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Photocatalysis in C-H Activation

  • R. H. Crabtree
Chapter
Part of the Catalysis by Metal Complexes book series (CMCO, volume 14)

Abstract

The catalytic chemistry of organometallic complexes usually depends on coordinative unsaturation. Most substrates can only bind if an empty orbital is available on the metal to receive it. One way in which photochemistry can facilitate catalysis is to generate coordinative unsaturation by photoextrusion of a ligand. Photoextrusion of CO and H2 are both well recognized in stoichiometric reactions and so it is not surprising that catalytic chemistry has also been seen in these systems.

Keywords

Oxidative Addition Kinetic Isotope Effect Vinyl Carbon Catalytic Turnover Catalytic Dehydrogenation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media Dordrecht 1993

Authors and Affiliations

  • R. H. Crabtree
    • 1
  1. 1.Dept. of ChemistryYale UniversityNew HavenUSA

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