Abstract
It is widely accepted that hydrogen energy can sustainably provide the world’s growing energy needs. Currently, hydrogen is produced from mainly nonrenewable feedstocks through biochemical and thermochemical technologies. However, to achieve a genuinely sustainable, economic, viable, and environmentally benign technology, hydrogen will need to be produced from renewable energy sources through innovative production processes. This chapter focuses on one of these technologies that provide a novel approach for hydrogen production: supercritical water gasification of biomass. The process has significant potential for the conversion of biomass to produce hydrogen and other combustible gases. It also has major advantages when compared with other processes, such as eliminating the necessity for drying of the feedstock, providing high gasification efficiency and hydrogen selectivity, enabling the formation of clean gaseous products, and producing much lower amounts of tars and chars. To increase the hydrogen selectivity, the use of catalysts is common, with the preferred catalysts being alkaline salts, some metals, and metal oxides. The supercritical water gasification process can exhibit different gas compositions or activities with respect to the feedstock, reaction conditions, or catalyst used. Therefore, in this chapter, hydrogen production from various biomass sources by supercritical water gasification is comparatively discussed with examples from the literature. The term biomass covered in this chapter includes model compounds (such as glucose, cellulose, and lignin), alcohols, and real biomass (such as industrial wastewaters and sewage sludge). The effects of reaction time, system temperature and pressure, biomass concentration, oxidant concentration, catalyst use, and the kind of catalyst on the hydrogen yield are investigated.
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Mattos LV, Noronha FB. Partial oxidation of ethanol on supported Pt catalysts. J Power Sources. 2005;145:10–5.
Susanti RF, Kim J, Yoo K. Supercritical water gasification for hydrogen production: current status and prospective of high-temperature operation. Supercritical fluid technology for energy and environmental applications, chapter 6. Elsevier:Poland, 2014.
Akgün M, Kıpçak E. Catalytic hydrogen production from 2-propanol in supercritical water: comparison of some metal catalysts. J Supercrit Fluids. 2014;90:101–9.
Alauddin ZABZ, Lahijani P, Mohammadi M, Mohamed AR. Gasification of lignocellulosic biomass in fluidized beds for renewable energy development: a review. Renew Sust Energ Rev. 2010;14:2852–62.
Kalinci Y, Hepbasli A, Dincer I. Biomass-based hydrogen production: a review and analysis. Int J Hydrog Energy. 2009;34:8799–817.
Zhang J. Hydrogen production by biomass gasification in supercritical water. Energeia. 2008;19(6):1–6.
Reddy SN, Nanda S, Dalai AK, Kozinski JA. Supercritical water gasification of biomass for hydrogen production. Int J Hydrog Energy. 2014;39:6912–26.
Kırtay E. Recent advances in production of hydrogen from biomass. Energy Convers Manag. 2011;52:1778–89.
Susanti RF, Veriansyah B, Kim J, Kim J, Lee Y. Continuous supercritical water gasification of isooctane: a promising reactor design. Int J Hydrog Energy. 2010;35:1957–70.
Ding N, Azargohar R, Dalai AK, Kozinski JA. Catalytic gasification of cellulose and pinewood to H2 in supercritical water. Fuel. 2014;118:416–25.
Azadi P, Farnood R. Review of heterogeneous catalysts for sub- and supercritical water gasification of biomass and wastes. Int J Hydrog Energy. 2011;36:9529–41.
Yanik J, Ebale S, Kruse A, Saglam M, Yüksel M. Biomass gasification in supercritical water: part 1. Effect of the nature of biomass. Fuel. 2007;86:2410–5.
Jessop PG, Leitner W. Chemical synthesis using supercritical fluids. Germany: WILEY-VCH; 1999.
Poling BE, Prausnitz JM, O’Connell JP. The properties of gases and liquids. 5th ed. New York: McGraw-Hill Higher Education; 2001.
Kruse A, Dinjus E. Hot compressed water as reaction medium and reactant 1. Properties and synthesis reactions. J Supercrit Fluids. 2007;39:362–80.
Akiya N, Savage PE. Roles of water for chemical reactions in high-temperature water. Chem Rev. 2002;102:2725–50.
Krammer P, Vogel H. Hydrolysis of esters in subcritical and supercritical water. J Supercrit Fluids. 2000;16:189–206.
Zhou N, Krishnan A, Vogel F, Peters WA. A computational model for supercritical water oxidation of toxic organic wastes. Adv Environ Res. 2000;4:79–95.
Brunner G. Near critical and supercritical ware. Part I. Hydrolytic and hydrothermal processes. J Supercrit Fluids. 2009;47:373–81.
He C, Chen CL, Giannis A, Yang Y, Wang JY. Hydrothermal gasification of sewage sludge and model compounds for renewable hydrogen production: a review. Renew Sust Energ Rev. 2014;39:1127–42.
Kruse A, Dinjus E. Hot compressed water as reaction medium and reactant 2. Degradation reactions. J Supercrit Fluids. 2007;41:361–79.
Gasafi E, Reinecke MY, Kruse A, Schebek L. Economic analysis of sewage sludge gasification in supercritical water for hydrogen production. Biomass Bioenergy. 2008;32:1085–96.
Kruse A, Gawlik A. Biomass conversion in water at 330–410°C and 30–50 MPa. Identification of key compounds for indicating different chemical reaction pathways. Ind Eng Chem Res. 2003;42:267–79.
Guo Y, Wang SZ, Xu DH, Gong YM, Ma HH, Tang XY. Review of catalytic supercritical water gasification for hydrogen production from biomass. Renew Sust Energ Rev. 2010;14:334–43.
Anikeev VI, Yermakova A, Manion J, Huie R. Kinetics and thermodynamics of 2-propanol dehydration in supercritical water. J Supercrit Fluids. 2004;32:123–35.
Basu P. Biomass gasification and pyrolysis: practical design and theory. United States: Elsevier Academic Press; 2010.
Susanti RF, Dianningrum LW, Yum T, Kim Y, Lee BG, Kim J. High-yield hydrogen production from glucose by supercritical water gasification without added catalyst. Int J Hydrog Energy. 2012;37:11677–90.
Lu Y, Li S, Guo L, Zhang X. Hydrogen production by biomass gasification in supercritical water over Ni/γAl2O3 and Ni/CeO2-γAl2O3 catalysts. Int J Hydrog Energy. 2010;35:7161–8.
Williams PT, Onwudili J. Composition of products from the supercritical water gasification of glucose: a model biomass compound. Ind Eng Chem Res. 2005;44:8739–49.
Müller JB, Vogel F. Tar and coke formation during hydrothermal processing of glycerol and glucose. Influence of temperature, residence time and feed concentration. J Supercrit Fluids. 2012;70:126–36.
Van Rossum G, Potic B, Kersten SRA, Van Swaaij WPM. Catalytic gasification of dry and wet biomass. Catal Today. 2009;145:10–8.
Matsumura Y, Minowa T, Potic B, Kersten SRA, Prins W, Van Swaaij WPM, Van de Beld B, Elliott DC, Neuenschwander GG, Kruse A, Antal Jr MJ. Biomass gasification in near- and super-critical water: status and prospects. Biomass Bioenergy. 2005;29:269–92.
Peterson AA, Vogel F, Lachance RP, Fröling M, Antal Jr MJ, Tester JW. Thermochemical biofuel production in hydrothermal media: a review of sub- and supercritical water technologies. Energy Environ Sci. 2008;1:32–65.
Boukis N, Diem V, Habicht W, Dinjus E. Methanol reforming in supercritical water. Ind Eng Chem Res. 2003;42:728–35.
Taylor JD, Herdman CM, Wu BC, Wally K, Rice SF. Hydrogen production in a compact supercritical water reformer. Int J Hydrog Energy. 2003;28:1171–8.
Goodwin AK, Rorrer GL. Reaction rates for supercritical water gasification of xylose in a micro-tubular reactor. Chem Eng J. 2010;163:10–21.
Jin H, Lu Y, Guo L, Cao C, Zhang X. Hydrogen production by partial oxidative gasification of biomass and its model compounds in supercritical water. Int J Hydrog Energy. 2010;35:3001–10.
Therdthianwong S, Srisiriwat N, Therdthianwong A, Croiset E. Hydrogen production from bioethanol reforming in supercritical water. J Supercrit Fluids. 2011;57:58–65.
Guo Y, Wang S, Huelsman CM, Savage PE. Products, pathways, and kinetics for reactions of indole under supercritical water gasification conditions. J Supercrit Fluids. 2013;73:161–70.
Liu Q, Liao L, Liu Z, Dong X. Hydrogen production by glycerol reforming in supercritical water over Ni/MgO-ZrO2 catalyst. J Energy Chem. 2013;22:665–70.
Zhang L, Xu C, Champagne P. Energy recovery from secondary pulp/paper-mill sludge and sewage sludge with supercritical water treatment. Bioresour Technol. 2010;101:2713–21.
Kıpçak E, Söğüt OÖ, Akgün M. Hydrothermal gasification of olive mill wastewater as a biomass source in supercritical water. J Supercrit Fluids. 2011;57:50–7.
Cao C, Guo L, Chen Y, Guo S, Lu Y. Hydrogen production from supercritical water gasification of alkaline wheat straw pulping black liquor in continuous flow system. Int J Hydrog Energy. 2011;36:13528–35.
Lu Y, Guo L, Zhang X, Ji C. Hydrogen production by supercritical water gasification of biomass: explore the way to maximum hydrogen yield and high carbon gasification efficiency. Int J Hydrog Energy. 2012;37:3177–85.
Chen Y, Guo L, Cao W, Jin H, Guo S, Zhang X. Hydrogen production by sewage sludge gasification in supercritical water with fluidized bed reactor. Int J Hydrog Energy. 2013;38:12991–9.
Sricharoenchaikul V. Assessment of black liquor gasification in supercritical water. Bioresour Technol. 2009;100:638–43.
Karakuş Y, Aynacı F, Kıpçak E, Akgün M. Hydrogen production from 2-propanol over Pt/Al2O3 and Ru/Al2O3 catalysts in supercritical water. Int J Hydrog Energy. 2013;38:7298–306.
Gadhe JB, Gupta RB. Hydrogen production by methanol reforming in supercritical water: catalysis by in-situ-generated copper nanoparticles. Int J Hydrog Energy. 2007;32:2374–81.
Byrd AJ, Pant KK, Gupta RB. Hydrogen production from ethanol by reforming in supercritical water using Ru/Al2O3 catalyst. Energy Fuel. 2007;21:3541–7.
D’Jesus P, Boukis N, Kraushaar-Czarnetzki B, Dinjus E. Influence of process variables on gasification of corn silage in supercritical water. Ind Eng Chem Res. 2006;45:1622–30.
D’Jesus P, Boukis N, Kraushaar-Czarnetzki B, Dinjus E. Gasification of corn and clover grass in supercritical water. Fuel. 2006;85:1032–8.
Arita T, Nakahara K, Nagamib K, Kajimoto O. hydrogen generation from ethanol in supercritical water without catalyst. Tetrahedron Lett. 2003;44:1083–6.
Boukis N, Diem V, Galla U, Dinjus E. Methanol reforming in supercritical water for hydrogen production. Combust Sci Technol. 2006;178:467–85.
Susanti RF, Nugroho A, Lee J, Kim Y, Kim J. Noncatalytic gasification of isooctane in supercritical water: a strategy for high-yield hydrogen production. Int J Hydrog Energy. 2011;36:3895–906.
Yu D, Aihara M, Antal Jr MJ. Hydrogen production by steam reforming glucose in supercritical water. Energy Fuel. 1993;7:574–7.
Xu D, Wang S, Tang X, Gong Y, Guo Y, Zhang J, Wang Y, Ma H, Zhou L. Influence of oxidation coefficient on product properties in sewage sludge treatment by supercritical water. Int J Hydrog Energy. 2013;38:1850–8.
Kıpçak E, Akgün M. Oxidative gasification of olive mill wastewater as a biomass source in supercritical water: effects on gasification yield and biofuel composition. J Supercrit Fluids. 2012;69:57–63.
Guo LJ, Lu YJ, Zhang XM, Ji CM, Guan Y, Pei AX. Hydrogen production by biomass gasification in supercritical water: a systematic experimental and analytical study. Catal Today. 2007;129:275–86.
Li S, Lu Y, Guo L, Zhang X. Hydrogen production by biomass gasification in supercritical water with bimetallic Ni-M/γAl2O3 catalysts (M = Cu, Co and Sn). Int J Hydrog Energy. 2011;36:14391–400.
Xu D, Wang S, Hu X, Chen C, Zhang Q, Gong Y. Catalytic gasification of glycine and glycerol in supercritical water. Int J Hydrog Energy. 2009;34:5357–64.
Watanabe M, Inomata H, Arai K. Catalytic hydrogen generation from biomass (glucose and cellulose) with ZrO2 in supercritical water. Biomass Bioenergy. 2002;22:405–10.
Watanabe M, Inomata H, Osada M, Sato T, Adschiri T, Arai K. Catalytic effects of NaOH and ZrO2 for partial oxidative gasification of n-hexadecane and lignin in supercritical water. Fuel. 2003;82:545–52.
Osada M, Sato T, Watanabe M, Adschiri T, Arai K. Low-temperature catalytic gasification of lignin and cellulose with a ruthenium catalyst in supercritical water. Energy Fuel. 2004;18:327–33.
Onwudili JA, Williams PT. Role of sodium hydroxide in the production of hydrogen gas from the hydrothermal gasification of biomass. Int J Hydrog Energy. 2009;34:5645–56.
Kruse A, Meier D, Rimbrecht P, Schacht M. Gasification of pyrocatechol in supercritical water in the presence of potassium hydroxide. Ind Eng Chem Res. 2000;39:4842–8.
Guo S, Guo L, Cao C, Yin J, Lu Y, Zhang X. Hydrogen production from glycerol by supercritical water gasification in a continuous flow tubular reactor. Int J Hydrog Energy. 2012;37:5559–68.
Hao XH, Guo LJ, Mao X, Zhang XM, Chen XJ. Hydrogen production from glucose used as a model compound of biomass gasified in supercritical water. Int J Hydrog Energy. 2003;28:55–61.
Sinag A, Kruse A, Rathert J. influence of the heating rate and the type of catalyst on the formation of key intermediates and on the generation of gases during hydropyrolysis of glucose in supercritical water in a batch reactor. Ind Eng Chem Res. 2004;42:502–8.
Madenoglu TG, Saglam M, Yuksel M, Ballice L. Simultaneous effect of temperature and pressure on catalytic hydrothermal gasification of glucose. J Supercrit Fluids. 2013;73:151–60.
Madenoglu TG, Boukis N, Saglam M, Yuksel M. Supercritical water gasification of real biomass feedstocks in continuous flow system. Int J Hydrog Energy. 2011;36:14408–15.
Taylor AD, DiLeo GJ, Sun K. Hydrogen production and performance of nickel based catalysts synthesized using supercritical fluids for the gasification of biomass. Appl Catal B Environ. 2009;93:126–33.
Yoshida T, Oshima Y, Matsumura Y. Gasification of biomass model compounds and real biomass in supercritical water. Biomass Bioenergy. 2004;26:71–8.
Lu Y, Li S, Guo L. Hydrogen production by supercritical water gasification of glucose with Ni/CeO2/Al2O3: effect of Ce loading. Fuel. 2013;103:193–9.
Osada M, Sato T, Watanabe M, Arai K, Shirai M. Water density effect on lignin gasification over supported noble metal catalysts in supercritical water. Energy Fuel. 2006;20:930–5.
Therdthianwong S, Srisiriwat N, Therdthianwong A, Croiset E. Reforming of bioethanol over Ni/Al2O3 and Ni/CeZrO2/Al2O3 catalysts in supercritical water for hydrogen production. Int J Hydrog Energy. 2011;36:2877–86.
Lee I. Effect of metal addition to Ni/activated charcoal catalyst on gasification of glucose in supercritical water. Int J Hydrog Energy. 2011;36:8869–77.
Osada M, Hiyoshi N, Sato O, Arai K, Shirai M. Reaction pathway for catalytic gasification of lignin in presence of sulfur in supercritical water. Energy Fuel. 2007;21:1854–8.
Byrd AJ, Kumar S, Kong L, Ramsurn H, Gupta RB. Hydrogen production from catalytic gasification of switchgrass biocrude in supercritical water. Int J Hydrog Energy. 2011;36:3426–33.
Byrd AJ, Pant KK, Gupta RB. Hydrogen production from glucose using Ru/Al2O3 catalyst in supercritical water. Ind Eng Chem Res. 2007;46:3574–9.
Onwudili JA, Williams PT. Hydrogen and methane selectivity during alkaline supercritical water gasification of biomass with ruthenium-alumina catalyst. Appl Catal B Environ. 2013;132–133:70–9.
Yamaguchi A, Hiyoshi N, Sato O, Bando KK, Osada M, Shirai M. Hydrogen production from woody biomass over supported metal catalysts in supercritical water. Catal Today. 2009;146:192–5.
Youssef EA, Elbeshbishy E, Hafez H, Nakhla G, Charpentier P. Sequential supercritical water gasification and partial oxidation of hog manure. Int J Hydrog Energy. 2010;35:11756–67.
Kıpçak E, Akgün M. In-situ gas fuel production during the treatment of textile wastewater at supercritical conditions. Water Sci Technol. 2013;67(5):1058–67.
Hendry D, Venkitasamy C, Wilkinson N, Jacoby W. Exploration of the effect of process variables on the production of high-value fuel gas from glucose via supercritical water gasification. Bioresour Technol. 2011;102:3480–7.
Guan Q, Savage PE, Weib C. Gasification of alga Nannochloropsis Sp. in supercritical water. J Supercrit Fluids. 2012;61:139–45.
Wilkinson N, Wickramathilaka M, Hendry D, Miller A, Espanani R, Jacoby W. Rate determination of supercritical water gasification of primary sewage sludge as a replacement for anaerobic digestion. Bioresour Technol. 2012;124:269–75.
Escot Bocanegra P, Reverte C, Aymonier C, Loppinet-Serani A, Barsan MM, Butler IS, Kozinski JA, Gökalp I. Gasification study of winery waste using a hydrothermal diamond anvil cell. J Supercrit Fluids. 2010;53:72–81.
Osada M, Sato O, Arai K, Shirai M. Stability of supported ruthenium catalysts for lignin gasification in supercritical water. Energy Fuel. 2006;20:2337–43.
Byrd AJ, Pant KK, Gupta RB. Hydrogen production from glycerol by reforming in supercritical water over Ru/Al2O3 catalyst. Fuel. 2008;87:2956–60.
Furusawa T, Sato T, Sugito H, Miura Y, Ishiyama Y, Sato M, Itoh N, Suzuki N. Hydrogen production from the gasification of lignin with nickel catalysts in supercritical water. Int J Hydrog Energy. 2007;32:699–704.
May A, Salvado J, Torras C, Montane D. Catalytic gasification of glycerol in supercritical water. Chem Eng J. 2010;160:751–9.
Youssef EA, Chowdhury MBI, Nakhla G, Charpentier P. Effect of nickel loading on hydrogen production and chemical oxygen demand (COD) destruction from glucose oxidation and gasification in supercritical water. Int J Hydrog Energy. 2010;35:5034–42.
Zhang L, Champagne P, Xu CC. Supercritical water gasification of an aqueous by-product from biomass hydrothermal liquefaction with novel Ru modified Ni catalysts. Bioresour Technol. 2011;102:8279–87.
Waldner MH, Vogel F. Renewable production of methane from woody biomass by catalytic hydrothermal gasification. Ind Eng Chem Res. 2005;44:4543–51.
Muangrat R, Onwudili JA, Williams PT. Alkaline subcritical water gasification of dairy industry waste (whey). Bioresour Technol. 2011;102:6331–5.
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Kıpçak, E., Akgün, M. (2015). Hydrogen Production by Supercritical Water Gasification of Biomass. In: Fang, Z., Smith, Jr., R., Qi, X. (eds) Production of Hydrogen from Renewable Resources. Biofuels and Biorefineries, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-7330-0_7
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DOI: https://doi.org/10.1007/978-94-017-7330-0_7
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