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Magnetic Resonances and Spin Dynamics in Molecular Magnets

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Molecular Magnetism: From Molecular Assemblies to the Devices

Part of the book series: NATO ASI Series ((NSSE,volume 321))

Abstract

Magnetic resonance techniques are very powerful for the investigation of magnetic molecular materials1–3. In fact electron paramagnetic resonance (EPR) can provide information on the nature of the ground state, and in some cases also of the excited states, on the delocalization of the spin density on the paramagnetic molecule, on the magnetic and crystal field anisotropy, on the dimensionality of the magnetic system, and on the spin dynamics at relatively high frequencies. Nuclear magnetic resonance (NMR) on the other hand can provide information on the sign and the intensity of the spin density, on the dimensionality of the spin system, and on the spin dynamics at relatively low frequencies4. Therefore, the two techniques are largely complementary to each other, and should be used whenever a detailed understanding of the magnetic materials is needed.

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References

  1. A. Bencini, D. Gatteschi, “Electron Paramagnetic Resonance of Exchange Coupled Systems”, Springer Verlag, Berlin (1990)

    Book  Google Scholar 

  2. F.E. Mabbs, D. Collison, “Electron Paramagnetic Resonance of d Transition Metal Compounds”, Elsevier (1992)

    Google Scholar 

  3. J.A. Weil, J.R. Bolton, J.P. Wertz, “Electron Paramagnetic Resonance Theory and Practical Applications”, Wiley, N.Y., (1994)

    Google Scholar 

  4. J.P. Renard, in “Magneto-Structural Correlations in Exchange Coupled Systems”, R.D. Willett, D. Gatteschi, O. Kahn, Eds, Reidel, Dordrecht, (1985)

    Google Scholar 

  5. A. Abragam, “ The Principles of Nuclear Magnetism”, Oxford University Press (1961)

    Google Scholar 

  6. I. Bertini, C. Luchinat, “NMR of Paramagnetic Molecules in Biological Systems”, Benjamin Cummins, Menlo Park (1986)

    Google Scholar 

  7. C. Kollmar, O. Kahn, J. Am. Chem. Soc., 113, 7687. (1991)

    Google Scholar 

  8. C. Kollmar, M. Couty, O. Kahn, J. Am. Chem. Soc., 113, 7994. (1991)

    Article  CAS  Google Scholar 

  9. F.H. Koehler, K.H. Doll, W. Proessdorf, J. Organomet. Chem., 224. (1982)

    Google Scholar 

  10. T. Moriya, in “Magnetism”, G.T. Rado, H. Suhl, Eds., Academic Press, New York, 1, 85. (1963)

    Google Scholar 

  11. A. Bencini, D. Gatteschi, C. Zanchini, Inorg. Chem., 24, 700. (1985)

    Article  CAS  Google Scholar 

  12. M.F. Charlot, Y. Journaux, O. Kahn, A. Bencini, D. Gatteschi, C. Zanchini, Inorg. Chem., 25, 1060. (1986)

    Article  CAS  Google Scholar 

  13. D. Gatteschi, L. Pardi, Gazz. Chini. It., 123, 231. (1993)

    CAS  Google Scholar 

  14. C. Delfs, D. Gatteschi, L. Pardi, R. Sessoli, K. Wieghardt, D. Hanke, Inorg. Chem., 32, 3099. (1993)

    Article  CAS  Google Scholar 

  15. C. Delfs, D. Gatteschi, L. Pardi, R. Sessoli, Comments Inorg. Chem., 15, 27. (1993)

    Article  CAS  Google Scholar 

  16. R. Prins, R.A.G. DeGraaf, J.G. Haasnoot, C. Vader, J. Reedijk, J. Chem. Soc. Chem. Commun., 1430. (1986)

    Google Scholar 

  17. A. Bencini, D. Gatteschi, C. Zanchini, J.G. Haasnoot, R. Prins, J. Reedijk, J. Am. Chem. Soc., 109, 2926. (1987)

    Article  CAS  Google Scholar 

  18. I. Fujita, Y. Teki, T. Takui, T. Kinoshita, K. Itoh, F. Miko, Y. Sawaki, H. Iwamura, A. Izuoka, T. Sugawara, J. Am. Chem. Soc., 112, 4074. (1990)

    Article  CAS  Google Scholar 

  19. R.H. Holm, J.M. Berg, in “Iron Sulfur Proteins”, T.G. Spiro, Ed., Wiley, New York. (1982)

    Google Scholar 

  20. H. Beinert, A.J. Thomson, Arch. Biochem. Biophys., 222, 333 (1983)

    Article  CAS  Google Scholar 

  21. S.J. George, F.A. Annstrong, E.C. Hatchikian, A.J. Thomson, Biochem. J.., 264, 275. (1989)

    CAS  Google Scholar 

  22. V. Papaefthymiou, M.M. Miller, E. Münck, Inorg. Chem., 25, 3010. (1986)

    Article  CAS  Google Scholar 

  23. M.J. Carney, G.C. Papaefthymiou, K. Spartalian, R.B. Frankel, R.H. Holm, J. Am. Cheni. Soc., 110, 6081. (1988)

    Google Scholar 

  24. R.E. Johnson, G.C. Papaefthymiou, R.B. Frankel, R.H. Holm, J. Am. Chem. Soc., 105, 7280. (1983)

    Article  CAS  Google Scholar 

  25. J. Gloux, P. Gloux, B. Lamotte, B. Rius, Phys. Rev. Leu., 54, 599. (1985)

    Article  CAS  Google Scholar 

  26. J. Gloux, P. Gloux, B. Lamotte, J.-M. Mouesca, G. Rius, J. Am. Chem. Soc., 116, 1953. (1994)

    Article  CAS  Google Scholar 

  27. F. Muller, M.A. Hopkins, N. Coron, M. Grynberg. L.C. Brunel, M. Martinez, Rev. Sci. Instrum., 60, 3681. (1989)

    Article  CAS  Google Scholar 

  28. A. Caneschi, D. Gatteschi, R. Sessoli, A.L. Barra, L.C. Brunel, M. Guillot, J. Am. Chem. Soc, 113, 5873. (1991)

    Article  CAS  Google Scholar 

  29. T. Lis, Acta Ciystallogr., B 36, 2042. (1980)

    Google Scholar 

  30. R. Sessoli, H.-L. Tsai, A.R. Schake, S. Wang, J.B. Vincent, K. Folting, D. Gatteschi, G. Christou, D.N. Hendrickson, J Am. Chem. Soc., 115, 1801 (1993).

    Article  Google Scholar 

  31. R. Kubo, K. Tornita, J Phys. Soc. Japan, 9, 316 (1954).

    Article  Google Scholar 

  32. P.M. Richards in “Local Properties at Phase Transitions”, K.A. Miller, A. Rigamonti, Eds., Editrice Compositori, Bologna, 535 (9176).

    Google Scholar 

  33. H. Kalt, E. Siegel, N. Pauli, H. Mosebach, J. Wiese, A. Edgar, J. Phys. C, 16, 6427 (1983).

    Article  CAS  Google Scholar 

  34. P.M. Richards, Phys. Rev. B, 13, 458 (1976).

    Article  CAS  Google Scholar 

  35. H. Mori, Progr. Theor. Phys., 33, 423 (1965).

    Article  Google Scholar 

  36. J.P. Boucher, M. Ahmed Bakheit, M. Nectschien, M. Villa, G. Bonera, F. Borsa, Phys. Rev. B, 13, 4098 (1976).

    Article  CAS  Google Scholar 

  37. K Nagat, Y. Tazuke, J Phys. Soc. Japan, 32, 377 (1972).

    Article  Google Scholar 

  38. T. Karasudani, H. Okamoto, Phys. Lett. A, 57, 77 (1975).

    Article  Google Scholar 

  39. D. Gatteschi, R. Sessoli, C. Zanchini in Magnetic Resonance and related phenomena, Proc. 24th Congress Ampere, J. Stankovski, N. Pislevski, S.K. Hoffmann, S. Idziate, Eds, Elsevier, Amsterdam 1989, p. 325.

    Google Scholar 

  40. P. Turek, Mol. Cryst. Liq. Cryst., 235, 551 (1993).

    Google Scholar 

  41. K. Awaga, T. Inabe, U. Nagashima, Y. Maruyama, J Chem. Soc. Chem. Commun., 1617 (1989).

    Google Scholar 

  42. A. Caneschi, F. Ferraro, D. Gatteschi, A. le Lirzin, M. Novak, E. Rentschler, Adv. Mater., 7, 476 (1995).

    Article  CAS  Google Scholar 

  43. A. Caneschi, F. Ferraro, D. Gatteschi, A. le Lirzin, E. Rentschler, Inorg. Chim. Acta, 235, 159 (1995).

    Article  CAS  Google Scholar 

  44. M.C.M. Gribnau, J.A. Pikkemat, E. de Boer, Mol. Phys., 67, 347 (1989). 45.0. Takizawa, Bull. Chem. Soc. Japan, 49, 583 (1976).

    Article  Google Scholar 

  45. P. Petit, J.J. Andri, J. Phys., 49, 833 (1988).

    Google Scholar 

  46. J.E. Gulley, D. Hone, D.J. Scalapino, B.G. Silbernagel, Phys. Rev. B, 1, 1020 (1970).

    Article  Google Scholar 

  47. C. Jeandey, J.P. Boucher, F. Ferrieu, M. Nechtschein, Solid State Commun, 23, 673 (1973).

    Article  Google Scholar 

  48. C. Benelli, A. Caneschi, D. Gatteschi, L. Pardi, P. Rey, Inorg. Chem., 28, 3230 (1989).

    Article  CAS  Google Scholar 

  49. A. Caneschi, D. Gatteschi, R. Sessoli, C.I. Cabello, P. Rey, A.L. Barra, L.C. Brunel, Inorg. Chem., 30, 1882 (1991).

    Article  CAS  Google Scholar 

  50. F. Ferraro, D. Gatteschi, Mol. Phys., 83, 933 (1994).

    Article  CAS  Google Scholar 

  51. F. Ferraro, D. Gatteschi, R. Sessoli, M. Corti, J. Am. Chem. Soc., 113, 8410 (1991).

    Article  CAS  Google Scholar 

  52. F. Borsa, J.P. Boucher, J. Villain, J Appl. Phys., 29, 1326 (1988).

    Google Scholar 

  53. A. Rettori in “Magnetic Properties of Matter”, F. Borsa, V. Tognetti, Eds., World Scientific, Singapore, (1988).

    Google Scholar 

  54. F. Borsa, M.G. Pini, A. Rettori, V. Tognetti, Phys. Rev. B, 28, 5173 (1982).

    Article  Google Scholar 

  55. F. Ferraro, D. Gatteschi, A. Rettori, M. Corti, Mol. Phys., 85, 1073 (1995).

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Florence, Via Maragliano 75/77, 50144, Florence, Italy

    D. Gatteschi

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  1. D. Gatteschi
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Editors and Affiliations

  1. Dept. de Química Inorgánica, Universidad de Valencia, Dr. Moliner 50, 46100, Burjassot, Valencia, Spain

    Eugenio Coronado

  2. Centre de Reserches Paul Pascal, CRPP-CNRS, Université de Bordeaux I, Av. A. Schweitzer, 33600, Pessac, Talence, France

    Pierre Delhaès

  3. Dipartimento di Chimica, Universitá degli Studi di Firenze, Via Maragliano, 75/77, 50144, Firenze, Italy

    Dante Gatteschi

  4. Dept. of Chemistry, University of Utah, 84112, Salt Lake City, Utah, USA

    Joel S. Miller

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© 1996 Springer Science+Business Media Dordrecht

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Gatteschi, D. (1996). Magnetic Resonances and Spin Dynamics in Molecular Magnets. In: Coronado, E., Delhaès, P., Gatteschi, D., Miller, J.S. (eds) Molecular Magnetism: From Molecular Assemblies to the Devices. NATO ASI Series, vol 321. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2319-0_6

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  • DOI: https://doi.org/10.1007/978-94-017-2319-0_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4724-3

  • Online ISBN: 978-94-017-2319-0

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