Abstract
The study of the elongational or extensional flow of polymeric fluids has been the subject of intense research for most of the last two decades. Continuing interest in this area stems from the fact that several industrially important polymer processing operations such as fibre spinning, blow moulding, flat film extrusion and film blowing involve a predominantly extensional mode of deformation. This flow field is also highly effective in orienting polymer molecules in the flow direction, and the high deformation rates which typically occur in industrial operations, albeit for a short duration, result in the presence of unusually large fluid stresses; the theoretical prediction of these stresses is an unsolved issue which represents an intellectual challenge to every rheologist.
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Abbreviations
- A 0 :
-
cross-sectional area of nozzle exit in eqns (8.18) and (8.19)
- a 1 to a 5 :
-
constants in eqn (8.17)
- D :
-
diameter
- F :
-
force (used with various subscripts)
- g :
-
acceleration due to gravity
- l :
-
sample length
- L :
-
capillary length
- L 0 :
-
initial length in eqn (8.7)
- l, l 0 :
-
sample length at time t and t = 0
- n :
-
power law index
- P Ent :
-
entrance pressure drop
- P 0, P x :
-
pressures in viscometer before and after stretching in eqns (8.20) and (8.21)
- Q :
-
volumetric flow rate
- Q 0,Q 1 :
-
volumetric flow rate without stretching and with stretching in eqns (8.20) and (8.21) r radius
- R :
-
capillary radius
- T r :
-
Trouton ratio
- v 1,v 2, v 3 :
-
flow velocity components
- V 0 :
-
average flow velocity at nozzle exit in eqn (8.19)
- x 1, x 2, x 3 :
-
coordinate directions, with flow in x x direction
- γ :
-
surface tension
- γ̇ A :
-
apparent shear rate
- ε̇ :
-
tensile strain rate
- ε̇ E :
-
net average extension rate
- η E :
-
tensile viscosity
- η + E :
-
tensile stress growth coefficient
- η :
-
shear viscosity
- ρ :
-
polymer density
- σ :
-
total stress tensor
- σ 11 :
-
total stress at x
- σ E :
-
net average extensional stress
- τ :
-
extra stress tensor
- τ 22 — τ 22 :
-
first normal stress difference
References
J. W. Hill and J. A. Cuculo, J. Macromol. Sc., Rev. Macromol. Chem., 1976, C14, 107.
C. J. S. Petrie, Elongational Flows, Pitman, London, 1979.
D. C. Bogue, Tensile Viscosity: a review, Polymer Science and Engineering report No. 123, University of Tennessee, Knoxville, 1978.
J. M. Dealy, J. Non—Newt. Fluid Mech., 1978, 4, 9.
J. L. White, J. Appl. Polym. Sci., Appl. Polym. Symp., 1978, 33, 31.
F. N. Cogswell, J. Non—Newt. Fluid Mech., 1978, 4, 23.
J. L. White, Polym. Eng. Rev., 1981, 1, 297.
J. M. Dealy, Rheometers for Molten Plastics, Van Nostrand Reinhold, New York, 1982.
J. Meissner, Chem. Eng. Comm., 1985, 33, 159.
F. T. Trouton, Proc. Roy. Soc. (Lond.), 1906, A77, 426.
K. Walters, Rheometry, Chapman and Hall, London, 1975.
J. M. Dealy, Polym. Eng. Sci., 1971, 11, 433.
R. L. Ballman, Rheol. Acta, 1965, 4, 137.
J. F. Stevenson, A.I.Ch.E.J., 1972, 18, 540.
G. V. Vinogradov, B. V. Radushkevich and V. D. Fikhman, J. Polym. Sci. (A2), 1970, 8, 1.
J. Rhi-Sausi and J. M. Dealy, Polym. Eng. Sci., 1976, 16, 799.
P. K. Agrawal, W. -K. Lee, J. M. Lorntson, C. I. Richardson, K. F. Wissbrun and A. B. Metzner, Trans. Soc. Rheol., 1977, 21, 355.
F. N. Cogswell, Plast. and Polym., 1968, 36, 109.
J. M. Dealy, R. Farber, J. Rhi-Sausi and L. Utracki, Trans. Soc. Rheol., 1976, 20, 455.
G. V. Vinogradov, V. D. Fikhman and B. V. Radushkevich, Rheol. Acta, 1972, 11, 286.
H. Munstedt, Rheol. Acta, 1975, 14, 1077.
H. Mundstedt, J. Rheol., 1979, 23, 421.
J. Meissner, Rheol. Acta, 1969, 8, 78.
J. Meissner, T. Raible and S. E. Stephenson, J. Rheol., 1981, 25, 1.
J. Meissner, Trans. Soc. Rheol., 1972, 16, 405.
J. Meissner, Ann. Rev. Fluid Mech., 1985, 17, 45.
O. Ishizuka and K. Koyama, Polymer, 1980, 21, 164.
Y. Ide and J. L. White, J. Appl. Polym. Sci., 1978, 22, 1061.
C. W. Macosko and J. M. Lorntson, Soc. Plast. Eng. Tech. Pap., 1973, 19, 461.
A. E. Everage and R. L. Ballman, J. Appl. Polym. Sci., 1976, 20, 1137.
R. W. Connelly, L. G. Garfield and G. H. Pearson, J. Rheol., 1979, 23, 651.
T. Matsumoto and D. C. Bogue, Trans. Soc. Rheol., 1977, 21, 453.
J. Meissner, Pure and Appl. Chem., 1975, 42, 553.
H. M. Laun and H. Munstedt, Rheol. Acta, 1976, 15, 517.
H. M. Laun and H. Munstedt, Rheol. Acta, 1978, 17, 415.
H. Munstedt and H. M. Laun, Rheol. Acta, 1979, 18, 492.
H. Munstedt, J. Rheol., 1980, 24, 847.
H. Munstedt and H. M. Laun, Rheol. Acta, 1981, 20, 211.
T. Raible, A. Demarels and J. Meissner, Polym. Bull., 1979, 1, 397.
R. B. Bird, R. C. Armstrong and O. Hassager, Dynamics of Polymeric Liquids, Vol. 1, Wiley, New York, 1977.
W. R. Schowalter, Mechanics of Non—Newtonian Fluids, Pergamon Press, Oxford, 1978.
R. I. Tanner, Engineering Rheology, Clarendon Press, Oxford, 1985.
R. B. Bird, Chem. Eng. Comm., 1982, 16, 175.
A. Ziabicki, Fundamentals of Fibre Formation, Wiley, London, 1976.
Z. K. Walczak, Formation of Synthetic Fibres, Gordon and Breach, New York, 1977.
M. M. Denn, Ann. Rev. Fluid Mech., 1980, 12, 365.
A. Ziabicki and H. Kawai (Eds), High Speed Fiber Spinning, Wiley, New York, 1985.
E. F. Matthys and M. Khatami, Paper presented at Winter Meeting of Society of Rheology, Santa Monica, California, 1987.
J. A. Spearot and A. B. Metzner, Trans. Soc. Rheol., 1972, 16, 495.
M. A. Matovich and J. R. A. Pearson, Ind. Eng. Chem. Fund., 1969, 8, 512.
N. Phan-Thien and B. Caswell, J. Non—Newt. Fluid Mech., 1986, 21, 225.
M. M. Denn, in Computational Analysis of Polymer Processing, J. R. A. Pearson and S. M. Richardson (Eds), Applied Science, London, 1983, p. 179.
C. D. Han, Rheology in Polymer Processing, Academic Press, New York, 1976.
C. D. Han, Multiphase Flow in Polymer Processing, Academic Press, New York, 1981.
F. N. Cogswell, Polym. Eng. Sci., 1972, 12, 64.
F. N. Cogswell, Trans. Soc. Rheol., 1972, 16, 383.
A. E. Everage and R. L. Ballman, Nature, 1978, 273, 213.
E. D. Johnson and S. Middleman, Polym. Eng. Sci., 1978, 18, 963.
H. Munstedt and S. Middleman, J. Rheol., 1981, 25, 29.
T. Takaki and D. C. Bogue, J. Appl. Polym. Sci., 1975, 19, 419.
H. Nitschmann and J. Schrade, Helv. Chim. Acta, 1948, 31, 297.
M. Zidan, Rheol. Acta, 1969, 8, 89.
C. B. Weinberger and J. D. Goddard, Int. J. Multiphase Flow, 1974, 1, 465.
K. M. Baid and A. B. Metzner, Trans. Soc. Rheol., 1977, 21, 237.
N. E. Hudson, J. Ferguson and P. Mackie, Trans. Soc. Rheol., 1974, 18, 541.
J. Ferguson and N. E. Hudson, J. Phys. (E), 1975, 8, 526.
M. Khagram, R. K. Gupta and T. Sridhar, J. Rheol., 1985, 29, 191.
R. Bragg and D. R. Oliver, Nature Phys. Sci., 1973, 241, 131.
D. R. Oliver and R. Bragg, Rheol. Acta, 1974, 13, 830.
G. Astarita and L. Nicodemo, Chem. Eng. J., 1970, 1, 57.
T. Sridhar and R. K. Gupta, Rheol. Acta, 1985, 24, 207.
J. Mewis and A. B. Metzner, J. Fluid Mech., 1974, 62, 593.
C. A. Moore and J. R. A. Pearson, Rheol. Acta, 1975, 14, 436.
J. C. Chang and M. M. Denn, J. Non—Newt. Fluid Mech., 1979, 5, 369.
N. E. Hudson and J. Ferguson, Trans. Soc. Rheol., 1976, 20, 265.
G. R. McKay, J. Ferguson and N. E. Hudson, J. Non—Newt. Fluid Mech., 1978, 4, 89.
A. B. Metzner and G. Prilutski, J. Rheol., 1986, 30, 661.
M. L. Becraft and A. B. Metzner, J. Rheol., in Press 1987.
T. Sridhar, R. K. Gupta, D. V. Boger and R. J. Binnington, J. Non—Newt. Fluid Mech., 1986,21, 115.
D. R. Oliver, Chem. Eng. J., 1975, 9, 255.
D. R. Oliver and R. C. Ashton, J. Non—Newt. Fluid Mech., 1976, 1, 93.
D. Acierno, G. Titomanlio and L. Nicodemo, Rheol. Acta, 1974, 13, 532.
D. Acierno, G. Titomanlio and R. Greco, Chem. Eng. Sci., 1974, 29, 1739.
L. Nicodemo, B. De Cindio and L. Nicolais, Polym. Eng. Sci., 1975, 25, 679.
S. T. J. Peng and R. F. Landel, J. Appl. Phys., 1976, 47, 4225.
R. T. Balmer and D. J. Hochschild, J. Rheol., 1978, 22, 165.
W. C. MacSporran, J. Non—Newt. Fluid Mech., 1981, 8, 119.
F. D. Martischius, Rheol. Acta, 1982, 21, 288.
Y. Demay and J. F. Agassant, J. Non—Newt. Fluid Mech., 1985, 18, 187.
J. Mewis and G. De Cleyn, A.I.Ch.E.J., 1982, 28, 900.
R. C. Chan, PhD dissertation, State University of New York at Buffalo, 1988.
D. V. Boger, R. K. Gupta and R. I. Tanner, J. Non—Newt. Fluid Mech., 1978, 4, 239.
J. P. Tordella, Trans. Soc. Rheol., 1957, 1, 203.
A. B. Metzner and A. P. Metzner, Rheol. Acta, 1970, 9, 174.
T. E. Kizior and F. A. Seyer, Trans. Soc. Rheol., 1974, 18, 271.
C. Balakrishnan and R. J. Gordon, Proc. 7th Int. Congr. Rheol., Gothenburg, 1976, p. 265.
H. N. Nguyen, PhD thesis, Monash University, Australia, 1978.
J. C. Hsu and R. W. Flummerfelt, Trans. Soc. Rheol., 1975, 19, 523.
G. Pearson and S. Middleman, A.I.Ch.E.J., 1977, 23, 722.
G. G. Fuller, C. A. Cathey, B. Hubbard and B. E. Zebrowski, J. Rheol., 1987, 31, 235.
P. Schummer and K. H. Tebel, J. Non—Newt. Fluid Mech., 1983, 12, 331.
D. F. James, Paper presented at Winter Meeting of Society of Rheology, Santa Monica, California, 1987.
K. P. Johnson, K. Walters and R. W. Williams, J. Non—Newt. Fluid Mech., 1984, 14, 173.
R. Buscall, D. J. Bye and I. S. Miles, J. Non—Newt. Fluid Mech., 1985, 17, 193.
G. K. Batchelor, J. Fluid Mech., 1971, 46, 813.
D. V. Boger, J. Non—Newt. Fluid Mech., 1978, 3, 87.
G. Prilutski, R. K. Gupta, T. Sridhar and M. E. Ryan, J. Non—Newt. Fluid Mech., 1983, 12, 233.
T. Sridhar and R. K. Gupta, J. Non—Newt. Fluid Mech., in press 1988.
T. Sridhar and R. K. Gupta, Proc. 4th Nat. Rheol. Conf, Adelaide, 1986, p. 185.
M. Doi, J. Polym. Sci., Polym. Phys. Ed., 1980, 18, 1005.
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Gupta, R.K., Sridhar, T. (1993). Elongational Rheometers. In: Collyer, A.A., Clegg, D.W. (eds) Rheological Measurement. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2898-0_8
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