Skip to main content

Modeling of Organic Liquid Entrapment and Surfactant Enhanced Recovery in Heterogeneous Media

  • Chapter
Computational Methods for Flow and Transport in Porous Media

Part of the book series: Theory and Applications of Transport in Porous Media ((TATP,volume 17))

  • 580 Accesses

Abstract

This paper provides an overview of modeling investigations designed to ex­plore the influence of textural heterogeneities on the migration, persistence, and surfactant enhanced solubilization of organic liquid contaminants in the subsur­face. Multiphase flow and transport simulators are used to model the entrapment and surfactant enhanced recovery of perchloroethylene from saturated media. A laboratory-based linear driving force expression is used to represent solubilization. Simulation results illustrate the influence of local permeability variations and mass transfer limitations on remediation performance. Additional model simulations of a controlled laboratory sandbox experiment are used to highlight the strengths and weaknesses of current modeling approaches.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Abriola, L.M., Modeling migration of organic chemicals in groundwater systems — A review and assessment, Envir. Health Perspectives, 83, 117–143, 1989.

    Google Scholar 

  2. Abriola, L.M., K. Rathfelder, S. Yadav and M. Maiza, VALOR: A PC Code for Simulating Subsurface Immiscible Contaminant Transport, Electric Power Research Institute (TR-101018), Palo Alto, California, 1992.

    Google Scholar 

  3. Abriola, L.M., T.J. Dekker and K.D. Pennell, Surfactant-enhanced solubilization of residual dodecane in soil columns. 2. Mathematical modeling, Environ. Sci. Technol., 27 (12), 2341–2351, 1993.

    Article  Google Scholar 

  4. Abriola, L.M., K.D. Pennell, G.A. Pope, T.J. Dekker and D.J. Luning-Prak, Impact of surfactant flushing on the solubilization and mobilization of dense nonaqueous-phase liquids. in: Surfactant-Enhanced Aquifer Remediation–Emerging Technologies, ACS Symposium Series 594, 11–23, 1995.

    Google Scholar 

  5. Abriola, L.M., W.E. Condit and M.A. Cowell, Investigation of the influence of soil texture on rate limited micellar solubilization, accepted for publication in J. Environmental Engineering, 1999.

    Google Scholar 

  6. Dekker, T.J., An Assessment of the Effects of Field-Scale Formation Heterogeneity on Surfactant Aquifer Remediation, Ph.D. Dissertation, The University of Michigan, 1996.

    Google Scholar 

  7. Dekker, T.J. and L.M. Abriola, The Influence of Field-Scale Heterogeneity on the Surfactant-Enhanced Remediation of Entrapped Nonaqueous Phase Liquids, accepted for publication in J. of Contaminant Hydrology, 1999.

    Google Scholar 

  8. Demond, A.H., K. Rathfelder and L.M. Abriola, Simulation of two-phase flow using estimated and measured transport properties, J. of Contaminant Hydrology, 22 (3–4), 223–239, 1996.

    Article  Google Scholar 

  9. Fountain, J.C., A. Klimek, M.G. Beikirch and T.M. Middleton, The use of surfactants for in situ extraction of organic pollutants from a contaminated aquifer, J. Hazardous Materials, 28, 295–311, 1991.

    Google Scholar 

  10. Jussel, P., F. Stauffer and T. Dracos, Transport modeling in heterogeneous aquifers: 1. Statistical description and numerical generation of gravel deposits, Water Resources Research, 30 (6), 1803–1817, 1994.

    Article  Google Scholar 

  11. Longino, B.L. and B.H. Kueper, Use of upward gradients to arrest downward dense nonaqueous phase liquid (DNAPL) migration in the presence of solubilizing surfactants, Can. Geotech. J., 32, 296–308, 1995.

    Article  Google Scholar 

  12. Mackay, D., W.Y. Shiu, A. Maijanen and S. Feenstra, Dissolution of non-aqueous phase liquids in groundwater. J. of Contaminant Hydrology, 8, 23–42, 1991.

    Article  Google Scholar 

  13. Miller, C.T., M.M. Poirer-McNeill and A.S. Mayer, Dissolution of trapped nonaqueous phase liquids: mass transfer characteristics, Water Resources Research, 26 (11), 2783–2796, 1990.

    Article  Google Scholar 

  14. National Research Council, Alternatives for Ground Water Cleanup, National Academy Press, Washington, D.C., 1994.

    Google Scholar 

  15. Pennell, K.D., L.M. Abriola and W.J. Weber, Surfactant-enhanced solubilization of residual dodecane in soil columns. 1. Experimental investigation, Environ. Sci. Technol., 27 (12), 2232–2340, 1993.

    Article  Google Scholar 

  16. Pennell, K.D., M. Jin, L.M. Abriola and G.A. Pope, Surfactant enhanced remediation of soil columns contaminated by residual tetrachloroethylene, J. of Contaminant Hydrol. 16, 35–53, 1994.

    Article  Google Scholar 

  17. Pennell, K.D., G.A. Pope, and L.M. Abriola, Influence of viscous and buoyancy forces on the mobilization of residual tetrachloroethylene during surfactant flushing, Environmental Science and Technology, 30 (4), 1328–1335, 1996.

    Article  Google Scholar 

  18. Powers, S.E., C.O. Loureiro, L.M. Abriola and W.J. Weber, W.J., Theoretical study of nonequilibrium dissolution of nonaqueous phase liquids in subsurface systems, Water Resources Research, 27 (4), 463–477, 1991.

    Article  Google Scholar 

  19. Powers, S.E., L.M. Abriola and W.J. Weber, An experimental investigation of nonequilibrium dissolution of nonaqueous phase liquids in subsurface systems, Water Resources Research, 28 (10), 2691–2705, 1992.

    Article  Google Scholar 

  20. Powers, S.E., L.M. Abriola, J.S. Dunkin and W.J. Weber, Phenomenological models for transient NAPL-water mass transfer processes, Journal Contam. Hydrol., 16, 1–33, 1994.

    Article  Google Scholar 

  21. Taylor, T.P., K.D. Pennell, L.M. Abriola and J.H. Dane, Surfactant enhanced recovery of tetrachloroethylene from a porous medium containing low permeability lenses 1. Experimental observations, in preparation, for submission to J. Contam. Hydrol., 1999.

    Google Scholar 

  22. Rathfelder, K. and L.M. Abriola, The influence of capillarity in numerical modeling of organic liquid redistribution in two-phase systems, Advances in Water Resources, 21 (2), 159–170, 1998a.

    Article  Google Scholar 

  23. Rathfelder, K.M., T.P. Taylor, L.M. Abriola, and K.D. Pennell, Simulation of the surfactant-enhanced solubilization of PCE in bench-scale laboratory studies, in Proc Remediation of Chlorinated and Recalcitrant Compounds, 1(2):91–96, Batelle Press, Columbus, 1998b.

    Google Scholar 

  24. Sudicky, E.A., A natural gradient experiment on solute transport in a sand aquifer: Spatial variability of hydraulic conductivity and its role in the dispersion process, Water Resources Research, 22 (13), 2069–2082, 1986.

    Google Scholar 

  25. Tompson, A.F.B., R. Ababou and L.W. Gelhar, Implementation of the three-dimensional turning bands random field generator, Water Resources Research, 25 (10), 2227–2243, 1989.

    Article  Google Scholar 

  26. Voss, C.I., USGS SUTRA manual, U.S. Geological Survey National Center, Reston, Va., 1984.

    Google Scholar 

  27. Woodbury, A.D. and E.A. Sudicky, The geostatistical characteristics of the Borden aquifer, Water Resources Research, 27 (4), 533–546, 1991.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2000 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Abriola, L.M. (2000). Modeling of Organic Liquid Entrapment and Surfactant Enhanced Recovery in Heterogeneous Media. In: Crolet, J.M. (eds) Computational Methods for Flow and Transport in Porous Media. Theory and Applications of Transport in Porous Media, vol 17. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-1114-2_20

Download citation

  • DOI: https://doi.org/10.1007/978-94-017-1114-2_20

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-5440-1

  • Online ISBN: 978-94-017-1114-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics