Abstract
Many metallo-proteins that catalyse the incorporation of oxygen atoms derived from dioxygen into organic substrates usually contain iron in mono- or polynuclear form. The “Ship-in-a-Bottle” approach proves an interesting approach to synthesise such metal complexes in zeolites and microporous materials [1]. The mechanistic understanding of the iron-containing hemeoxygenases has been substantially advanced (high-valent iron porphyrin oxocomplexes) [2]. In case of iron-containing non-heme-oxygenases such as methane mono-oxygenase [3] our understanding is more limited as only a few suitable models are known.
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Knops-Gerrits, P.P., Jacobs, P.A. (1998). Mono- and Binuclear Iron Complexes in Zeolites, Clays and Mesoporous Oxides as Biomimetic Catalysts. In: Derouane, E.G., Haber, J., Lemos, F., Ribeiro, F.R., Guisnet, M. (eds) Catalytic Activation and Functionalisation of Light Alkanes. NATO ASI Series, vol 44. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0982-8_18
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DOI: https://doi.org/10.1007/978-94-017-0982-8_18
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