylimidazolium tetrafluoroborate. Journal of Chemical & Engineering Data 50 (1): 173–176.

    Article  CAS  Google Scholar 

  40. Ferreira R, Blesic M, Trindade J, Marrucho I, Lopes JNC, Rebelo LPN (2008) Solubility of fluorinated compounds in a range of ionic liquids. Cloud-point temperature dependence on composition and pressure. Green Chemistry 10 (9): 918–928.

    Article  CAS  Google Scholar 

  41. Reiter J, Vondrák J, Michálek J, Micka Z (2006) Ternary polymer electrolytes with 1-methylimidazole based ionic liquids and aprotic solvents. Electrochimica Acta 52 (3): 1398–1408.

    Article  CAS  Google Scholar 

  42. Gao H, Qi F, Wang H (2009) Densities and volumetric properties of binary mixtures of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate with benzaldehyde at T = (298.15 to 313.15) K. The Journal of Chemical Thermodynamics 41 (7): 888–892.

    Article  CAS  Google Scholar 

  43. Qi F, Wang H (2009) Application of Prigogine–Flory–Patterson theory to excess molar volume of mixtures of 1-butyl-3-methylimidazolium ionic liquids with N-methyl-2-pyrrolidinone. The Journal of Chemical Thermodynamics 41 (2): 265–272.

    Article  CAS  Google Scholar 

  44. Kühne E, Santarossa S, Perez E, Witkamp GJ, Peters CJ (2008) New approach in the design of reactions and separations using an ionic liquid and carbon dioxide as solvents: Phase equilibria in two selected ternary systems. The Journal of Supercritical Fluids 46 (2): 93–98.

    Article  Google Scholar 

  45. Kühne E, Perez E, Witkamp GJ, Peters CJ (2008) Solute influence on the high-pressure phase equilibrium of ternary systems with carbon dioxide and an ionic liquid. The Journal of Supercritical Fluids 45 (1): 27–31.

    Article  Google Scholar 

  46. Zhang LZ, Deng DS, Han JZ, Ji DX, Ji JB (2007) Isobaric vapor–liquid equilibria for water + 2-propanol + 1-butyl-3-methylimidazolium tetrafluoroborate. Journal of Chemical & Engineering Data 52 (1): 199–205.

    Article  CAS  Google Scholar 

  47. Li Q, Zhang J, Lei Z, Zhu J, Wang B, Huang X (2009) Isobaric vapor–liquid equilibrium for (propan-2-ol + water + 1-butyl-3-methylimidazolium tetrafluoroborate). Journal of Chemical & Engineering Data 54 (9): 2785–2788.

    Article  CAS  Google Scholar 

  48. Wu B, Zhang Y, Wang H, Yang L (2008) Temperature dependence of phase behavior for ternary systems composed of ionic liquid + sucrose + water. The Journal of Physical Chemistry B 112 (41): 13163–13165.

    Article  CAS  Google Scholar 

  49. Wu B, Zhang Y, Wang H (2008) Phase behavior for ternary systems composed of ionic liquid + saccharides + water. The Journal of Physical Chemistry B 112 (20): 6426–6429.

    Article  CAS  Google Scholar 

  50. Kühne E, Calvo ES, Witkamp GJ, Peters CJ (2008) Fluid phase behaviour of the ternary system bmim[BF4] + 1-(4-isobutylphenyl)-ethanol + carbon dioxide. The Journal of Supercritical Fluids 45 (3): 293–297.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Zhang, S., Zhou, Q., Lu, X., Song, Y., Wang, X. (2016). Properties of 1-butyl-3-methylimidazolium tetrafluoroborate mixtures. In: Zhang, S., Zhou, Q., Lu, X., Song, Y., Wang, X. (eds) Physicochemical Properties of Ionic Liquid Mixtures. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-7573-1_34

Download citation

Publish with us

Policies and ethics