Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds pp 51-69 | Cite as
Photocatalysis: Definitions and Classifications
- 4 Citations
- 296 Downloads
Abstract
The photosynthesis of the green plants may be regarded as the greatest chemical factory on the earth. More than 2·1014 tons of organic material are produced every year by consuming of more than 2·1018 kJ of photonic energy. That means, more raw material is produced in this way than it is achieved by any human activities like mining or large-scale chemical industry. On the other hand, the classical photographic process based on light-sensitive silver halides may be considered as an impressive example in using photons in artificial manner. Since Schulze’s detection of the light-sensitivity of silver compounds more than 250 years ago, it was a fascinating way to the Daguerreotypes and finally to todays color photography. Both, the photosynthesis and the silver halide photography have unambiguously to do with the topics of this chapter: Both are kept going or initiated by light and they are catalytic with respect to chemical substrate conversions.
Keywords
Quantum Yield Active Species Transition Metal Complex Photocatalytic Reaction Organometallic CompoundPreview
Unable to display preview. Download preview PDF.
References
- 1.W. Ostwald: Die Mühle des Lebens, Thomas, Leipzig (1911).Google Scholar
- 2.V. Plotkinow: Lehrbuch der Allgemeinen Photochemie, de Gruyter, Leipzig (1920).Google Scholar
- 3.V. Balzani, F. Bolletta, M. Ciano, and M. Maestri: J. Chem. Educ. 60, 447 (1983).CrossRefGoogle Scholar
- 4.H. Hennig, P. Thomas, R. Wagener, D. Rehorek, and K. Jurdeczka: Z. Chem. 17, 241 (1977).CrossRefGoogle Scholar
- 5.H. Hennig, D. Rehorek, and R.D. Archer: Coord. Chem. Rev. 61, 1 (1985).CrossRefGoogle Scholar
- 6.H. Hennig and D. Rehorek: Excited States and Reactive Intermediates (ed. A.B.P.Lever), p. 104, American Chemical Society, Washington (1985).Google Scholar
- 7.H. Hennig, D. Rehorek, and R. Billing: Coordination Chemistry and Catalysis (ed. J.J.Ziolkowski), p. 421, World Scientific, Singapore (1988).Google Scholar
- 8.H. Hennig and D. Rehorek: Photochemische und photokatalytische Reaktionen von Koordinationsverbindungen, Teubner, Stuttgart (1988).Google Scholar
- 9.M.S. Wrighton, D.S. Ginley, M.A. Schroeder, and D.L. Morse: Pure Appl. Chem. 41, 671 (1975).CrossRefGoogle Scholar
- 10.L. Moggi, A. Juris, D. Sandrini, and M.F. Manfrin: Rev. Chem. Intermed. 4, 171 (1981); 5, 107 (1984).CrossRefGoogle Scholar
- 11.R.G. Salomon:Tetrahedron 39, 485 (1983).Google Scholar
- 12.C. Kutal: Coord. Chem. Rev. 64, 191 (1985).CrossRefGoogle Scholar
- 13.M.J. Mirbach: EPA Newslett. 20, 16 (1984).Google Scholar
- 14.V. Carassiti: EPA Newslett. 21, 12 (1984).Google Scholar
- 15.H. Kisch and H. Hennig: EPA Newslett. 19, 23 (1983).Google Scholar
- 16.E. Pelizzetti and N. Serpone (eds.): Photocatalysis, Wiley, New York (1989).Google Scholar
- 17.H. Kisch: in [16], p. 1.Google Scholar
- 18.F. Chanon and M. Chanon: in [16], p. 489.Google Scholar
- 19.H. Kisch and R. Künneth: Progress in Photochemistry and Photophysic s (ed. J.F.Rabek), Vol. IV, p. 131, CRC Press, Boca Raton (1990).Google Scholar
- 20.R. Billing, D. Rehorek, J. Salvetter, and H. Hennig: Z. anorg. allg. Chem. 557, 234 (1988).CrossRefGoogle Scholar
- 21.S.E. Braslaysky and K.N. Houk, Pure Appl.Chem. 60, 1055 (1988).CrossRefGoogle Scholar
- 22.R. Billing, D. Rehorek and H. Hennig: Topics Curr. Chem. 158, 151 (1990).CrossRefGoogle Scholar
- 23.G.G. Wubbels: Acc. Chem. Res. 16, 285 (1983).CrossRefGoogle Scholar
- 24.H. Hennig, E. Hoyer, E. Lippmann, E. Nagorsnik, P. Thomas, and M. Weissenfels: J. Inf. Rec. Mater. 6, 39 (1978).Google Scholar
- 25.H. Hennig, R. Stich, H. Knoll, and D. Rehorek: Z. anorg. allg. Chem. 576, 139 (1989).CrossRefGoogle Scholar
- 26.H. Knoll, R. Stich, H. Hennig, and D.J. Stufkens:Inorg. Chim. Acta 178 71 (1990).Google Scholar
- 27.H. Hennig, R. Stich, H. Knoll, D. Rehorek, D.J.Stufkens: Coord. Chem. Rev. 111, 131 (1991).Google Scholar
- 28.H. Hennig, D. Rehorek, R. Stich, and L. Weber: Pure Appl. Chem. 62, 1489 (1990).CrossRefGoogle Scholar
- 29.H. Hennig, P. Thomas, R. Wagener, M. Ackermann, R. Benedix, and D. Rehorek: J. Inf. Rec. Mater. 9, 269 (1981).Google Scholar
- 30.L. Weber, G. Haufe, D. Rehorek, and H. Hennig: J. Mol. Cat. 60, 267 (1990).CrossRefGoogle Scholar
- 31.L. Weber, G. Haufe, D. Rehorek, and H. Hennig: J. Chem. Soc. Chem. Commun. 1991, 502.Google Scholar
- 32.A. Hiskia and E. Papaconstantinou: Inorg. Chem. 31, 163 (1992).CrossRefGoogle Scholar
- 33.B.V. Koryakin, T.S. Tsabiev, and A.E. Shilov: Dokl. Akad. Nauk SSSR 229, 128 (1976).Google Scholar
- 34.R.G. Salomon: Adv. Chem. Ser. 168, 174 (1978).CrossRefGoogle Scholar
- 35.C. Kutal, C.K. Kelly and G. Ferraudi: Inorg. Chem. 26, 3258 (1987).CrossRefGoogle Scholar
- 36.N. Borsub and C. Kutal: J. Am. Chem. Soc. 106, 4826 (1984).CrossRefGoogle Scholar
- 37.See, e.g., H. Hennig, L. Weber, R. Stich, M. Grosche, and D. Rehorek: Progress in Photochemistry and Photophysics (ed. J.F. Rabek), Vol. VI, p. 167, CRC Press, Boca Raton (1992).Google Scholar
- 38.See, e.g., M.Grätzel (ed.): Energy Resources through Photochemistry and Catalysis, Academic Press, New York (1983).Google Scholar
- 39.See, e.g., H. Böttcher and J. Epperlein: Moderne Photographische Systeme, Verlag Grundstoffind., Leipzig (1988).Google Scholar
- 40.See, e.g., D.F. 011is, E. Pelizzetti, and N. Serpone: in [16], p. 603.Google Scholar
- 41.See, e.g., V. Balzani and F. Scandola: Supramolecular Photochemistry, Ellis Horwood, New York (1990).Google Scholar
- 42.D. Rehorek, H. Grikos, and R. Billing: Z.Chem. 30, 378 (1990).CrossRefGoogle Scholar
- 43.L. Weber, I. Imiolczyk, G. Haufe, D. Rehorek, and H. Hennig: J. Chem. Soc. Chem. Commun., 301 (1992)Google Scholar
- 44.H. Hennig, P. Scheibler, R. Wagener and D. Rehorek, Inorg. Chim. Acta, 44, L231 (1980)CrossRefGoogle Scholar
- 45.H. Hennig, P. Scheibler, R. Wagener and D. Rehorek, Z. Chem., 22, 30 (1982)CrossRefGoogle Scholar
- 46.H. Hennig, P. Scheibler, R. Wagener and D. Rehorek, J. Prakt. Chem., 324, 279 (1982).CrossRefGoogle Scholar