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Electron Donor-Acceptor Interactions and Photo-Induced Electron Transfer of Organometallic Compounds

  • T. M. Bockman
  • J. K. Kochi
Chapter
Part of the Catalysis by Metal Complexes book series (CMCO, volume 14)

Abstract

An electron-transfer process is represented in its simplest form as
$$D\, + \,\,A\, \to \,D{ \cdot ^{ + \,\,}} + \,A{ \cdot ^ - }$$
(1)
in which an electron is transferred from the HOMO of the electron donor (D) to the LUMO of the electron acceptor (A) in one single (overall) process. [For simplicity, the electron donor and acceptor are written here as uncharged and diamagnetic, which is not always the case.] The formulation described in equation (1) does not, however, take into account the interaction between A and D over the diminished intermolecular distance in which the electron is transferred. The corresponding interactions between the products (A· and D·+) must also be considered in a more comprehensive account of the electron-transfer process. Accordingly, Scheme I depicts the interactions between donor and acceptor in terms of the precursor (electron donor-acceptor or EDA)

Keywords

Molecular Complex Photoinduced Electron Transfer Redox Pair Vertical Ionization Potential Donor Strength 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    R.S. Mulliken: Rec. Tray. Chim. 75, 845 (1956).Google Scholar
  2. 2.
    L.E. Orgel and R.S. Mulliken: J. Am. Chem. Soc. 79, 4839 (1957).CrossRefGoogle Scholar
  3. 3.
    R.S. Mulliken: J. Am. Chem. Soc. 74, 811, (1952).Google Scholar
  4. 4.
    G. Jones, II: Photoinduced Electron Transfer, Part A (eds. M.A. Fox and M. Chanon), p. 245, Elsevier, New York (1988).Google Scholar
  5. 5.
    G.L. Geoffroy and M.S. Wrighton: Organometallic Photochemistry, Academic, New York (1979).Google Scholar
  6. 6.
    J.K. Kochi: Organometallic Mechanisms and Catalysis, Academic, New York (1978).Google Scholar
  7. 7.
    N.G. Connelly and W.E. Geiger: Adv. Organometal. Chem. 23, 1, (1984).CrossRefGoogle Scholar
  8. 8.
    J.W. Herschberger and J.K. Kochi: Polyhedron 2, 929 (1983).Google Scholar
  9. 9.
    G.J. Leigh, R.H. Morris, C.J. Pickett, D.R. Stanley and J. Chatt: J. Chem. Soc. Dalton Trans., 800, (1981).Google Scholar
  10. 10.
    P. Hydes, J.A. McCleverty and D. G. Orchard: J. Chem. Soc. (A), 3660 (1971).Google Scholar
  11. 11.
    D.J. Kuchynka, C. Amatore and J.K. Kochi: Inorg. Chem. 25, 4087 (1986).CrossRefGoogle Scholar
  12. 12.
    A.E. Stiegman and D.R. Tyler: Comments Inorg. Chem. 5, 215 (1986).CrossRefGoogle Scholar
  13. 13.
    J.R. Hamon, D. Astruc and P. Michaud: J. Am. Chem. Soc. 103, 758 (1981).CrossRefGoogle Scholar
  14. 14.
    N. El Murr, J.E. Sheats, W. E. Geiger, Jr. and J.D.L. Holloway: Inorg. Chem. 18, 1443 (1979).CrossRefGoogle Scholar
  15. 15.
    C. Zou, K.J. Ahmed and M.S. Wrighton: J. Am. Chem. Soc. 111, 1133 (1989).CrossRefGoogle Scholar
  16. 16.
    M.J. Therien, C.L. Ni, F. Anson, J.G. Osteryoung and W.C. Trogler: J. Am. Chem. Soc. 108, 4037 (1986).CrossRefGoogle Scholar
  17. 17.
    B. Wassinck, M.J. Thomas, S.C. Wright, D.J. Gillis and M.C. Baird: J. Am. Chem. Soc. 109, 1995 (1987).Google Scholar
  18. 18.
    H. Yesaka, T. Kobayashi, K. Yasufuku and S. Nagakura: J. Am. Chem. Soc. 105, 6249 (1983).CrossRefGoogle Scholar
  19. 19.
    D.R. Kidd and T.L. Brown: J. Am. Chem. Soc. 100, 4095 (1978).CrossRefGoogle Scholar
  20. 20.
    A. Fox, J. Malito and A. Poe: J. Chem. Soc. Chem. Commun., 1052 (1981).Google Scholar
  21. 21.
    T.R. Herrinton and T.L. Brown: J. Am. Chem. Soc. 107, 5700 (1985).CrossRefGoogle Scholar
  22. 22.
    R.H. Magnuson, R. Meirowitz, S.J. Zulu and W.P. Giering: Organometallics 2, 460 (1983).CrossRefGoogle Scholar
  23. 23.
    K.M. Doxsee, R.H. Grubbs and F.C. Anson: J. Am. Chem. Soc. 106, 7819 (1984).CrossRefGoogle Scholar
  24. 24.
    J.K. Kochi: Angew. Chem. Int. Ed. Engl. 27, 1227 (1988).Google Scholar
  25. 25.
    C. Giannotti, S. Gaspard and P. Krausz: Photoinduced Electron Transfer Part 2 (eds. M.A. Fox and M. Chanon) p. 200, Elsevier, New York (1988).Google Scholar
  26. 26.
    A. Vogler and H. Kunkely: Top. Curr. Chem. 158, 1 (1990).CrossRefGoogle Scholar
  27. 27.
    J.K. Kochi: Acta Chem. Scand. 44, 409 (1990).Google Scholar
  28. 28.
    G. Bieri, F. Burger, E. Heilbronner and J.P. Maier: Heiv. Chim. Acta 60, 2213 (1977).CrossRefGoogle Scholar
  29. 29.
    H.C. Gardner and J.K. Kochi: J. Am. Chem. Soc. 97, 1855 (1975).CrossRefGoogle Scholar
  30. 30.
    H.C. Gardner and J.K. Kochi: J. Am. Chem. Soc. 98, 2460 (1976).CrossRefGoogle Scholar
  31. 31.
    R.J. Klingler, J.K. Kochi: J. Am. Chem. Soc. 103, 5839 (1981).CrossRefGoogle Scholar
  32. 32.
    D.K. Creber and G.M. Bancroft: Inorg. Chem. 19, 643 (1980).CrossRefGoogle Scholar
  33. 33.
    S. Fukuzumi and J.K. Kochi: J. Am. Chem. Soc. 102, 2141 (1980).CrossRefGoogle Scholar
  34. 34.
    J.C. Green, S.E. Jackson and B. Higginson: J. Chem. Soc. Dalton Trans., 403 (1975).Google Scholar
  35. 35.
    J.J. Ko, T.M. Bockman and J.K. Kochi: Organometallics 9, 1833 (1990).CrossRefGoogle Scholar
  36. 36.
    R.J. Klingler, J.C. Huffman and J.K. Kochi: J. Am. Chem. Soc. 102, 208 (1980).CrossRefGoogle Scholar
  37. 37.
    J.W. Rabalais, L.O. Werme, T. Bergmark, L. Karlsson, M. Hussain and K. Siegbahn: J. Chem. Phys. 57, 1185 (1972).CrossRefGoogle Scholar
  38. 38.
    S. Evans, J.C. Green, P.J. Joachim, A.F. Orchard, D.W. Turner and J.P. Maier: J. Chem. Soc. Faraday Trans. 2 68, 905 (1972).CrossRefGoogle Scholar
  39. 39.
    A.M. Stolzenberg and M.T. Stershic: J. Am. Chem. Soc. 110, 6391 (1988).CrossRefGoogle Scholar
  40. 40.
    J.C. Green: Struct. Bonding (Berlin) 43, 37 (1981).Google Scholar
  41. 41.
    T.A. Albright, J.K. Burdett and M.H. Whangbo: Orbital Interactions in Chemistry, Wiley, New York (1985).Google Scholar
  42. 42.
    C.A. Tolman: Chem. Soc. Rev. 1, 337 (1972).Google Scholar
  43. 43.
    N. Ito, T. Saji, K. Suga and S. Aoyagui: J. Organometal. Chem. 229, 43 (1982).Google Scholar
  44. 44.
    L.P. Yureva, S.M. Peregudova, L.N. Nekrasov, A.P. Korotkov, N.N. Zaitseva, N.V. Zakurin and A. Yu. Vasilkov: J. Organometal. Chem. 219, 43 (1981).CrossRefGoogle Scholar
  45. 45.
    J.O. Howell, J.M. Goncalves, C. Amatore, L. Klasinc, R.M. Wightman and J.K. Kochi: J. Am. Chem. Soc. 106, 3968 (1984).CrossRefGoogle Scholar
  46. 46.
    M.K. Lloyd, J.A. McCleverty, J.A. Connor and E.M. Jones: J. Chem. Soc. Dalton Trans., 1768 (1973).Google Scholar
  47. 47.
    S.P. Gubin and V.S. Khandkarova: J. Organometal. Chem. 22, 449 (1970).CrossRefGoogle Scholar
  48. 48.
    K.L. Amos and N.G. Connelly: J. Organometal. Chem. 194, C57 (1980).CrossRefGoogle Scholar
  49. 49.
    N.G. Connelly, Z. Demidowicz and R.L. Kelly: J. Chem. Soc. Dalton Trans., 2335 (1975).Google Scholar
  50. 50.
    H. Kobayashi, M. Kobayashi and Y. Kaizu: Bull. Chem. Soc. Jpn. 48, 1222 (1975).CrossRefGoogle Scholar
  51. 51.
    H. Kobayashi, M. Kobayashi and Y. Kaizu: Bull. Chem. Soc. Jpn. 46, 3109 (1973).CrossRefGoogle Scholar
  52. 52.
    H. Kobayashi, K. Kobayashi and Y. Kaizu: Inorg. Chem. 20, 4135 (1981).Google Scholar
  53. 53.
    B.R. Higginson, D.R. Lloyd, P. Burroughs, D.M. Gibson and A.F. Orchard: J. Chem. Soc. Faraday Trans. 2 69, 1659 (1973).CrossRefGoogle Scholar
  54. 54.
    D.R. Lloyd and E.W. Schlag: Inorg. Chem. 8, 2544 (1969).CrossRefGoogle Scholar
  55. 55.
    S. Evans, A.F. Orchard and D.W. Turner: Int. J. Mass. Spectrom. Ion Phys. 7, 261 (1971).CrossRefGoogle Scholar
  56. 56.
    A.T. Weibel and J.P. Oliver: J. Am. Chem. Soc. 94, 8590 (1972).CrossRefGoogle Scholar
  57. 57.
    G.W. Rice and R.S. Tobias: Inorg. Chem. 14, 2402 (1975).CrossRefGoogle Scholar
  58. 58.
    S. Chowdhury, T. Heinis, E.P. Grimsrud and P. Kebarle: J. Phys. Chem. 90, 2750 (1986).Google Scholar
  59. 59.
    J.A. Connor, E.M. Jones, G.A. McEwen, M.K. Lloyd, J.A. McCleverty: J. Chem. Soc. Dalton Trans., 1246 (1972).Google Scholar
  60. 60.
    B.E. Bursten: J. Am. Chem. Soc. 104, 1299 (1982).Google Scholar
  61. 61.
    J.A. McCleverty: Prog. Inorg. Chem. 10, 49 (1968).Google Scholar
  62. 62.
    D.B. Morse, D.N. Hendrickson, T.B. Rauchfuss and S.R. Wilson: Organometallics 7, 496 (1988).CrossRefGoogle Scholar
  63. 63.
    Y. Mugnier, C. Moise, J. Tirouflet and E. Laviron: J. Organometal. Chem. 186, C49 (1980).CrossRefGoogle Scholar
  64. 64.
    W.E. Geiger, Jr. and D. E. Smith: J. Electroanal. Chem. Interfac. Electrochem. 50, 31 (1974).CrossRefGoogle Scholar
  65. 65.
    Z.J. Karpinski and J.K. Kochi: J. Organometal. Chem.,in press (1992) for the mesitylene analogue.Google Scholar
  66. 66.
    C.J. Pickett, D. Pletcher: J. Chem. Soc. Dalton Trans., 636 (1976).Google Scholar
  67. 67.
    D. Astruc: Top. Curr. Chem. 160, 49 (1991).Google Scholar
  68. 68.
    G. Fairhurst and C. White: J. Chem. Soc. Dalton Trans., 1531 (1979).Google Scholar
  69. 69.
    U. Koelle, B. Fuss, M.V. Rajasekharan, B.L. Ramakrisna, J.H. Ammeter and M.C. Böhm: J. Am. Chem. Soc. 106, 4152 (1984).CrossRefGoogle Scholar
  70. 70.
    A.M. Bond and R. Colton: Inorg. Chem. 15, 2036 (1976).CrossRefGoogle Scholar
  71. 71.
    T. Madach and H. Vahrenkamp: Z. Naturforsch. 34b, 573 (1979).Google Scholar
  72. 72.
    D. Miholova and A.A. Vlcek: Inorg. Chim. Acta 41, 119 (1980).CrossRefGoogle Scholar
  73. 73.
    C.S. Ilenda, N.E. Schore and R.G. Bergman: J. Am. Chem. Soc. 98, 255 (1976).CrossRefGoogle Scholar
  74. 74.
    D.J. Kuchynka and J.K. Kochi: Inorg. Chem. 28, 855 (1989).CrossRefGoogle Scholar
  75. 75.
    K.Y. Lee, D. J. Kuchynka and J.K. Kochi: Organometallics 6, 1886 (1987).CrossRefGoogle Scholar
  76. 76.
    M.J.S. Dewar and A.R. Lepley: J. Am. Chem. Soc. 83, 4560 (1961).CrossRefGoogle Scholar
  77. 77.
    A.R. Lepley: J. Am. Chem. Soc. 84, 3577 (1962).Google Scholar
  78. 78.
    S.H. Hastings, J.L. Franklin, J.C. Schiller and F.A. Matsen: J. Am. Chem. Soc. 75, 2900 (1953).CrossRefGoogle Scholar
  79. 79.
    G. Briegleb and J. Czekalla: Z. Elektrochem. 63, 6 (1959).Google Scholar
  80. 80.
    H.A. Benesi and J.H. Hildebrand: J. Am. Chem. Soc. 71, 2703 (1949).CrossRefGoogle Scholar
  81. 81.
    W. Damerau: Z. Naturforsch. 21b, 937 (1966).Google Scholar
  82. 82.
    A. Zweig, J.E. Lehnsen, W.G. Hodgson, W.H. Jura: J. Am. Chem. Soc. 85, 3937 (1963).CrossRefGoogle Scholar
  83. 83.
    S. Iwata, J. Tanaka, and S. Nagakura: J. Am. Chem. Soc. 88, 894 (1966).CrossRefGoogle Scholar
  84. 84.
    M. Kinoshita: Bull. Chem. Soc. Jpn. 35, 1609 (1964).CrossRefGoogle Scholar
  85. 85.
    P.R. Hammond: J. Chem. Soc., 3113 (1963); 471 (1964).CrossRefGoogle Scholar
  86. 86.
    N. Mataga and T. Kubota: Molecular Interactions and Electronic Spectra, p. 219, Dekker, New York (1970).Google Scholar
  87. 87.
    P. Debye: Physik Z. 21, 178 (1920).Google Scholar
  88. 88.
    W.J. Duffin: Electricity and Magnetism, p. 79, McGraw Hill, New York (1973).Google Scholar
  89. 89.
    F. London: Trans. Faraday Soc. 33, 8 (1937).CrossRefGoogle Scholar
  90. 90.
    J.P. Fackler, T.S. Davis and I.D. Chawla: Inorg. Chem. 4, 130 (1965).CrossRefGoogle Scholar
  91. 91.
    S.O. Chan and D.R. Eaton: Can. J. Chem. 54, 1332 (1976).Google Scholar
  92. 92.
    V. Balzani, N. Sabbatini and F. Scandola: Chem. Rev. 86, 319 (1986).CrossRefGoogle Scholar
  93. 93.
    D.R. Eaton: Rev. Chem. Intermed. 9, 201 (1988).Google Scholar
  94. 94.
    V.M. Nekipelov and K.I. Zamaraev: Coord. Chem. Rev. 61, 185 (1985).CrossRefGoogle Scholar
  95. 95.
    M.T. Beck: Coord. Chem. Rev. 3, 91 (1968).Google Scholar
  96. 96.
    G.S. Vigee and C.L. Watkins: Inorg. Chem. 16, 709 (1977).CrossRefGoogle Scholar
  97. 97.
    K. Endo, I. Morishima and T. Yonezawa: J. Chem. Phys. 67, 4760 (1977).CrossRefGoogle Scholar
  98. 98.
    A.L. Buchachenko: Russ. Chem. Rev. 48, 1713 (1979).Google Scholar
  99. 99.
    K.I. Zamaraev and A.N. Kitaigorodskii: Coord. Chem. 6, 563 (1980).Google Scholar
  100. 100.
    D.R. Eaton and K.L. Chua: Can. J. Chem. 51, 4137 (1973).CrossRefGoogle Scholar
  101. 101.
    A.G. Stephanov, V.M. Nekipelov and K.I. Zamaraev: Dokl. Akad. Nauk. SSSR Ser. Khim. 274, 1144 (1984).Google Scholar
  102. 102.
    O.V. Nesterov, V.M. Nekipelov, Yu. N. Chirkov, A.N. Kitaigorodskii and S.G. Entelis: Kinet. Katal. 21, 1238 (1980).Google Scholar
  103. 103.
    J.C.D. Brand and W. Snedden: Trans. Faraday Soc. 53, 894 (1957).CrossRefGoogle Scholar
  104. 104.
    L.A. Burkhardt, P.R. Hammond, R.H. Knipe and R.R. Lake: J. Chem. Soc. (A), 3789 (1971).Google Scholar
  105. 105.
    R.M. Fuoss: J. Am. Chem. Soc. 80, 5059 (1958).Google Scholar
  106. 106.
    M. Eigen: Z. Phys. Chem. 1, 176 (1954).Google Scholar
  107. 107.
    J.E. Gordon: Organic Chemistry of Electrolyte Solutions, p. 372f, Wiley, New York (1975).Google Scholar
  108. 108.
    K.C.M. Davis: Molecular Association, Vol. 1 (ed. R. Foster), p. 151, Academic, New York (1975).Google Scholar
  109. 109.
    M. Szwarc (ed.) Ions and Ion Pairs in Organic Reactions, Vol. 1 and 2, Wiley, New York ( 1972, 1974 ).Google Scholar
  110. 110.
    A. Loupy and B. Tchoubar: Effets de Sels en Chimie Organique et Organometallique, p. 12f, Dunod, Paris (1988).Google Scholar
  111. 111.
    C. Reichardt: Solvent and Solvent Effects in Organic Chemistry, VCH, Weinheim (1988).Google Scholar
  112. 112.
    Y. Marcus (ed.) Ion Solvation, Wiley, New York (1985).Google Scholar
  113. 113.
    R.M. Fuoss and F. Accascina: Electrolytic Conductance, Wiley, New York (1959).Google Scholar
  114. 114.
    I.R. Gould, R.H. Young, R.E. Moody and S. Farid: J. Phys. Chem. 95, 2068 (1991).CrossRefGoogle Scholar
  115. 115.
    S. Ojima and H. Miyasaka, N. Mataga: J. Phys. Chem. 94, 5834, 7534 (1990).CrossRefGoogle Scholar
  116. 116.
    T. Yabe and J.K. Kochi: J. Am. Chem. Soc. 114, 4491 (1992).CrossRefGoogle Scholar
  117. 117a).
    A. Elder and S. Petrucci: Inrg. Chem. 9 19 (1970).Google Scholar
  118. 117(b).
    S. Winstein, E. Clippinger, A.H. Fainberg and G.C. Robinson: J. Am. Chem. Soc. 76, 2597 (1954).CrossRefGoogle Scholar
  119. 118.
    M.V. Smoluchowski: Phys. Z. 17, 557, 983 (1916).Google Scholar
  120. 119.
    V.E. Kampar and O.Ya. Neilands: Russ. Chem. Rev. 55, 334 (1986).CrossRefGoogle Scholar
  121. 120.
    V.E. Kampar, I.Ya. Gudele and O.Ya. Neilands: Theor. Exper. Chem. 16, 321 (1980).CrossRefGoogle Scholar
  122. 121.
    K. Szczepaniak and A. Tramer: J. Phys. Chem. 71, 3035 (1967).CrossRefGoogle Scholar
  123. 122.
    J. Yarwood: Spectroscopy and Structure of Molecular Complexes, p. 105, Plenum, London (1973).Google Scholar
  124. 123.
    F. Wudl, D. Wobschall and E.J. Hufnagel: J. Am. Chem. Soc. 94, 670 (1972).CrossRefGoogle Scholar
  125. 124.
    F. Wudl: Accts. Chem. Res. 17, 227 (1984).CrossRefGoogle Scholar
  126. 125.
    T. Ishiguro: Physica C 153, 1055 (1988).CrossRefGoogle Scholar
  127. 126.
    J.D. Wright: Molecular Crystals, p. 131f, Cambridge University Press, New York (1987).Google Scholar
  128. 127.
    J.B. Torrance: Accts. Chem. Res. 12, 79 (1979).Google Scholar
  129. 128.
    J.S. Miller, J.C. Calabrese, H. Rommelmann, S.R. Chittipeddi, J.H. Zhang, W.M. Reiff and A.J. Epstein: J. Am. Chem. Soc. 109, 769 (1987).CrossRefGoogle Scholar
  130. 129.
    J.R. Morton, K.F. Preston, M.D. Ward and P.J. Fagan: J. Chem. Phys. 90, 2148 (1989).CrossRefGoogle Scholar
  131. 130.
    E.K. Kim and J.K. Kochi: J. Am. Chem. Soc. 113, 4962 (1991).CrossRefGoogle Scholar
  132. 131.
    S. Brownstein, E. Gabe, F. Lee and A. Piotrowski: Can. J. Chem. 64, 1661 (1986).CrossRefGoogle Scholar
  133. 132.
    K.-M. Chi, J.C. Calabrese, W.M. Reiff and J.S. Miller: Organometallics 10, 688 (1991).CrossRefGoogle Scholar
  134. 133.
    W. Dumler and H. Kisch: New J. Chem. 15, 649 (1991).Google Scholar
  135. 134.
    D.R. Rosscinsky, K. Kite, R.E. Malpas and R.A. Hann: J. Electroanal. Chem. 68, 120 (1976).CrossRefGoogle Scholar
  136. 135.
    J.M. Williams and A.J. Schultz: Molecular Metals (ed. W.E. Hatfield), p. 337, Plenum, New York (1978).Google Scholar
  137. 136.
    J.S. Miller and A.J. Epstein: Prog. Inorg. Chem. 20, 1 (1976).CrossRefGoogle Scholar
  138. 137.
    M.W. Hanna and L.J. Lippert: Molecular Complexes (ed. R. Foster), p. lf, Elek, London (1973).Google Scholar
  139. 138.
    R. Foster: Organic Charge-Transfer Complexes, p. 33f, Academic, New York (1969).Google Scholar
  140. 139.
    See N. Mataga et al. in reference 86, p. 201f.Google Scholar
  141. 140.
    R.S. Mulliken and W.B Person: Molecular complexes. A Lecture and Reprint Volume, Wiley, New York (1969).Google Scholar
  142. 141.
    R.S. Mulliken: J. Am. Chem. Soc. 72, 600 (1950).Google Scholar
  143. 142.
    F.K. Velichko, L.V. Balabanova, T.T. Vasil’eva, O.P. Bondarenko and G.A. Shvekhgeimer: Isv. Akad. Nauk. SSSR Ser Khim, 711 (1988).Google Scholar
  144. 143.
    A. Nakamura and S. Otsuka: Bull. Chem. Soc. Jpn. 49, 3641 (1976).CrossRefGoogle Scholar
  145. 144.
    P.G. Sennikov, V.A. Kuznetsov, A.N. Egorochkin, N.I. Sirotkin, R.G. Nazarova and G.A. Razuvaev: J. Organometal. Chem. 196, 167 (1980).CrossRefGoogle Scholar
  146. 145.
    R.E. Lehmann and J.K. Kochi: J. Am. Chem. Soc. 113, 501 (1991).CrossRefGoogle Scholar
  147. 146.
    R.D. Schmitt, R.M. Wing and A.H. Maki: J. Am. Chem. Soc. 91, 4394 (1969).CrossRefGoogle Scholar
  148. 147.
    T.M. Bockman and J.K. Kochi: J. Am. Chem. Soc. 111, 4669 (1989).CrossRefGoogle Scholar
  149. 148.
    F. Calderazzo, G. Pampaloni, G. Pelizzi and F. Vitali: Organometallics 7, 1083 (1988).CrossRefGoogle Scholar
  150. 149.
    H. Hennig, R. Benedix and R. Billing: J. Prakt. Chem. 328, 829 (1986).CrossRefGoogle Scholar
  151. 150.
    R. Billing, D. Rehorek and H. Hennig: Top. Curr. Chem. 158, p. 166f (1990).Google Scholar
  152. 151.
    I.G. Dance, P.J. Solstad and J.C. Calabrese: Inorg. Chem. 12, 2161 (1973).CrossRefGoogle Scholar
  153. 152.
    S. Lahner, Y. Wakatsuki and H. Kisch: Chem. Ber. 120, 1011 (1987).CrossRefGoogle Scholar
  154. 153.
    B.P. Sullivan, J.C. Curtis, E.M. Kober and T.J. Meyer: Nouv. J. Chim. 4, 643 (1980).Google Scholar
  155. 154.
    E.G. McRae: J. Phys. Chem. 61, 562 (1957).Google Scholar
  156. 155.
    E.M. Kosower and P.E. Klinedinst: J. Am. Chem. Soc. 78, 3493 (1956).CrossRefGoogle Scholar
  157. 156.
    E.M. Kosower: J. Am. Chem. Soc. 80, 3253 (1958).Google Scholar
  158. 157.
    T.M. Bockman, H.-R. Chang, H.G. Drickamer and J.K. Kochi: J. Phys. Chem. 94, 8483 (1990).CrossRefGoogle Scholar
  159. 158.
    A.H. Ewald and J.A. Scudder: J. Phys. Chem. 76, 249 (1972).CrossRefGoogle Scholar
  160. 159.
    See J.D. Wright, in reference 126, p. 88f.Google Scholar
  161. 160.
    J. Tanaka, M. Tanaka. T. Kawai, T. Takabe and O. Maki: Bull. Chem. Soc. Jpn. 49, 2358 (1976).CrossRefGoogle Scholar
  162. 161.
    W.B. Person, R.E. Ericson and R.E. Buckles: J. Am. Chem. Soc. 82, 29 (1960).CrossRefGoogle Scholar
  163. 162.
    J. Yarwood and R. Arndt: Molecular Association, Vol. 2 (ed. R.F. Foster), p. 267f, Academic, New York (1979).Google Scholar
  164. 163.
    Z.G. Soos and D.J. Klein: Molecular Association, Vol. 1 (ed. R.F. Foster), p. 2f, Academic, New York (1975).Google Scholar
  165. 164.
    C.K. Prout and B. Kamenar: Molecular Complexes, Vol. 1 (ed. R.F. Foster) p. 49f, Elek, London (1969).Google Scholar
  166. 165.
    C-.H. Wei, T.M. Bockman and J.K. Kochi: J. Organometal. Chem. 428, 85 (1992).CrossRefGoogle Scholar
  167. 166.
    W.F. Edgell, J. Lyford, A. Barbetta and C.I. Jose: J. Am. Chem. Soc. 93, 6403 (1971).CrossRefGoogle Scholar
  168. 167.
    M.Y. Darensbourg and C.E. Ash: Adv. Organometal. Chem. 27, 1 (1987).CrossRefGoogle Scholar
  169. 168.
    T.M. Bockman and J.K. Kochi: New J. Chem. 16, 39 (1992)Google Scholar
  170. 169.
    M.Y. Darensbourg: Prog. Inorg. Chem. 33, 221 (1985).Google Scholar
  171. 170.
    C. Schramm and J.I. Zink: J. Am. Chem. Soc. 101, 4554 (1979).CrossRefGoogle Scholar
  172. 171.
    A. Vogler and H. Kunkely: J. Organometal. Chem. 355, 1 (1988).CrossRefGoogle Scholar
  173. 172.
    A. Vogler and H. Kunkely: Z. Naturforsch, 44b, 132 (1989).Google Scholar
  174. 173.
    J.M. Burlitch: J. Am. Chem. Soc. 91, 4562 (1969).Google Scholar
  175. 174.
    M. Rosenblum, R.W. Fish and C. Bennett: J. Am. Chem. Soc. 86, 5166 (1964).CrossRefGoogle Scholar
  176. 175.
    J.S. Miller, A.J. Epstein and W.M. Reiff: Chem. Rev. 88, 201 (1988).CrossRefGoogle Scholar
  177. 176.
    J.S. Miller, W.M. Reiff, J.H. Zhang. L.D. Preston, A.H. Reis, Jr., E. Gebert, M. Extine, J. Troup, D.A. Dixon, A.J. Epstein and M.D. Ward: J. Phys. Chem. 91, 4344 (1987).CrossRefGoogle Scholar
  178. 177.
    M.R. Wasielewski and D.M. Tiede: FEBS Lett. 204 (1986).Google Scholar
  179. 178.
    E.F. Hilinski and P.M. Rentzepis: Acc. Chem. Res. 16, 224 (1983).CrossRefGoogle Scholar
  180. 179.
    N. Mataga: Pure Appl. Chem. 56, 1255 (1984).CrossRefGoogle Scholar
  181. 180.
    T.W. Ebbesen, L.E. Manring and K.S. Peters: J. Am. Chem. Soc. 106, 7400 (1984).CrossRefGoogle Scholar
  182. 181.
    J.M. Masnovi, J.C. Huffman, J.K. Kochi, E.F. Hilinski and P.M. Rentzepis: Chem. Phys. Lett. 106, 20 (1984).CrossRefGoogle Scholar
  183. 182.
    S.M. Hubig and M.A. J. Rodgers: Handbook of Organic Photochemistry, Vol. 1 (ed. J.C. Scaiano), p. 315, CRC Press, Boca Raton, FL (1989).Google Scholar
  184. 183.
    J. Mattay and M. Vondenhof: Top. Curr. Chem. 159, 219 (1991).CrossRefGoogle Scholar
  185. 184.
    Y. Wang, J.J. Tria and L.M. Doifiiian: J. Phys. Chem. 83, 1946 (1979).CrossRefGoogle Scholar
  186. 185.
    T. Shida: Electronic Absorption Spectra of Radical Ions, Elsevier, New York (1988).Google Scholar
  187. 186.
    P.K. Das: J. Chem.Soc. Faraday Trans. 179, 1135 (1983).Google Scholar
  188. 187.
    J.A. Hutchinson, J. Di Benedetto and P.M. Rentzepis: J. Am. Chem. Soc. 108, 6517 (1986).CrossRefGoogle Scholar
  189. 188.
    See L.M. Hadel in reference 182.Google Scholar
  190. 189.
    R.V. Bensasson, E.J. Land and T.G. Truscott: Flash Photolysis and Pulse Radiolysis, Pergamon, New York (1983).Google Scholar
  191. 190.
    M.A. West: Investigation of Rates and Mechanisms of Reactions, Part II (ed. C.F. Bemasconi), p. 391f, Wiley, New York (1986).Google Scholar
  192. 191.
    B.T. Lozhkin, O.B. Lyakhova, A.V. Churkin and A.V. Vannikov: High Energy Chem. 19, 51 (1985).Google Scholar
  193. 192.
    J.C. Curtis, B.P. Sullivan and T.J. Meyer: Inorg. Chem. 19, 3833 (1980).CrossRefGoogle Scholar
  194. 193.
    A. Fernandez, H. Görner, H. Kisch: Chem. Ber. 118, 1936 (1985).CrossRefGoogle Scholar
  195. 194.
    J. Burgess, K.C.M. Davis, R.D.W. Kemmitt, J.B. Raynor and J. Stocks: Inorg. Chim. Acta 4, 129 (1970).CrossRefGoogle Scholar
  196. 195.
    T. Watanabe and K. Honda: J. Phys. Chem. 86, 2617 (1982).CrossRefGoogle Scholar
  197. 196.
    L.J. Rothberg, N.J. Cooper, K.S. Peters and V. Vaida: J. Am. Chem. Soc. 104, 3536 (1982).CrossRefGoogle Scholar
  198. 197.
    R.F. Cozzens and T.A. Cover: J. Phys. Chem. 74, 3003 (1970).CrossRefGoogle Scholar
  199. 198.
    D.R. Rosseinsky and R.E. Malpas: J. Chem. Soc. Dalton Trans., 749 (1979).Google Scholar
  200. 199.
    H. Meier, W. Albrecht, H. Kisch and F. Nusslein: J. Phys. Chem. 93, 7726 (1989).CrossRefGoogle Scholar
  201. 200.
    R.A. Marcus: Ann. Rev. Phys. Chem. 15, 155 (1964).Google Scholar
  202. 201.
    L. Eberson: Electron Transfer Reactions in Organic Chemistry, p. 32, Springer Verlag, New York (1987).Google Scholar
  203. 202.
    F.D. Saeva: Top. Curr. Chem. 156, 59 (1989).Google Scholar
  204. 203.
    R. Kaptein: Chemically Induced Magnetic Polarization (eds. A.R. Lepley and G.L. Closs ), Wiley, New York (1973).Google Scholar
  205. 204.
    R.Z. Sagdeev, K.M. Salikhov and Yu.M. Molin: Russ. Chem. Rev. 46, 297 (1977).CrossRefGoogle Scholar
  206. 205.
    T.M. Bockman, Z.J. Karpinski, S. Sankararaman and J.K. Kochi: J. Am. Chem. Soc. 114, 1970 (1992).CrossRefGoogle Scholar
  207. 206.
    K. Mochida, J.K. Kochi, K.S. Chen and J.K.S. Wan: J. Am. Chem. Soc. 100, 2927 (1978).CrossRefGoogle Scholar
  208. 207.
    E.F. Hilinski, J.M. Masnovi, J.K. Kochi and P.M. Rentzepis: J. Am. Chem. Soc. 106, 8071 (1984).CrossRefGoogle Scholar
  209. 208.
    E. Körner von Gustorf, H. Köller, M.-J. Jun and G.O. Schenk: Chem. Eng. Tech. 35, 591 (1963).Google Scholar
  210. 209.
    O. Traverso and F. Scandola: Inorg. Chim. Acta 4, 493 (1970).CrossRefGoogle Scholar
  211. 210.
    C.P. Andrieux, A. Merz and J.-M. Saveant: J. Am. Chem. Soc. 107, 6097 (1985).CrossRefGoogle Scholar
  212. 211.
    C. R. Bock and M.S. Wrighton: Inorg. Chem. 16, 1309 (1977).CrossRefGoogle Scholar
  213. 212.
    P. Borrell and E. Henderson: J. Chem. Soc. Dalton Trans., 432 (1975).Google Scholar
  214. 213.
    O. Traverso, C. Chiorboli, U. Mazzi and G.L. Zucchini: Gazz. Chim. Ital. 107, 181 (1977).Google Scholar
  215. 214.
    W. Lau, J.C. Huffman and J.K. Kochi: J. Am. Chem. Soc. 104, 5515 (1982).Google Scholar
  216. 215.
    A. Jaworska-Augustyniak and J. Wojtczak: Trans. Met. Chem. (Weinheim) 10, 96 (1985).CrossRefGoogle Scholar
  217. 216.
    G. Fachinetti, T. Funaioli and P.F. Zanazzi: J. Chem. Soc. Chem. Commun., 1100 (1988).Google Scholar
  218. 217.
    J.D. Wilkey and G.B. Schuster: J. Am. Chem. Soc. 113, 2149 (1991).CrossRefGoogle Scholar
  219. 218.
    A. Tatikolov, X. Yang, B. Saucrwein and G.B. Schuster: Acta Chem. Scand. 44, 837 (1990).CrossRefGoogle Scholar
  220. 219.
    D.G. Borden: Photogr. Sci. Eng. 16, 300 (1972).Google Scholar
  221. 220.
    S.F. Clark, R.J. Watts, D.L. Dubois, J.S. Connolly and J.C. Smart: Coord. Chem. Rev. 64, 273 (1985).CrossRefGoogle Scholar
  222. 221.
    D.H. Geske: J. Phys. Chem. 63, 1062 (1959).Google Scholar
  223. 222.
    J.D. Wilkey and G.B. Schuster: J. Org . Chem. 52, 2117 (1987).CrossRefGoogle Scholar
  224. 223.
    W. Lau, J.C. Huffman and J.K. Kochi: Organometallics 1, 155 (1982).CrossRefGoogle Scholar
  225. 224.
    S. Komiya, T.A. Albright, R. Hoffmann and J.K. Kochi: J. Am. Chem. Soc. 98, 7255 (1976).CrossRefGoogle Scholar
  226. 225.
    P.F. de Violet and S.R. Logan: J. Chem. Soc. Faraday Trans 1 76, 578 (1980).CrossRefGoogle Scholar
  227. 226.
    R.J. Devoe, M.R.V. Sahyun, N. Serpone and D.K. Sharma: Can. J. Chem. 65, 2342 (1987).CrossRefGoogle Scholar
  228. 227.
    J.P. Fouassier, D. Burr and J.V. Crivello: J. Photochem. Photobiol. 49, 317 (1989).CrossRefGoogle Scholar
  229. 228.
    C. Galli: Chem. Rev. 88, 765 (1988).CrossRefGoogle Scholar
  230. 229.
    R. Billing, D. Rehorek, J. Salvetter and H. Hennig: Z. Anorg. Allg. Chem. 557, 234 (1988).CrossRefGoogle Scholar
  231. 230.
    A. Vogler and H. Kunkely: Top. Curr. Chem. 158, 24 (1990).Google Scholar
  232. 231.
    A. Vogler and J. Kisslinger: J. Am. Chem. Soc. 104, 2311 (1982).CrossRefGoogle Scholar
  233. 232.
    H. Hennig, A. Rehorek, D. Rehorek, P. Thomas and D. Bäzold: Inorg. Chim. Acta 77, L11 (1983).CrossRefGoogle Scholar
  234. 233.
    H. Hennig, A. Rehorek, D. Rehorek, P. Thomas: Inorg. Chim. Acta 86, 41 (1984).CrossRefGoogle Scholar
  235. 234.
    H. Horii, S. Fujita, T. Mori and S. Taniguchi: Bull. Chem. Soc. Jpn. 52, 3099 (1979).CrossRefGoogle Scholar
  236. 235.
    A. Vogler and H. Kunkely: Organometallics 7, 1449 (1988).CrossRefGoogle Scholar
  237. 236.
    M.O. Albers and N.J. Coville: Coord. Chem. Rev. 53, 227 (1984).CrossRefGoogle Scholar
  238. 237.
    N.G. Connelly: Chem. Soc. Rev. 18, 153 (1989).Google Scholar
  239. 238.
    M.C. Baird: Chem. Rev. 88, 1217 (1988).Google Scholar
  240. 239.
    H. Knoll, R. Billing, H. Hennig and D.J. Stufkens: Inorg. Chem. 29, 3051 (1990).CrossRefGoogle Scholar
  241. 240.
    F.D. Lewis: Acc. Chem. Res. 19, 401 (1986).Google Scholar
  242. 241.
    H. Shizuka: Acc. Chem. Res. 18, 141 (1985).CrossRefGoogle Scholar
  243. 242.
    O.B. Ryan, M. Tilset and V.D. Parker: J. Am. Chem. Soc. 112, 2618 (1990).CrossRefGoogle Scholar
  244. 243.
    A. Nakamura and S. Otsuka: J. Am. Chem. Soc. 95, 7262 (1973).CrossRefGoogle Scholar
  245. 244.
    W. Lau and J.K. Kochi: J. Am. Chem. Soc. 108, 6720 (1986).CrossRefGoogle Scholar
  246. 245.
    E.G. Megeehee, C.E. Johnson and R. Eisenberg: Inorg. Chem. 28, 2423 (1989).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 1993

Authors and Affiliations

  • T. M. Bockman
    • 1
  • J. K. Kochi
    • 1
  1. 1.Department of ChemistryUniversity of HoustonHoustonUSA

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