Abstract
The environmental chemistry of beryllium (Be) was investigated at the Lysina catchment in western Bohemia, Czech Republic, a forest ecosystem with high loadings of acidic atmospheric deposition. The catchment supports Norway spruce plantations; it is underlain by leucogranite and the soils are Spodosols. Average concentrations of Be were high in groundwater (3.3 µg L−1) and in stream water (1.5 µg L−1), in comparison to the drinking water standard of the Czech Republic (0.2 µg L−1). Chemical equilibrium calculations suggest that aquoberyllium Be2+ was the prevailing inorganic species in drainage waters at the site. Atmospheric deposition of Be (45 µg m−2 yr−1) was small in comparison to drainage outflow (586 µg m −2 yr−1) at Lysina. Elevated Be concentrations in drainage water appear to be the result of the mobilization of Be from soils and weathered bedrock due to acidic atmospheric deposition. Increased mobility of Be due to acidification may have serious ecological consequences in acid-sensitive areas with terrestrial pools of available Be.
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References
Anonymous: 1992, CSN 73 6053, Vydavatelstvi Norem, Prague.
Baes Jr., C.F. and Mesmer, R.E.: 1976, The Hydrolysis of Cations, John Wiley and Sons, New York.
Bouska, V. and Pesek, J.: 1997, Distribution of Sulfur and Arsenic in Coal of the Sokolov Basin, Research Report, Charles University, Prague (in Czech).
Breiter, K.: 1988, Silicate Analyses–Database, Czech Geological Survey, Prague. Breiter, K.: 1996, “Granites of the Slavkov Forest,” in Conference Proceedings: Mining Past and Future of the Slavkov Forest, Okresni Muzeum Sokolov, Sokolov, Czech Republic, pp. 25–44 (in Czech).
Buzek, F., Hruska, J. and Kram, P.: 1995, Water, Air, Soil Pollut. 79, 391.
Klein, C., and Hurlbut, Jr, C.S.: 1985, Manual ofMineralogy afterJ.D. Dana, 20th Edition, John Wiley and Sons, New York.
Kram, P. and Hruska, J.: 1994, Appl. Hydrogeol. 2/94, 50.
Kram, P., Hruska, J., Driscoll, C.T. and Johnson, C.E.: 1995, Water, Air, Soil Pollut. 85, 1831.
Kram, P., Hruska, J., Wenner, B.S., Driscoll, C.T. and Johnson, C.E.: 1997, Biogeochemistry 37, 173.
Kubiznakova, J.: 1987a, “Behavior of Beryllium in the Sokolov District”, in B. Moldan and T. Paces (eds.), GEOMON Extended Abstracts, Czech Geol. Survey, Prague, pp. 188–190.
Kubiznakova, J.: 1987b, Water, Air, Soil Pollut. 34, 363.
Martin, R.B.: 1986, “Bioinorganic Chemistry of Metal Ion Toxicity”, in H. Sigel (ed.), Metal Ions in Biological Systems, Vol. 20, Concept on Metal Ion Toxicity, Marcel Dekker, New York.
Moldan, B. and Schnoor, J.L.: 1992, Environ. Sci. Technol. 26, 14.
Moore, J.W.: 1991, “Beryllium”, in Inorganic Contaminants of Surface Water-Research and Monitoring Priorities, Springer Series on Environmental Management, Springer-Verlag, New York, pp. 50–56.
Panzer, R.E.: 1985, “Beryllium, Magnesium, Calcium, Strontium, Barium, and Radium”, in A.J. Bard, R. Parsons and J. Jordan (eds.), Standard Potentials in Aqueous Solutions, Int. Union Pure Appl. Chem., Marcel Dekker, New York, pp. 675–686.
Pontius, F.W.: 1993, Am. Water Works Assoc. J. 85, 42.
Schecher, W.D. and McAvoy, D.C.: 1991, MINEQL‘: A Chemical Equilibrium Program for Personal Computers - User’s Manual, Version 2.1., Environ. Res. Software, Edgewater, Maryland.
Veselÿ, J.: 1994, “Effects of Acidification on Trace Metal Transport in Fresh Waters”, in C.E.W.. Steinberg and R.F. Wright (eds.), Acidification of Freshwater Ecosystems, John Wiley & Sons, Chichester, pp. 141–151.
Veselÿ, J., P. Benes, and K. Sevcik: 1989, Water Res. 23, 711.
Wong, C.Y., and J.D. Woolins: 1994, Coord. Chem. Rev., 130, 243.
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Krám, P., Hruška, J., Driscoll, C.T. (1998). Beryllium Chemistry in the Lysina Catchment, Czech Republic. In: Wieder, R.K., Novák, M., Černý, J. (eds) Biogeochemical Investigations at Watershed, Landscape, and Regional Scales. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0906-4_37
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DOI: https://doi.org/10.1007/978-94-017-0906-4_37
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