Abstract
The emergence of the synthetic dyestuffs industry during the second half of the nineteenth century is often presented as a tale of poorly exploited British inventiveness, followed by smooth and unhindered German successes. The British failed, according to the standard story, because they neglected appropriate education and legislation, were incompetent, and preferred to invest in profitable heavy manufacturing and colonial enterprises.1 The Germans succeeded because of their mastery of the use of formal knowledge, the introduction in 1877 of a comprehensive patent system, the inauguration of dedicated industrial research laboratories, and the application of business strategies based increasingly upon the power of ‘conventions,’ or cartels, and ‘communities of interests.’2
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References
Some of these issues are addressed elsewhere in this volume by Harm G. Schröter and Anthony S. Travis.
J.J. Beer, The Emergence of the German Dye Industry (Urbana, 1959; New York, 1981); G. Meyer-Thurow, `The industrialization of invention: A case study from the German chemical industry’, Isis, 73 (1982), 363–381.
A. Bernthsen, `Heinrich Caro’, Berichte der Deutschen Chemischen Gesellschaft, 45 (1912), 1987–2042.
Caro, Mannheim, to Meldola, London, 8 June 1886. Transcription by Geissler from Caro’s correspondence notebook, 1883–90 (original held in the Sondersammlung, Deutsches Museum, Munich, reference 8096) at BASF Archives, Ludwigshafen, section W1 (biographical) page no. 86a (Caro page no. 232). Hereafter cited as Geissler. Lothar Meinzer and Ruth Fromm of BASF Archives are thanked for assistance in providing copies of these transcriptions.
Meldola to Caro, 19 June 1886, uncatalogued item, general reference N93, Caro Nachlass, Sondersammlung, Deutsches Museum, hereafter SSDM. Elisabeth Vaupel of the chemistry department, Deutsches Museum, is thanked for assistance in locating relevant items of correspondence.
For the development of German patent law, see A. Fleischer, Patentgesetzgebung und chemisch pharmazeutischeIndustrie in deutschen Kaissereich (1871–1918) (Stuttgart, 1984), esp. pp. 98–169.
Journal of the Socie ty of Chemical Industry,10 (31 July 1891), 623. Cf. Fleischer, op. cit. (6), p. 122.
Heinrich Caro’s translation from the German, accompanying a letter to his London patent agent, John Henry Johnson, 8 November 1886, uncatalogued item, reference N93, SSDM. On Caro’s role in the patent cases discussed here, see also Fleischer, op. cit. (6), pp. 142147; and H. van den Belt, and A. Rip, `The Nelson-Winter-Dosi model and synthetic dye chemistry’, in W.E. Bijker, T.P. Hughes, and T. Pinch eds., The Social Construction of Technological Systems (Cambridge, Mass., 1987), pp. 135–158, esp. pp. 149–155.
H. Levinstein, `Proceedings of the Society. The first George Douglas lecture: George Douglas, his times, and some thoughts on the future’, Journal of the Society of Dyers and Colourists, 65 (1949), 272.
See M. Wyler, Ivan Levinstein - What I Know of Him (Manchester, 1937), reprinted in Journal of the Society of Dyers and Colourists, 55 (1939), 142–146. Wyler and others have pondered over the reasons for Levinstein’s failure to win the fast red AV case.
W.J. Reader, Imperial Chemical Industries: A History, vol. 1: The Forerunners 1870–1926 (London, 1970), p. 262.
F. Stern, Gold and Iron: Bismarck, Bleichröder and the Building of the German Empire (Harmondsworth, 1987), p. 18 (footnote).
M.R. Fox, Dye-makers of Great Britain, 1856–1976: A History of Chemists,Companies, Products and Changes (Manchester, 1987), chapter 1.
A.S. Travis, The Rainbow Makers: The Origins of the Synthetic Dyestuffs Industry in Western Europe (Bethlehem, Pa., 1993), pp. 131–134.
For the significance of chemical analysis, and chemical analysts, see James Donnelly, `Structural locations for chemists in the British alkali industry, 1850–1920’, this volume.
Heinrich Caro, Great Britain patent no. 786 of February 1878, and German patent no. 5,411 of 12 March 1878. For a comprehensive early history of azo dyes see H. Caro, `Veber die Entwickelung der Theerfarben-Industrie’, Berichte der Deutschen Chemischen Gesellschaft, 25 (1892), 955–1105.
P.A. Zimmermann, Patentwesen in der Chemie: Ursprünge, Anfänge, Entwicklung (Ludwigshafen, 1965, 1979), pp. 74–76.
Fox, op. cit. (13), pp. 18–20.
Heinrich Caro, German patent no. 10,785 of 28 December 1879.
There were 42 cartels, or syndicates, in Germany during 1887, and the number had grown to 77 at the end of 1889.
Heinrich Caro to BASF management, 15 December 1887. Management correspondence, BASF-Heinrich Caro, 1878–1908, reference C10, BASF Archives. Fox, op. cit. (13), p. 20, states that Levinstein arranged for manufacture of roccelline in Holland, but this was probably after the 1890 merger with AGFA and Bayer.
Carsten Reinhardt, `An instrument of corporate strategy: The Central Research Laboratory at BASF, 1868–1890’, this volume. Carsten Reinhardt is thanked for critical discussions that have been invaluable in the interpretation of the Caro correspondence discussed here.
Leonhardt was mentioned in connection with naphthol yellow, and Geigy of Basle in connection with methylene blue and auramine.
Levinstein’s patents for nitroso-alpha-naphthol mono and disulphonic acids, Great Britain no. 5,692 of 30 November 1882, United States no. 28,9543 of 4 December 1883.
This is an excellent example of the tension between private and public knowledge, especially at critical moments in the history of a company, discussed further by James Donnelly in this volume.
Ernst F. Ehrhardt, `Badische v. Dawson’, statement of the case dated 20 May 1889. Management correspondence, BASF-Heinrich Caro, 1878–1908, reference C10, BASF Archives.
Theodore Aston Co., Lincoln’s Inn, London (writing from the Royal Courts of Justice), to Caro, 26 May 1889, uncatalogued item, reference N93, SSDM.
Levinstein to Caro, 7 June 1889, reference 1977/32/191/3, SSDM. German in the original.
Levinstein to Caro, 1889, item no. 1977/32/191/5, SSDM. German in the original.
Reinhardt, op. cit. (22).
Verg et al., op. cit. (31), pp. 118–120.
See van den Belt, and Rip, op. cit. (8). This otherwise highly readable account relies on Carl Duisberg’s, Meine Lebenserinnerungen (Leipzig, 1933), p. 44, which does not give Caro credit for introducing this aspect of novelty, instead of Duisberg’s obituary note, `Heinrich Caro’, Zeitschrift für Angewandte Chemie, 23 (1911), 1057–1058, which does.
O.N. Witt, Chemische Homologie und Isomeric in ihrem Einflusse aufE findungen aus dem Gebiete der organischen Chemie. Eine Patentrechlichte Studie vom Standpunkte des Chemikers (Berlin, 1889).
Caro to Meldola, 8 June 1886, Geissler page no. 86a.
Duisberg (1911), op. cit. (33), pp. 1057–1058.
Duisberg (1933), op. cit. (33), p.44.
Fleischer, op. cit. (6), pp. 142–147.
Levinstein to Caro, 5 July 1889, reference 1977/32/191/2, SSDM. German in the original.
Some of these patents correspond to marketed dyes: 28753/84 is Congo red (Böttiger), 39096/85 is Congo Corinth, and 41095/87 is Brilliant Congo G.
Fox, op. cit. (13), p. 20.
`Sectional Committees of the Chambers of Commerce, December 1889’, Journal of the Society of Chemical Industry, 7 (1889), 962–965, esp. pp. 963–964.
Caro to Levinstein, 16 January 1890, Geissler page no. 150. German in the original.
Levinstein to Caro, 29 January 1890, reference 1977/32/191/6, SSDM. German in the original.
“ Caro to Levinstein, 4 February 1890. Geissler page no. 151. German in the original.
Levinstein, op. cit. (9), p. 272.
Levinstein’s tone in his Douglas Lecture was influenced by the considerable anti-German feeling in Britain at the end of the 1940s.
‘P. Reed, ’The British chemical industry and the indigo trade’, British Journal for the History of Science, 25 (1992), 113–125, esp. pp. 116–118.
L.F. Haber, The Chemical Industry during the Nineteenth Century: A Study of the Economic Aspect of Applied Chemistry in Europe and North America (Oxford, 1958), p. 200.
It is worth noting that fast red is still in extensive use as a textile colorant. Production of benzidine dyes declined from the 1960s, following conclusive evidence that their manufacture was linked with bladder cancer.
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Travis, A.S. (1998). Heinrich Caro and Ivan Levinstein. In: Homburg, E., Travis, A.S., Schröter, H.G. (eds) The Chemical Industry in Europe, 1850–1914. Chemists and Chemistry, vol 17. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-3253-6_15
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