Abstract
The main features concerning the selective activation of light alkanes are described and discussed for heterogeneous catalysts based on oxides and phosphates. These key features are then exemplified using the oxidation of alkanes over vanadium phosphate catalysts, in particular for the oxidation of butane to maleic anhydride. In the final part of the paper a simplified approach for the design of novel catalyst systems, based on D/H and 18O2/16O2 exchange reactions, is described and exemplified.
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Hutchings, G.J. (1998). Selective Oxidation of Light Alkanes. In: Derouane, E.G., Haber, J., Lemos, F., Ribeiro, F.R., Guisnet, M. (eds) Catalytic Activation and Functionalisation of Light Alkanes. NATO ASI Series, vol 44. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0982-8_6
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DOI: https://doi.org/10.1007/978-94-017-0982-8_6
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