Skip to main content

Elongational Rheometers

  • Chapter

Abstract

The study of the elongational or extensional flow of polymeric fluids has been the subject of intense research for most of the last two decades. Continuing interest in this area stems from the fact that several industrially important polymer processing operations such as fibre spinning, blow moulding, flat film extrusion and film blowing involve a predominantly extensional mode of deformation. This flow field is also highly effective in orienting polymer molecules in the flow direction, and the high deformation rates which typically occur in industrial operations, albeit for a short duration, result in the presence of unusually large fluid stresses; the theoretical prediction of these stresses is an unsolved issue which represents an intellectual challenge to every rheologist.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Abbreviations

A 0 :

cross-sectional area of nozzle exit in eqns (8.18) and (8.19)

a 1 to a 5 :

constants in eqn (8.17)

D :

diameter

F :

force (used with various subscripts)

g :

acceleration due to gravity

l :

sample length

L :

capillary length

L 0 :

initial length in eqn (8.7)

l, l 0 :

sample length at time t and t = 0

n :

power law index

P Ent :

entrance pressure drop

P 0, P x :

pressures in viscometer before and after stretching in eqns (8.20) and (8.21)

Q :

volumetric flow rate

Q 0,Q 1 :

volumetric flow rate without stretching and with stretching in eqns (8.20) and (8.21) r radius

R :

capillary radius

T r :

Trouton ratio

v 1,v 2, v 3 :

flow velocity components

V 0 :

average flow velocity at nozzle exit in eqn (8.19)

x 1, x 2, x 3 :

coordinate directions, with flow in x x direction

γ :

surface tension

γ̇ A :

apparent shear rate

ε̇ :

tensile strain rate

ε̇ E :

net average extension rate

η E :

tensile viscosity

η + E :

tensile stress growth coefficient

η :

shear viscosity

ρ :

polymer density

σ :

total stress tensor

σ 11 :

total stress at x

σ E :

net average extensional stress

τ :

extra stress tensor

τ 22τ 22 :

first normal stress difference

References

  1. J. W. Hill and J. A. Cuculo, J. Macromol. Sc., Rev. Macromol. Chem., 1976, C14, 107.

    Article  Google Scholar 

  2. C. J. S. Petrie, Elongational Flows, Pitman, London, 1979.

    Google Scholar 

  3. D. C. Bogue, Tensile Viscosity: a review, Polymer Science and Engineering report No. 123, University of Tennessee, Knoxville, 1978.

    Google Scholar 

  4. J. M. Dealy, J. Non—Newt. Fluid Mech., 1978, 4, 9.

    Article  CAS  Google Scholar 

  5. J. L. White, J. Appl. Polym. Sci., Appl. Polym. Symp., 1978, 33, 31.

    CAS  Google Scholar 

  6. F. N. Cogswell, J. Non—Newt. Fluid Mech., 1978, 4, 23.

    Article  CAS  Google Scholar 

  7. J. L. White, Polym. Eng. Rev., 1981, 1, 297.

    CAS  Google Scholar 

  8. J. M. Dealy, Rheometers for Molten Plastics, Van Nostrand Reinhold, New York, 1982.

    Book  Google Scholar 

  9. J. Meissner, Chem. Eng. Comm., 1985, 33, 159.

    Article  CAS  Google Scholar 

  10. F. T. Trouton, Proc. Roy. Soc. (Lond.), 1906, A77, 426.

    Article  Google Scholar 

  11. K. Walters, Rheometry, Chapman and Hall, London, 1975.

    Google Scholar 

  12. J. M. Dealy, Polym. Eng. Sci., 1971, 11, 433.

    Article  CAS  Google Scholar 

  13. R. L. Ballman, Rheol. Acta, 1965, 4, 137.

    Article  CAS  Google Scholar 

  14. J. F. Stevenson, A.I.Ch.E.J., 1972, 18, 540.

    Article  CAS  Google Scholar 

  15. G. V. Vinogradov, B. V. Radushkevich and V. D. Fikhman, J. Polym. Sci. (A2), 1970, 8, 1.

    Article  CAS  Google Scholar 

  16. J. Rhi-Sausi and J. M. Dealy, Polym. Eng. Sci., 1976, 16, 799.

    Article  CAS  Google Scholar 

  17. P. K. Agrawal, W. -K. Lee, J. M. Lorntson, C. I. Richardson, K. F. Wissbrun and A. B. Metzner, Trans. Soc. Rheol., 1977, 21, 355.

    Article  CAS  Google Scholar 

  18. F. N. Cogswell, Plast. and Polym., 1968, 36, 109.

    CAS  Google Scholar 

  19. J. M. Dealy, R. Farber, J. Rhi-Sausi and L. Utracki, Trans. Soc. Rheol., 1976, 20, 455.

    Article  Google Scholar 

  20. G. V. Vinogradov, V. D. Fikhman and B. V. Radushkevich, Rheol. Acta, 1972, 11, 286.

    Article  CAS  Google Scholar 

  21. H. Munstedt, Rheol. Acta, 1975, 14, 1077.

    Article  Google Scholar 

  22. H. Mundstedt, J. Rheol., 1979, 23, 421.

    Article  Google Scholar 

  23. J. Meissner, Rheol. Acta, 1969, 8, 78.

    Article  CAS  Google Scholar 

  24. J. Meissner, T. Raible and S. E. Stephenson, J. Rheol., 1981, 25, 1.

    Article  CAS  Google Scholar 

  25. J. Meissner, Trans. Soc. Rheol., 1972, 16, 405.

    Article  CAS  Google Scholar 

  26. J. Meissner, Ann. Rev. Fluid Mech., 1985, 17, 45.

    Article  Google Scholar 

  27. O. Ishizuka and K. Koyama, Polymer, 1980, 21, 164.

    Article  CAS  Google Scholar 

  28. Y. Ide and J. L. White, J. Appl. Polym. Sci., 1978, 22, 1061.

    Article  CAS  Google Scholar 

  29. C. W. Macosko and J. M. Lorntson, Soc. Plast. Eng. Tech. Pap., 1973, 19, 461.

    CAS  Google Scholar 

  30. A. E. Everage and R. L. Ballman, J. Appl. Polym. Sci., 1976, 20, 1137.

    Article  CAS  Google Scholar 

  31. R. W. Connelly, L. G. Garfield and G. H. Pearson, J. Rheol., 1979, 23, 651.

    Article  CAS  Google Scholar 

  32. T. Matsumoto and D. C. Bogue, Trans. Soc. Rheol., 1977, 21, 453.

    Article  CAS  Google Scholar 

  33. J. Meissner, Pure and Appl. Chem., 1975, 42, 553.

    Article  Google Scholar 

  34. H. M. Laun and H. Munstedt, Rheol. Acta, 1976, 15, 517.

    Article  CAS  Google Scholar 

  35. H. M. Laun and H. Munstedt, Rheol. Acta, 1978, 17, 415.

    Article  CAS  Google Scholar 

  36. H. Munstedt and H. M. Laun, Rheol. Acta, 1979, 18, 492.

    Article  Google Scholar 

  37. H. Munstedt, J. Rheol., 1980, 24, 847.

    Article  Google Scholar 

  38. H. Munstedt and H. M. Laun, Rheol. Acta, 1981, 20, 211.

    Article  Google Scholar 

  39. T. Raible, A. Demarels and J. Meissner, Polym. Bull., 1979, 1, 397.

    Article  CAS  Google Scholar 

  40. R. B. Bird, R. C. Armstrong and O. Hassager, Dynamics of Polymeric Liquids, Vol. 1, Wiley, New York, 1977.

    Google Scholar 

  41. W. R. Schowalter, Mechanics of Non—Newtonian Fluids, Pergamon Press, Oxford, 1978.

    Google Scholar 

  42. R. I. Tanner, Engineering Rheology, Clarendon Press, Oxford, 1985.

    Google Scholar 

  43. R. B. Bird, Chem. Eng. Comm., 1982, 16, 175.

    Article  CAS  Google Scholar 

  44. A. Ziabicki, Fundamentals of Fibre Formation, Wiley, London, 1976.

    Google Scholar 

  45. Z. K. Walczak, Formation of Synthetic Fibres, Gordon and Breach, New York, 1977.

    Google Scholar 

  46. M. M. Denn, Ann. Rev. Fluid Mech., 1980, 12, 365.

    Article  CAS  Google Scholar 

  47. A. Ziabicki and H. Kawai (Eds), High Speed Fiber Spinning, Wiley, New York, 1985.

    Google Scholar 

  48. E. F. Matthys and M. Khatami, Paper presented at Winter Meeting of Society of Rheology, Santa Monica, California, 1987.

    Google Scholar 

  49. J. A. Spearot and A. B. Metzner, Trans. Soc. Rheol., 1972, 16, 495.

    Article  CAS  Google Scholar 

  50. M. A. Matovich and J. R. A. Pearson, Ind. Eng. Chem. Fund., 1969, 8, 512.

    Article  CAS  Google Scholar 

  51. N. Phan-Thien and B. Caswell, J. Non—Newt. Fluid Mech., 1986, 21, 225.

    Article  Google Scholar 

  52. M. M. Denn, in Computational Analysis of Polymer Processing, J. R. A. Pearson and S. M. Richardson (Eds), Applied Science, London, 1983, p. 179.

    Chapter  Google Scholar 

  53. C. D. Han, Rheology in Polymer Processing, Academic Press, New York, 1976.

    Google Scholar 

  54. C. D. Han, Multiphase Flow in Polymer Processing, Academic Press, New York, 1981.

    Google Scholar 

  55. F. N. Cogswell, Polym. Eng. Sci., 1972, 12, 64.

    Article  CAS  Google Scholar 

  56. F. N. Cogswell, Trans. Soc. Rheol., 1972, 16, 383.

    Article  CAS  Google Scholar 

  57. A. E. Everage and R. L. Ballman, Nature, 1978, 273, 213.

    Article  CAS  Google Scholar 

  58. E. D. Johnson and S. Middleman, Polym. Eng. Sci., 1978, 18, 963.

    Article  CAS  Google Scholar 

  59. H. Munstedt and S. Middleman, J. Rheol., 1981, 25, 29.

    Article  Google Scholar 

  60. T. Takaki and D. C. Bogue, J. Appl. Polym. Sci., 1975, 19, 419.

    Article  CAS  Google Scholar 

  61. H. Nitschmann and J. Schrade, Helv. Chim. Acta, 1948, 31, 297.

    Article  CAS  Google Scholar 

  62. M. Zidan, Rheol. Acta, 1969, 8, 89.

    Article  CAS  Google Scholar 

  63. C. B. Weinberger and J. D. Goddard, Int. J. Multiphase Flow, 1974, 1, 465.

    Article  Google Scholar 

  64. K. M. Baid and A. B. Metzner, Trans. Soc. Rheol., 1977, 21, 237.

    Article  CAS  Google Scholar 

  65. N. E. Hudson, J. Ferguson and P. Mackie, Trans. Soc. Rheol., 1974, 18, 541.

    Article  CAS  Google Scholar 

  66. J. Ferguson and N. E. Hudson, J. Phys. (E), 1975, 8, 526.

    CAS  Google Scholar 

  67. M. Khagram, R. K. Gupta and T. Sridhar, J. Rheol., 1985, 29, 191.

    Article  CAS  Google Scholar 

  68. R. Bragg and D. R. Oliver, Nature Phys. Sci., 1973, 241, 131.

    Article  CAS  Google Scholar 

  69. D. R. Oliver and R. Bragg, Rheol. Acta, 1974, 13, 830.

    Article  Google Scholar 

  70. G. Astarita and L. Nicodemo, Chem. Eng. J., 1970, 1, 57.

    Article  Google Scholar 

  71. T. Sridhar and R. K. Gupta, Rheol. Acta, 1985, 24, 207.

    Article  CAS  Google Scholar 

  72. J. Mewis and A. B. Metzner, J. Fluid Mech., 1974, 62, 593.

    Article  Google Scholar 

  73. C. A. Moore and J. R. A. Pearson, Rheol. Acta, 1975, 14, 436.

    Article  Google Scholar 

  74. J. C. Chang and M. M. Denn, J. Non—Newt. Fluid Mech., 1979, 5, 369.

    Article  CAS  Google Scholar 

  75. N. E. Hudson and J. Ferguson, Trans. Soc. Rheol., 1976, 20, 265.

    Article  CAS  Google Scholar 

  76. G. R. McKay, J. Ferguson and N. E. Hudson, J. Non—Newt. Fluid Mech., 1978, 4, 89.

    Article  CAS  Google Scholar 

  77. A. B. Metzner and G. Prilutski, J. Rheol., 1986, 30, 661.

    Article  CAS  Google Scholar 

  78. M. L. Becraft and A. B. Metzner, J. Rheol., in Press 1987.

    Google Scholar 

  79. T. Sridhar, R. K. Gupta, D. V. Boger and R. J. Binnington, J. Non—Newt. Fluid Mech., 1986,21, 115.

    Article  CAS  Google Scholar 

  80. D. R. Oliver, Chem. Eng. J., 1975, 9, 255.

    Article  CAS  Google Scholar 

  81. D. R. Oliver and R. C. Ashton, J. Non—Newt. Fluid Mech., 1976, 1, 93.

    Article  CAS  Google Scholar 

  82. D. Acierno, G. Titomanlio and L. Nicodemo, Rheol. Acta, 1974, 13, 532.

    Article  Google Scholar 

  83. D. Acierno, G. Titomanlio and R. Greco, Chem. Eng. Sci., 1974, 29, 1739.

    Article  CAS  Google Scholar 

  84. L. Nicodemo, B. De Cindio and L. Nicolais, Polym. Eng. Sci., 1975, 25, 679.

    Article  Google Scholar 

  85. S. T. J. Peng and R. F. Landel, J. Appl. Phys., 1976, 47, 4225.

    Article  Google Scholar 

  86. R. T. Balmer and D. J. Hochschild, J. Rheol., 1978, 22, 165.

    Article  Google Scholar 

  87. W. C. MacSporran, J. Non—Newt. Fluid Mech., 1981, 8, 119.

    Article  CAS  Google Scholar 

  88. F. D. Martischius, Rheol. Acta, 1982, 21, 288.

    Article  CAS  Google Scholar 

  89. Y. Demay and J. F. Agassant, J. Non—Newt. Fluid Mech., 1985, 18, 187.

    Article  CAS  Google Scholar 

  90. J. Mewis and G. De Cleyn, A.I.Ch.E.J., 1982, 28, 900.

    Article  CAS  Google Scholar 

  91. R. C. Chan, PhD dissertation, State University of New York at Buffalo, 1988.

    Google Scholar 

  92. D. V. Boger, R. K. Gupta and R. I. Tanner, J. Non—Newt. Fluid Mech., 1978, 4, 239.

    Article  Google Scholar 

  93. J. P. Tordella, Trans. Soc. Rheol., 1957, 1, 203.

    Article  CAS  Google Scholar 

  94. A. B. Metzner and A. P. Metzner, Rheol. Acta, 1970, 9, 174.

    Article  CAS  Google Scholar 

  95. T. E. Kizior and F. A. Seyer, Trans. Soc. Rheol., 1974, 18, 271.

    Article  Google Scholar 

  96. C. Balakrishnan and R. J. Gordon, Proc. 7th Int. Congr. Rheol., Gothenburg, 1976, p. 265.

    Google Scholar 

  97. H. N. Nguyen, PhD thesis, Monash University, Australia, 1978.

    Google Scholar 

  98. J. C. Hsu and R. W. Flummerfelt, Trans. Soc. Rheol., 1975, 19, 523.

    Article  Google Scholar 

  99. G. Pearson and S. Middleman, A.I.Ch.E.J., 1977, 23, 722.

    Article  CAS  Google Scholar 

  100. G. G. Fuller, C. A. Cathey, B. Hubbard and B. E. Zebrowski, J. Rheol., 1987, 31, 235.

    Article  CAS  Google Scholar 

  101. P. Schummer and K. H. Tebel, J. Non—Newt. Fluid Mech., 1983, 12, 331.

    Article  Google Scholar 

  102. D. F. James, Paper presented at Winter Meeting of Society of Rheology, Santa Monica, California, 1987.

    Google Scholar 

  103. K. P. Johnson, K. Walters and R. W. Williams, J. Non—Newt. Fluid Mech., 1984, 14, 173.

    Article  Google Scholar 

  104. R. Buscall, D. J. Bye and I. S. Miles, J. Non—Newt. Fluid Mech., 1985, 17, 193.

    Article  CAS  Google Scholar 

  105. G. K. Batchelor, J. Fluid Mech., 1971, 46, 813.

    Article  Google Scholar 

  106. D. V. Boger, J. Non—Newt. Fluid Mech., 1978, 3, 87.

    Article  Google Scholar 

  107. G. Prilutski, R. K. Gupta, T. Sridhar and M. E. Ryan, J. Non—Newt. Fluid Mech., 1983, 12, 233.

    Article  CAS  Google Scholar 

  108. T. Sridhar and R. K. Gupta, J. Non—Newt. Fluid Mech., in press 1988.

    Google Scholar 

  109. T. Sridhar and R. K. Gupta, Proc. 4th Nat. Rheol. Conf, Adelaide, 1986, p. 185.

    Google Scholar 

  110. M. Doi, J. Polym. Sci., Polym. Phys. Ed., 1980, 18, 1005.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Gupta, R.K., Sridhar, T. (1993). Elongational Rheometers. In: Collyer, A.A., Clegg, D.W. (eds) Rheological Measurement. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2898-0_8

Download citation

  • DOI: https://doi.org/10.1007/978-94-017-2898-0_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-017-2900-0

  • Online ISBN: 978-94-017-2898-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics