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Intermolecular Energy and Electron Transfer Processes

  • V. Balzani
  • M. Maestri
Chapter
Part of the Catalysis by Metal Complexes book series (CMCO, volume 14)

Abstract

The first act of any photochemical and photophysical process is the absorption of a photon by a molecule (equation (1)). The excited state that
$$A+hv\to*A$$
(1)
is formed in this way is a high energy, unstable species which must undergo some type of deactivation [1]. As shown in figure 1, excited state deactivation can occur via (i) disappearance of the original molecule and formation of products (photochemical reaction), (ii) emission of light (radiative deactivation, also called luminescence), (iii) degradation of excess energy into heat (nonradiative deactivation), and (iv) some type of interaction with other species present in the solution (quenching processes).

Keywords

Excited State Energy Transfer Electron Transfer Reaction Electron Transfer Process Photoinduced Electron Transfer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media Dordrecht 1993

Authors and Affiliations

  • V. Balzani
    • 1
  • M. Maestri
    • 1
  1. 1.“G. Ciamician” Chemistry DepartmentUniversity of BolognaBolognaItaly

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