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Photocatalytic Transformations of Organic Substrates Using Inorganic Salts and Complexes

  • U. Kölle
Chapter
Part of the Catalysis by Metal Complexes book series (CMCO, volume 14)

Abstract

In the following reactions are discussed which use UV or visible light and a metal salt or a transition metal complex, in general in less than stoichiometric quantity, to effect an organic substrate transformation. The cases presented are a selection which is intended to illustrate the possibilities — also pitfalls — of this type of photocatalysis. An overview in tabular form can be found in ref. [1]. Not considered is organic photochemistry sensitized by Hg [2] and reactions coupled to excitation of semiconductors. No consideration is given to phototransformations which effect only a change in the metal complex [3] and of the many catalytic reaction cycles which are initiated by ligand loss from a transition metal carbonyl, olefin, alkyl or hydride complex [4]. Informative and timely reviews are available on this topic.

Keywords

Organic Substrate Allyl Alcohol Transition Metal Salt Cycloaddition Product Isomerization Catalyst 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Springer Science+Business Media Dordrecht 1993

Authors and Affiliations

  • U. Kölle
    • 1
  1. 1.Institute of Inorganic ChemistryRWTH, Technical University at AachenAachenGermany

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