Abstract
Environmental data is generally expected to be lognormally distributed and hence the logarithmetic transformation of the data has been used to calculate effluent limits in various regulatory programs (E.P.A., 1987). The choice of a distribution to characterize a set of data is a common cause of subjective bias and a wrong choice of distribution could lead to improper effluent limits. The problem becomes more acute when some of the data are below the laboratory detection limit (DL) leading to censoring of data. This study is concerned with the case where the square root transformation of the data is more appropriate than the logarithmetic transformation for setting effluent limits. The maximum likelihood estimator of the mean of the raw data is unbiased and is shown to have smaller mean square error than the estimator obtained by transforming back using the parameters of the corresponding distribution. For the estimation of the 99-th percentile, the maximum likelihood estimator, the estimator obtained by transforming back and the unbiased estimator are compared. The 95-th percentile of the mean of four observations is based on the 95-th percentile of a noncentral distribution with four degrees of freedom. When some of the data are below the laboratory detection limit, simulation is used to calculate the 95-th percentile of the mean of four observations. Using Ontario’s Municipal/Industrial Strategy for Abatement (MISA) data, methods of this paper are compared with United States Environmental Protection Agency (EPA) methods, the methods of El-Shaarawi and Dolan for censored data (1989), and methods based on estimation of parameters by probability plots.
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References
El-Shaarawi, A.H. and Dolan, D.M. (1989) “Maximum Likelihood Estimation of Water Quality Concentrations from Censored Data”, Canadian Journal of Fisheries and Aquatic Sciences, 46, 9, 1033–1039.
E.P.A. (1987) Development Document for Effluent Limitations Guidelines and Standards for the Organic Chemicals, Plastics and Synthetic Fibres. Point Source Category. Vol 1 and 2, 2 PB88–171335. National Technical Information Service. Springfield, VA 22161, U.S.A.
Lindgren, B.W., (1976) Statistical Theory, Macmillan Publishing Co., Inc., New York.
MOE (1988) “MISA Effluent Monitoring Regulations for the Petroleum Refining Sector, Ontario Ministry of the Environment”, Queen’s Printer for Ontario. Toronto.
Nielson, K.K and Rogers, V.C. (1989) “Statistical Estimation of Analytical Data Distributions and Censored Measurements”; Anal. Chem., 61, 2719–2724.
Shumway, R.H., Azari, A.S, and Johnson, P. (1989) “Estimating Mean Concentrations Under Transformation for Environmental Data With Detection Limits”, Technometrics, 31, 3, 347–356.
Srivastava, M.S. and Carter, E.M. (1983) An Introduction to Applied Multivariate Statistics, North Holland, New York.
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© 1994 Springer Science+Business Media Dordrecht
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Selliah, J., Sharma, A. (1994). Square Root Transformation of Data in an Effluent Limit Setting Program. In: Hipel, K.W., Fang, L. (eds) Stochastic and Statistical Methods in Hydrology and Environmental Engineering. Water Science and Technology Library, vol 10/2. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-3081-5_10
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DOI: https://doi.org/10.1007/978-94-017-3081-5_10
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-4380-1
Online ISBN: 978-94-017-3081-5
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