Abstract
Transformation of low molecular weight alkanes to alkenes and aromatics via oxidative and non-oxidative routes presents a major challenge since the implementation of the “Cyclar” process. Catalysts containing ZSM-5 zeolite modified with Ga or Zn species were investigated widely for this purpose [1]. Recently other zeolites (faujasite, ferrierite, Beta) were studied in the title reaction [2,3]. We showed that the already few gallium ions accommodated by the faujasite matrix significantly increase the selectivity to propene [2]. Preliminary results on zeolite Beta modified with Ga- and B-species [3] have also shown that this structure possesses promising activity and selectivity in the oxidative dehydrogenation (ODH) of propane.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
B. Sulikowski, Heterogeneous Chemistry Reviews, 3, (3), 203–268 (1996).
B. Sulikowski, Z. Olejniczak, V. Cortés Corberân, J Phys. Chem., 100, (24), 10323–30 (1996).
V. Cortés Corberán, R. X. Valenzuela, B. Sulikowski, M. Derewinski, Z. Olejniczak, J. Kry_ciak, Catalysis Today, 32, (1–4), 193–204 (1996).
W.M. Meier, D.H. Olson, Ch. Baerlocher, “Atlas of Zeolite Structure Types”, 4th edition, Elsevier, London, 1996, p. 62.
M. Derewinski, F. Fajula, Appl. Catal. A, 108, 53–61 (1994).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Derewinski, M. et al. (1998). Oxidative Dehydrogenation of Propane on Large-Pore Zeolites. In: Derouane, E.G., Haber, J., Lemos, F., Ribeiro, F.R., Guisnet, M. (eds) Catalytic Activation and Functionalisation of Light Alkanes. NATO ASI Series, vol 44. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0982-8_16
Download citation
DOI: https://doi.org/10.1007/978-94-017-0982-8_16
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-4999-5
Online ISBN: 978-94-017-0982-8
eBook Packages: Springer Book Archive