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Molecular Magnetism: From Molecular Assemblies to the Devices pp 243–288Cite as

Bimetallic Molecular-Based Magnetic Materials

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Part of the book series: NATO ASI Series ((NSSE,volume 321))

Abstract

Among all the molecules and molecular assemblies relevant to molecular magnetism [1], those containing two (or possibly more) kinds of metal ions have played a particularly important role. Two reasons, at least, justify this situation. First, the diversity of the situations which can be encountered concerning the interaction between two spin carriers A and B within a molecular unit is much greater when A and B are different. For instance, the strict orthogonality of the magnetic orbitals leading to the stabilization of the molecular state of highest spin multiplicity is much easier to achieve in heterobimetallic than in homobimetallic species [2]. Secondly, with several kinds of magnetic centers, it is possible to design molecular lattices showing quite peculiar spin topologies. It is in particular the case of ferrimagnetic lattices.

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Authors and Affiliations

  1. Laboratoire des Sciences Moléculaires, Institut de Chimie de la, Matière Condensée de Bordeaux, 33608, Pessac, France

    Olivier Kahn

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  1. Olivier Kahn
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Editors and Affiliations

  1. Dept. de Química Inorgánica, Universidad de Valencia, Dr. Moliner 50, 46100, Burjassot, Valencia, Spain

    Eugenio Coronado

  2. Centre de Reserches Paul Pascal, CRPP-CNRS, Université de Bordeaux I, Av. A. Schweitzer, 33600, Pessac, Talence, France

    Pierre Delhaès

  3. Dipartimento di Chimica, Universitá degli Studi di Firenze, Via Maragliano, 75/77, 50144, Firenze, Italy

    Dante Gatteschi

  4. Dept. of Chemistry, University of Utah, 84112, Salt Lake City, Utah, USA

    Joel S. Miller

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Kahn, O. (1996). Bimetallic Molecular-Based Magnetic Materials. In: Coronado, E., Delhaès, P., Gatteschi, D., Miller, J.S. (eds) Molecular Magnetism: From Molecular Assemblies to the Devices. NATO ASI Series, vol 321. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2319-0_10

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  • DOI: https://doi.org/10.1007/978-94-017-2319-0_10

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