Skip to main content

Concentrated Dispersions I. Fundamental Considerations

  • Chapter
Science and Technology of Polymer Colloids

Part of the book series: NATO ASI Series ((NSSE,volume 2))

Abstract

In the general field of Colloid Science and more specifically in the area of Polymer Colloids much of our current knowledge on the behaviour of dispersions has been gained from studies on dilute systems. In these dilute systems of low number concentration the particles can move around freely and their motion, the so-called Brownian Motion, is the translational diffusion of the particles. It was examined in some detail experimentally by Perrin (1) and theoretically by Einstein (2) in the early part of the twentieth century. The particles are in complete DISORDER and the essential features are:-

Thermal motion predominates over the effects imposed by interparticle forces giving a random arrangement of particles.

Particles interact mainly by two-body collisions. Simultaneous three-body collisions are rare.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Perrin, M. Jean. Brownian Movement and Molecular Reality, London, Taylor and Francis, 1910.

    Google Scholar 

  2. Einstein, A. Investigations on the Theory of Brownian Motion, (English Trans.) London, Metheun, 1926.

    Google Scholar 

  3. Brown, J.C., P.N. Pusey, J.W. Goodwin and R.H. Ottewill. J.Phys.A: Math.Gen.8, (1975) 664.

    Article  CAS  Google Scholar 

  4. Pusey, P.N. J.Phys.A: Math.Gen. 11 (1978) 119.

    Article  CAS  Google Scholar 

  5. Kerker, M. The Scattering of Light and Other Electromagnetic Radiation, New York, Academic Press, 1969.

    Google Scholar 

  6. Jacrot, B. Rep.Prog.Phys. 39 (1976) 911.

    Article  CAS  Google Scholar 

  7. Debye, P. Ann.Physik, 46 (1915) 809.

    Article  CAS  Google Scholar 

  8. Ottewill, R.H. Review Symposium on Colloid Science, London, Royal Society of Chemistry, Chapter 9, 1982.

    Google Scholar 

  9. Ottewill, R.H. and R.A. Richardson. Colloid and Polymer Science, (1982) in press.

    Google Scholar 

  10. Ashcroft, N.W. and J. Lekner. Phys.Rev. 45 (1966) 33.

    Google Scholar 

  11. Hayter, J.B. and J. Penfold, Molecular Physics 42 (1981) 109.

    Article  CAS  Google Scholar 

  12. Barker, G.A. and D. Henderson, J.Chem.Phys. 47 (1967) 4714.

    Article  CAS  Google Scholar 

  13. Barker, G.A. and D. Henderson, Ann.Rev.Phys.Chem. 23 (1972) 439.

    Article  CAS  Google Scholar 

  14. Derjaguin, B.V. and L. Landau, Acta Physicochim. U.R.S.S. 14 (1941) 633.

    Google Scholar 

  15. Verwey, E.J.W. and J.Th.G. Overbeek. Theory of the Stability of Lyophobic Colloids, Amsterdam, Elsevier, 1948.

    Google Scholar 

  16. Brenner, S.L. J.Physical Chem., 80 (1976) 1474.

    Article  Google Scholar 

  17. van Megen, W. and I. Snook, Faraday Disc.Chem.Soc., 65 (1978) 92.

    Article  Google Scholar 

  18. Percus, J.K. and G.J. Yevick, Phys.Rev. 110 (1958) 1.

    Article  CAS  Google Scholar 

  19. Vrij, A., E.A. Nieuwenhuis, H.M. Fijnaut and W.G.M. Agterof, Faraday Disc.Chem.Soc. 65 (1978) 101.

    Article  CAS  Google Scholar 

Useful General References

  • Croxton, C. Introduction to Liquid State Physics, London. John Wiley and Sons, 1975.

    Google Scholar 

  • Goodwin, J.W. Review Symposium on Colloid Science, London, Royal Society of Chemistry, 1982.

    Google Scholar 

  • McQuarrie, D.A. Statistical Mechanics, London, Harper and Row, 1976.

    Google Scholar 

  • Rowell, R.L. Characterization of Latices I. Optical Methods, this volume p.

    Google Scholar 

  • Tadros, Th.F. Physical Stability of Suspension Concentrates. Advances in Colloid and Interface Science, 12 (1980) 141–261.

    Article  CAS  Google Scholar 

  • Tadros, Th.F. Concentrated Dispersions II. An Industrial Viewpoint, this volume p.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Ottewill, R.H. (1983). Concentrated Dispersions I. Fundamental Considerations. In: Poehlein, G.W., Ottewill, R.H., Goodwin, J.W. (eds) Science and Technology of Polymer Colloids. NATO ASI Series, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-4795-0_12

Download citation

  • DOI: https://doi.org/10.1007/978-94-017-4795-0_12

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-247-2833-6

  • Online ISBN: 978-94-017-4795-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics