Abstract
The role of streambed sediment as a sink for pesticides and heavy metals was investigated in 30 Danish lowland streams. The investigated streams drain catchments varying in hydrology, topography, soil type and land use. The <250 Am newly accumulated fraction of the uppermost 1–2 cm layer of streambed sediment was analysed for 19 old and modern pesticides and 9 heavy metals. DDE was present in the sediment of all the streams. Of the herbicides, fungicides and insecticides currently in use, the most frequently detected was diuron (50.0%), fenpropimorph (66.7%) and lambda-cyhalothrin (6.7%), respectively. The pesticides detected in the highest concentration were fenpropimorph (1700 ng g−1), propiconazole (130 ng g−1) and isoproturon (110 ng g−1). The heavy metals are listed in order of increasing median concentration: Cd (0.80 μg g−1), Co (9.1 μg g−1), As (12.0 μg g−1), Ni (19.0 μg g−1), Cr (19.2 μg g−1), Pb (19.7 μg g−1), Cu (20.1 μg g−1), V (28.5 μg g−1), Zn (103 μg g−1). The average number of pesticides detected in the 27 streams draining predominantly agricultural catchments was (3.7±2.0) being higher (p = 0.077) than in the three streams draining non-agricultural catchments (1.7±0.6). Pesticides were significantly related to catchment size, soil type and hydrological regime. Several heavy metals (Cr, Cu, Pb, V and Zn) were related to urban activity and soil type.
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References
Bogestrand, J., 1999. Vandlob og kilder (Streams and springs 1999). Report no. 336 from The Danish National Environmental Research Institute. 2000 (in Danish).
European Comission. 2000. Directive 2000/60/EC of the European Parliament and the Council.
Friberg, N., M. Lindstrom, B. Kronvang and S. E. Larsen. 2003. Macroinvertebrate/sediment relationships along a pesticide gradient in Danish streams. Hydrobiologia 494 ( Dev. Flydrobiol. 169 ): 103–110.
Hollander. M. and D. A. Wolte. 1973. Nonparametric Statistical Methods. John Wiley, New York.
Förstner, U. and ( 3. Wittmann, 1983. Metal pollution in the aquatic environment. Springer-Verlag, Berlin.
Jongman, R. H. G., C. J. F ter Brak and O. F. R. van Tongeren, 1995. Data analysis in community and landscape ecology, Cambridge University Press, Cambridge.
Kassim. T. I.. H. A. Al-Saadi. A. A AlLami and H. H. Al-.Jaberi, 1997. Heavy metals in water. suspended particles, sediments and aquatic plants of the upper region of Euphrates river, Iraq. J. I.nviron. Sci. Health, part A; 32: 2497–2506.
Kern, E. and B. Westrich, 1995. Sediment contamination by heavy metals in a lock-regulated section of the river Neckar. Mar. Freshwat. Res. 46: 101–106.
Kreueer J. 1996. Pesticides in stream water within a small catchment in southern Sweden. Report from the Vemmenhög-project 1990–1994. Technical report No. 32, Swedish University of Agricultural Sciences, Division of Water Quality Management, Uppsala. 56 pp.
Kreuger, J. and L. Törngvist, 1998. Multiple regression analysis of pesticide occurrence in streamffow related to pesticide properties and quantities applied. Chemosphere 37: 189–207.
Larson, D. J., R. D. Capel and M. S. Majewski, 1997. Pesticides in surface water: distribution, trends and governing factors. Vol. 3 of the Series - Pesticides in the Hydrologic System, Ann Arbor Press, Inc., Chelsea, Michigan, U.S.A. 373 pp.
McCullueh. P. and J. A. Nelder. 1989. Generalized Linear Models. Second Edition. Chapman and Hall. London.
Melluso, G., A. I.sposito, M. Guida, F. Maurano, N. M. Tuieff and G. Pagano, 1994. Distribution of inorganic and organic pollutants in river sediments in Campania, Italy. Bull. Environ. Contam. Toxicol. 52: 13–18.
Mogensen, B. and B. Kronvang, 2000. Pdvisninger of pesticider i overlladevand–Detection of Pesticides in Danish Surface Waters. I: 17. Danske Plantevxrnskonference I. Formidling/miljo/ukrudt. Danmarks JordbrugsForskning. D.TF rapport. Markbuug23: 51–61 (in Danish).
Munn, M. D. and S. J. Gruber, 1997. The relationship between land use and organochlorine compounds in streambed sediment and fish in the central Columbia plateau Washington and Idaho, U.S.A. Environ. Toxicol. Chem. 16: 1877–1887.
Pereira, W. E., J. L. Domaealski. F. D. Hostettler. L. R. Brown and J. B. Rapp. 1996. Occurrence and accumulation of pesticides and organic contaminants in river sediment, water and clam tissues from the San Joaquin river and tributaries, California. Hnviron. Toxicol. Chem. 15: 172–180.
Rees, J. G., J. Ridgway, R. W. O. B. Knox, G. Wiggans and N. Breward, 1999. Sediment-borne contaminants in rivers discharging into the Humber estuary. U.K. Mar. Poll. Bull. 37: 316–329.
Rice, K. C., 1999. Trace-element concentrations in streambed sediment across the conterminous United States. Hnviron. Sci. Technol. 33: 2499–2504.
Singh, M.. A. A. Ansari, G. Muller and I. B. Singh, 1997. heavy metals in Freshly deposited sediments of the Gomati river (a tributary of the Ganges river) - effects of human activities. Environ. Geol. 29: 246–252.
Smith, J. A., P. T. Harte and M. A. Hardy, 1987. Trace-metal and organochlorine residues in sediments of the upper Rockaway river, New Jersey. Bull. I.nviron. Contam. Toxicol. 39: 465–473.
Stackelberg, P. E.. 1997. Presence and distribution of chlorinated organic compounds in streambed sediments. New Jersey. J. am. Wat. Resour. Ass. 33: 271–284.
Svendsen, L. M., B. Kronvang. P. Kristensen and P. Grrsholl, 1995. Dynamics of phosphorus compounds in a lowland river system: importance of retention and non-point sources. Hydro]. Process. 9: 119–142.
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Kronvang, B., Laubel, A., Larsen, S.E., Friberg, N. (2003). Pesticides and heavy metals in Danish streambed sediment. In: Kronvang, B. (eds) The Interactions between Sediments and Water. Developments in Hydrobiology, vol 169. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-3366-3_14
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DOI: https://doi.org/10.1007/978-94-017-3366-3_14
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