Abstract
A “carboxylated polymer” is one which contains a minor proportion of monomer units which bear carboxylic-acid groups copolymerized with a major proportion of monomer units which do not bear carboxylic-acid groups. By “minor proportion” in this context is meant between zero and about 10% by weight; in many cases, the amount is less than 5% by weight. It is usually understood that the carboxylic-acid-bearing monomer units are copolymerized essentially at random with the other monomer units; thus, for instance, the term “carboxylated polymer” as commonly used excludes carboxyl-terminated polymers in which the carboxylic-acid groups are confined to the ends of the polymer chains.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Marvel, C.S., et al., J. Polymer Science, 1952, 8, 599
Frank, C.E., Kraus, G., and Haefner, A.J., Industrial and Engineering Chemistry, 1952, 44, 1600
B.F. Goodrich Company, U.S. Patent No. 2,662, 874 (1953)
B.F. Goodrich Company, U.S. Patent No. 2,671, 074 (1954)
B.F. Goodrich Company, U.S. Patent No. 2,698, 318 (1954)
Brown, H.P., and Gibbs, C.F., Industrial and Engineering Chemistry, 1955, 47, 1006
Brown, H.P., Rubber Chemistry and Technology, 1957, El, 1347
Brown, H.P., Rubber Chemistry and Technology, 1963, 3. 60 931
Firestone Tire & Rubber Company, U.S. Patent No. 2, 849, 426 (1958)
Feast, A.A., “Synthetic Latices” in Polymer Latices and their Applications“, ed. Calvert, K.O., Applied Science, London, 1982
Greene, B.W., Sheetz, D.P., and Filer, T.D., J. Colloid and Interface Science, 1970, 32, 90
Greene, B.W., and Sheetz, D.P., J. Colloid and Interface Science, 1970, 32, 96
Greene, B.W., and Saunders, F.L., J. Colloid and Interface Science 1970, 5J., 393
Snupârek, J., and T1A6,lkov5,, A., J. Applied Polymer Science, 1979, 221, 915
Greene, B.W., Nelson, A.R., and Keskey, W.H., J. Physical Chemistry, 1980, IA, 1615
Dow Chemical Company, British Patent No. 1, 023, 202 (1966)
Dow Chemical Company, U.S. Patent No. 3,422, 038 (1969)
Zimmerman, R.L., Hibbard, B.B., and Bailey, H.R., Rubber Age, New York, 1966, 28 (5), 68
Doverstrand, British Patent No. 1, 182, 253 (1970)
Dow Chemical Company, British Patent No. 945, 219 (1963)
Nishida, S., El-Aasser, M.S., Klein A., and Vanderhoff, J.W.,“Preparation and Characterization of Alkali-Swellable Carboxylated Latexes” in Emulsion Polymers and Emulsion Polymerization, ed. Bassett, D.R., and Hamielec, A.E., ACS Symposium Series No. 165, ACS, Washington, 1981, pp. 290–314
Nishida, S., Ph.D. Dissertation, Lehigh University, 1980
Standard Brands Chemical Industries, U.S. Patent No. 3,480, 578 (1969)
Egusa, S., and Makuuchi, K., J. Colloid and Interface Science, 1981, 79 350
Dow Chemical Company, British Patent No.1, 076, 231 (1967)
Wesslau, H., Makromolekulare Chemie, 1963, 62, 220
Verbrugge, C.J., J. Applied Polymer Science 1970, JAL, 897
Verbrugge, C.J., J. Applied Polymer Science, 1970, 21, 911
Hoy, K.L., J. Coatings Technology 1979, 5.1(651)27
Bassett, D.R., and Hoy, K.L., “The Expansion Characteristics of Carboxylic Emulsion Polymers. I. Particle Expansion Determined by Sedimentation” in Polymer Colloids II,ed. Fitch, R.M., Plenum Press, New York, 1980, pp. 1–25
Muroi, S., Hosoi, K., and Ishikawa, T., J. Applied Polymer Science, 1967, 11, 1963
Vanderhoff, J.W., van den Hul, H.J., and Hamburg, R.D., paper presented at ACS International Symposium on Emulsion Polymers, Philadelphia, 1975; Polymer Preprints 1975, 155
Ceska, G.W., J. Applied Polymer Science, 1974, 18, 427
Sakota, K., and Okaya, T., J. Applied Polymer Science, 1976, 20, 1735
Sakota, K., and Okaya, T., J. Applied Polymer Science, 1976, 20, 2583
Greene, B.W., J. Colloid and Interface Science 1973,,E 449
Greene, B.W., J. Colloid and Interface Science 1973, Al, 462
Ono, H., Jidai, E., and Shibayama, K., British Polymer J., 1975, 1, 109
Ono, H., Jidai, E., and Shibayama, K., Colloid and Polymer Science, 1977, 212, 105
Vijayendran, B.R., J. Applied Polymer Science, 1979, 2, 893
Ceska, G.W., J. Applied Polymer Science, 1974, 18, 2493
Sakota, K., and Okaya, T., J. Applied Polymer Science, 1976 20, 1745
Sakota, K., and Okaya, T., J. Applied Polymer Science, 1976, 20, 3255
Sakota, K., and Okaya, T., J. Applied Polymer Science, 1976, 20, 3265
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Blackley, D.C. (1983). Production of Carboxylated Latices by Emulsion Polymerization. In: Poehlein, G.W., Ottewill, R.H., Goodwin, J.W. (eds) Science and Technology of Polymer Colloids. NATO ASI Series, vol 67-68. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-4797-4_9
Download citation
DOI: https://doi.org/10.1007/978-94-017-4797-4_9
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-247-2832-9
Online ISBN: 978-94-017-4797-4
eBook Packages: Springer Book Archive