Abstract
Polymer colloids are produced in batch, semi-batch and continuous reactors of a wide variety of designs. All of these reactors have assets and liabilities and every commercial process design involves compromises among concerns for product quality, manufacturing simplicity, costs, and potential future alternatives. The primary purpose of this paper is to provide information on continuous emulsion polymerization reactors that will help the reader to make rational decisions on the possible use of such reactors in the commercial production of polymer latexes. A second purpose is to demonstrate the utility of continuous reactors as a tool for studying reaction kinetics.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Poehlein, G. W. and D. J. Dougherty. Rubber Chem. Technol. vol. 50 (3) (1977) 601–638.
Poehlein, G. W. in Emulsion Polymerization, I. Piirma, Ed. (New York, Academic Press, 1982).
Lee, C. K. and T. H. Forsyth in Emulsion Polymers and Emulsion Polymerization, D. R. Basset and A. E. Hamielec, Eds. (Washington, DC, ACS Symposium Series 165, 1981).
Rollin, A. L., W. Ian Patterson, J. Archambault and B. Bataille in Polymerization Reactors and Processes, J. N Henderson and T. C. Bouton, Eds. (Washington, DC, ACS Symposium Series 104, 1979).
Lanthier, R. U.S. Patent 3,551,396 Assigned to Gulf Oil Canada, Ltd. (1970).
Gonzalez P., R. A. M.S. Thesis, Chem. Engr. Dept. Lehigh University (1974).
Greene, R. K., R. A. Gonzalez P. and G. W. Poehlein in Emulsion Polymerization, I. Piirma and J. Gardon, Eds. (Washington, DC, ASC Symposium Series, 24, 1976).
Pettelkau and Ehrig.German Patent 2,520,891 Assigned to Bayer AG (1976).
Poehlein, G. W. in Polymerization Reactors and Processes, J. Henderson and T. Bouton, Eds. (Washington, DC, ACS Symposium Series 104, 1979).
Smith, W. V. and R. H. Ewart. J. Chem. Phys., vol. 16 (1948) 592.
DeGraff, A. W. and G. W. Poehlein. J. Poly. Sci. A-2, vol. 9 (1971) 1955.
Nomura, M. and M. Harada in Emulsion Polymers and Emulsion Polymerization, D. Bassett and A. Hamielec, Eds. (Washington, DC, ACS Symposium Series 165, 1981).
Bassett, D. R. and K. L. Hoy, Ibid. 371–387.
Johnston, J.A., D. R. Bassett and T. B. MacRury, Ibid. 388–403.
O’Toole, J. T. J. Appl. Poly. Sci. vol. 9 (1965) 1291.
Ugelstad, J., P. C. Merk and J. 0. Aasen. J. Poly. Sci. A-1, vol. 5 (1967) 2281.
Poehlein, G. W., W. Dubner and H. C. Lee. Brit. Poly. J. In press (1982).
Lee, H. C. and G. W. Poehlein. Unpublished Work, Georgia Institute of Technology (1982).
Berens, A. J. Appl. Poly. Sci. vol. 18 (1974) 2379.
Gardon, J. L. J. Poly. Sci. A-1, vol. 6 (1968) 623.
Kiparissides, C., J. M. MacGregor and A. E. Hamielec. J. Appl. Poly. Sci., vol. 23 (1979) 401; and Can. J. Chem. Eng. vol. 58 (1980) 48, 56, 65.
Kirillov, V. A. and W. H. Ray. Chem. Eng. Sci. vol. 23 (1978) 1499.
Dickinson, R. F. PhD Thesis, Chem. Eng. Dept. Univ. of Waterloo, Canada (1976).
Chiang, A. S. T. and R. W. Thompson. AIChE J. vol. 25 (1979) 552.
Schork, F. J. and W. H. Ray. J. Appl. Poly. Sci., vol. 20 (1982).
Guyot, A., J. Guillot, C. Pichot and L. Rois Guerrero in Emulsion Polymers and Emulsion Polymerization, D. Bassett and A. Hamielec, Eds. (Washington, DC, ACS Symposium Series 165, 1981).
Hamielec, A. E. and J. F. MacGregor in Emulsion Polymerization, I. Piirma, Ed. (New York, Academic Press, 1982).
Gordon, D. L. and K. R. Weidner, Ibid.
Leffew, K. W. and P. B. Deshpande, Ibid.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Poehlein, G.W. (1983). Emulsion Polymerization In Continuous Reactors. In: Poehlein, G.W., Ottewill, R.H., Goodwin, J.W. (eds) Science and Technology of Polymer Colloids. NATO ASI Series, vol 67-68. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-4797-4_5
Download citation
DOI: https://doi.org/10.1007/978-94-017-4797-4_5
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-247-2832-9
Online ISBN: 978-94-017-4797-4
eBook Packages: Springer Book Archive