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Catalytic Activation and Functionalisation of Light Alkanes pp 369–388Cite as

Molecular Chemistry of Alkane Activation

Formation and Reactions of CHx species on Metal Surfaces

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Part of the book series: NATO ASI Series ((ASHT,volume 44))

Abstract

The results obtained on the formation, stability and reactions of CXHy hydrocarbon fragments (CH2, CH3, C2H5 and C3H7) on metal single crystal surfaces, particularly on Rh and Pd, are summarized and discussed. CXHy species are produced by thermal and photo-induced dissociation of corresponding iodo compounds. Methods used include X-ray and ultraviolet photoelectron spectroscopy, high resolution electron energy loss spectroscopy and temperature programmed desorption. Studies performed on supported metals on the chemistry of CXHy fragments and on the reaction of adsorbed CH3 and gaseous CO2 are also reported.

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Author information

Authors and Affiliations

  1. Institute of Solid State and Radiochemistry, A. József University and Reaction Kinetics Research Group of the Hungarian Academy of Sciences, P.O. Box 168, H-6701, Szeged, Hungary

    F. Solymosi

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  1. F. Solymosi
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Editor information

Editors and Affiliations

  1. Leverhulme Centre for Innovative Catalysis, University of Liverpool, UK

    Eric G. Derouane

  2. Polish Academy of Sciences, Krakow, Poland

    Jerzy Haber

  3. Instituto Superior Técnico, Lisboa, Portugal

    Francisco Lemos  & Fernando Ramôa Ribeiro  & 

  4. Université de Poitiers, Poitiers, France

    Michel Guisnet

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© 1998 Springer Science+Business Media Dordrecht

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Solymosi, F. (1998). Molecular Chemistry of Alkane Activation. In: Derouane, E.G., Haber, J., Lemos, F., Ribeiro, F.R., Guisnet, M. (eds) Catalytic Activation and Functionalisation of Light Alkanes. NATO ASI Series, vol 44. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0982-8_14

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  • DOI: https://doi.org/10.1007/978-94-017-0982-8_14

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4999-5

  • Online ISBN: 978-94-017-0982-8

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