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Desulphurization of Coal to Protect the Environment

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Mineral Processing and the Environment

Part of the book series: NATO ASI Series ((ASEN2,volume 43))

Abstract

The major coal desulphurization technologies prior to combustion are physical coal cleaning, chemical and biological methods. Each has some technical and economical limitations. Physical coal cleaning can only remove limited amount of inorganic sulphur due to insufficient liberation. Fine grinding can liberate fine pyrites, where novel coal cleaning techniques are required for separation. Advanced froth flotation, oil agglomeration, selective flocculation and heavy media cycloning are the novel cleaning techniques, most of which have been, or nearly being, commercially deployed. Chemical cleaning techniques, due to their high processing costs, and bicrobiological desulphurization, with its technical and economical uncertainties, are not already commercially applied. Preliminary cost estimations have shown that pre-combustion desulphurization techniques might be competitive with the current post-combustion technologies.

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References

  1. Highton, N.H., and Chadwick, M.J. (1982), The effects of changing patterns of energy use on sulphur emissions and depositions in Europe, Ambio, 11 (6), 324–329.

    Google Scholar 

  2. Batyko, R.J., Ralston, P.E. (1993) Available technologies for flue gas desulphurization in thermal power plants, lEA 2nd International Conference on Clean and Efficient Use of Coal and Lignite: Its Role in Energy, Environment and Life, Nov. 30-December 3, Hong Kong, pp. 871–881.

    Google Scholar 

  3. Bubrov, A.P., Kotkin, A.M.; and Zhulid, E.F. (1974) Size distribution of pyrite inclusions in some sulphur-rich Donbas coals, Koks i Khimiya 4, 11–15.

    Google Scholar 

  4. Ozbayoglu, G., Yarar, B. (1986) Ash and Sulphur removal from Turkish Lignites: A technical and economic evaluation, 1 d e International Coal Preparation Congress Proceedings, 1–5 September, Edmonton, Canada, pp. 181–191.

    Google Scholar 

  5. Hake, W.D. (1976) Application of the Batac jig for processing fine coal, Mining Congress Journal, September, 52–55.

    Google Scholar 

  6. Davis, H. (1976) PPL updates its preparation plant to reduce coal’s sulphur content by 40%, Coal Age, November, 72–76.

    Google Scholar 

  7. Nicol, S.K. (1992) Fine coal beneficiation, in Swenson and Portridge (eds.) Advanced Coal Preparation Monograph Series, Australian Coal Preparation Society, Indooroopilly, Queensland, Australia, vol. IV, part 9.

    Google Scholar 

  8. Hambleton, G.C. (1987) Design of coal preparation plants in U.S.A., MinPrep 87, International Symposium, Innovative Plant and Processing for Mineral Engineering, Doncaster, Yorkshire, April, pp. 1–19.

    Google Scholar 

  9. Feng, Y.; Xichuno, X.; Jianguo, Y.; Dashan, C. (1994) The principle of autogenous medium drum coal separation and its application in China, 11` h annual International Coal Conference Proceedings, Pittsburgh, September, pp. 595–599.

    Google Scholar 

  10. Fan, J., Yung-Song, Y., Zhang-Shen, L. (1982) Study on application of centrifugal table for fine coal concentration, Proceedings of 9th International Coal Preparation Congress, New Delhi, G5 1–15.

    Google Scholar 

  11. Anon (1984) Australian spiral for minus 2 mm coal separation, Mining Journal, April, 248.

    Google Scholar 

  12. West, T.W.; Apodaca, L.E. (1988) Cost effective Btu recovery by fine coal washing spirals, SME Annual Meeting, Phoenix, Arizona, January.

    Google Scholar 

  13. Ozbayoglu, G. (1986) Desulphurization of lignites by HGMS, I“ International Mineral Processing Symposium, 29 September-1 October, Izmir, Turkey, pp. 635–645.

    Google Scholar 

  14. Balzarini, J., and Hucko, R.E. (1991) Recent developments in coal preparation, 8th Annual International Coal Conference Proceedings, October 14–18, pp. 218–228.

    Google Scholar 

  15. Kindig, J.K.; Turner, R.L. (1976) Dry chemical process to magnetize pyrite and ash for removal from coal, AIME Society of Mining Engineering Fall Meeting, Denver, September, 19.

    Google Scholar 

  16. Wheelock, T.D.; Markuszewski, R. (1984) Coal preparation and cleaning, in B.R. Copper and W.A Ellingson (eds.), The Science and Technology of Coal and Coal Utilization, Plenum Press, New York, pp. 47–123.

    Chapter  Google Scholar 

  17. Choudhry, V.; Aplan, F.F. (1992) Pyrite depression during coal flotation, Part 1, Inorganic ions, Minerals and Metallurgical Processing, 9, No. 2, 51–56.

    Google Scholar 

  18. Aplan, F.F. (1977) Use of flotation process for desulphurization of coal, in T.D Wheelock (ed.) Coal Desulphurization, ACS Symposium Series 64, ACS, Washington DC, pp. 70–82.

    Chapter  Google Scholar 

  19. Mishra, B.K., Yu Q., Hu. W. (1990), Autogenous Carrier Flotation for low-ash and low-sulphur coal production. 7 th Annual International Pittsburgh Coal Conference Proceedings, 10–14 September, pp. 671–679.

    Google Scholar 

  20. Dogan, Z.M., Özbayoglu,G., Hiçyilmaz,C., Sarikaya,M., and Özcengiz,G., (1985), Bacterial leaching versus bacterial conditioning and flotation in desulphurization of coal, XVth International Mineral Processing Congress Proceedings, Cannes, France, Vol.I1, pp. 304313.

    Google Scholar 

  21. Tosun, Y.I.; Veasey,T.J.; Rowson, N.A. (1994), Bio-column flotation of coal for desulphurization and comparison with conventional and column flotation, in H. Demirel, S. Ersayin (eds.) Progress in Mineral Processing Technology, Balkema, pp. 465–471.

    Google Scholar 

  22. Atkins, A.S.; Townsley, C.C.; Al-Ameen, S.I. (1987), Application of a biological sulphur depressant to the desulphurization of coal in froth flotation, MinPrep 87, International Symposium on Innovative Plant and Processing for Minerals Engineering, Doncaster, Yorkshire, April, pp. 1–13.

    Google Scholar 

  23. Miller, K.J. (1974), Coal-Pyrite flotation, AIME Annual Meeting, Dallas, Texas, February Preprint No: 74-F-37, pp. 23–28,.

    Google Scholar 

  24. Miller, K.J., and Deurbrouck, A.W. (1982) Froth flotation to desulphurize coal, in Y.A. Liu (ed), Physical Cleaning of Coal-Present and Developing Methods, Marcel Dekker Inc. New York, pp. 255–292.

    Google Scholar 

  25. Luttrell, G.H.; Mankosa, M.J., and Yoon, R.H. (1991), Development of the Microcell Technology, 8 th Annual International Pittsburgh Coal Conference Proceedings, October 14–18, pp. 247–253.

    Google Scholar 

  26. Barnett, W.P., and Feeley, T.J. (1992), Status of advanced coal cleaning as a compliance technology, Mining Engineering, 44, No 10, 1225–1230.

    Google Scholar 

  27. Feeley III, T.J.; Mc Lean, V.L. (1993), Advanced physical coal cleaning as a clean air act compliance technology, Mining Engineering 10, 1253–257.

    Google Scholar 

  28. Yang, D.C. (1993), Advanced Flotation: Packed Column Froth Separation for fine coal cleaning, IEA 2 nd International Conference on The Clean and Efficient use of Coal and Life Conference Proceedings, Hong Kong, 30 November-3 December, pp. 557–565.

    Google Scholar 

  29. Miller, J.D., Van Camp, M.V. (1982), Fine coal flotation in a centrifugal field with an airsparged hydrocyclone, Mining engineering 34, No 11, 1575–1580.

    Google Scholar 

  30. Nieuwoudt, D.J., Van Deventer, J.S.J., Reuter, M.A. and Ross, V.E. (1990), The influence of design variables on the flotation of pyrite in an air-sparged hydrocyclone, Minerals Engineering 3, No 5, 483–499.

    Article  Google Scholar 

  31. Anon. (1980), Oil Agglomeration offers technical and economical advantages, Mining Engineering 8, 1230–1234.

    Google Scholar 

  32. Kempton, A.G., Moneib, N., Mc Cready, R.G., and Capes, C.E. (1980), Removal of pyrite from coal by conditioning with Thiobacillus ferrooxidans followed by oil agglomeration, Hydrometallurgy 5, 117–125.

    Article  Google Scholar 

  33. Simmons, F.J., and Keller, D.V. (1986), Two ton per day production of Otisca-T process ultra clean coal/water slurry 10th International Coal Preparation Congress Edmonton, Canada, September, pp. 1–8.

    Google Scholar 

  34. Good, R.J., Badgujar, M.N., Huang, H.T.L., Handur-Kulkarni, S.N. (1991), The enhancement of the selectivity of the oil agglomeration for the elimination of iron pyrite from coal, 8` h Annual International Pittsburgh Coal Conference Proceedings, October 1418, pp. 260–265.

    Google Scholar 

  35. Capes, C.E. (1989), Liquid phase agglomeration: process opportunities for economic and environmental challenges, Challenges in Mineral Processing, SME, Littleton, pp. 237–252.

    Google Scholar 

  36. Feng, Y.R., He, S.H., Chiang, S.H., Klinzing, G.E., Mulik, P.R., Yang, W.C. (1994) Further study of the Licado coal cleaning process, 11th Annual Intern. Pittsburgh Coal Conference Proceedings, September 12–16, pp. 582–587.

    Google Scholar 

  37. Attia, Y.A., Krishnan, S.V. and Deason, D.M. (1983), Selective flocculation technology group program, Final Report, June, Batelle-Columbus, Ohio.

    Google Scholar 

  38. Misra, M., Smith, R.W., Dubel, J. and Chen, S. (1993), Selective flocculation of fine coal with hydrophobic Mycobacterium phlei, Minerals and Metallurgical Processing 10, No 1, February, pp. 20–23.

    Google Scholar 

  39. Kindig, J.K. (1991), Middlings grinding and novel fine-coal cleaning produces feedstock for self-scrubbing coal, 8 th Annual International Pittsburgh Coal Conference Proceedings, Sept. 12–16, pp. 231–235.

    Google Scholar 

  40. Fourie, P.J.F. (1980). Dense medium beneficiation of minus 0.5 mm coal in the Republic of South Africa, S th International Conference on Coal Research, Dusseldorf, Germany, 1–5 September, Proceedings vol.Il, pp. 737–747.

    Google Scholar 

  41. Mellanby-Lee, H. (1986), Physical coal beneficiation and electricity costs, ICEAS/C3, February, lEA Coal Research, London.

    Google Scholar 

  42. Wills, B.A. (1985), Coal Preparation, Mining Annual Review, 266–275.

    Google Scholar 

  43. Stevens, C.J., Noah, K.S. and Andrews, G.F. (1993) Large laboratory scale demonstration of combined bacterial and physical coal depyritization, Fuel 72, No 12, 1601–1606.

    Article  Google Scholar 

  44. Isbister, J.D., Kobylinski, E.A. (1985), Microbial desulphurization of coal, Processing and Utilization of High Sulphur Coals, Y. Attia (ed.), Elsevier, New York, Columbus, Ohio, October 13–17, pp. 627–641.

    Google Scholar 

  45. Ryu, H.W., Chang,Y.K. and Kim,S.D. (1993) Microbial coal desulphurization in an airlift bioreactor by sulphur-oxidizing bacterium Thiobacillus ferrooxidans, Fuel Processing Technology 36, 267–275.

    Google Scholar 

  46. Detz, C.M. and Barvinchak, G. (1979) Microbial desulphurization of coal, Mining Congress Journal 7, 75–86.

    Google Scholar 

  47. McCaughey,M.S., and Andrew,G. (1991) An Economic evaluation of microbial desulphurization of coal, 8 th Annual Intern. Pittsburgh Coal Conference Proceedings, 14–18 October, pp. 254–259.

    Google Scholar 

  48. Meyers R.A. (1977), Chemical desulphurization of coal,AICHE Symposium Series, No: 165, vol. 73, 179–182.

    Google Scholar 

  49. Meyers, R.A. (1979), Systems optimises coal desulphurization, Hydrocarbon Processing 58 (16), 123–126.

    Google Scholar 

  50. Markuszewski, R. Mroch, D., Norton, G.A. and Straszheim, W.E. (1986), in R. Markuszewski and B.D. Blaustein (eds.), Coal Desulphurization and Demineralization by Molten Caustic Mixtures,American Chemical Society, Washington, DC,pp. 42–50.

    Google Scholar 

  51. Gray, D. and Sawy, A.E. (1990), Chemical and biodesulphurization systems for removal of organic sulphur from coal: a critical review, National Technical Information Service, Contractors Report DE 90 011 259, NTIS, Springfield, VA.

    Google Scholar 

  52. Chriswell, C.D., Markuszewski, R. (1991), Improved molten caustic cleaning of coal by two-stage leaching, 8th Annual International Coal Conference Proceedings, October 14–18, pp. 305–311.

    Google Scholar 

  53. Meyer, R.A., Hart, W.D., Mc Clanathan, L.C., Ledgerwood, L., Turner, W.D., Maddalone, R.D., Barrish, E.M. and Hardgrove, J.A. (1993), Gravimelt Process for Coal Desulphurization and Mineralization- Multi High Value Products from Coal, IEA 2 nd International Conference on the clean and efficient Use of Coal and Lignite: Its role in Energy, Environment and Life, Hong Kong, 30 November-3 December, p. 869.

    Google Scholar 

  54. Chriswell, C.D., Markuszewski, R. and Jewell, D.V. (1994), Improved caustic coal desulphurization by a float-sink/leaching process employing 50% aqueous NaOH solution, Fuel Processing Technology 37, 19–32.

    Article  Google Scholar 

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Ozbayoglu, G. (1998). Desulphurization of Coal to Protect the Environment. In: Gallios, G.P., Matis, K.A. (eds) Mineral Processing and the Environment. NATO ASI Series, vol 43. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2284-1_10

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  • DOI: https://doi.org/10.1007/978-94-017-2284-1_10

  • Publisher Name: Springer, Dordrecht

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