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NMR of Ordered Liquids pp 137–161Cite as

NMR of Partially Ordered Solutes with Emphasis on Structure Determination

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Abstract

The 1963 observation of Englert and Saupe [1] that the 1HNMR spectrum of benzene in a nematic liquid crystalline phase has a complex appearance compared to a single line in an isotropic medium (Fig. 7.1) has led to the discovery of a new method for the determination of molecular structure. It provides the only direct method for the precise determination of molecular geometries in the liquid phase and is the latest addition to the earlier existing list of methods such as X-ray, neutron and electron diffractions and microwave spectroscopy.

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Authors and Affiliations

  1. Sanjay Gandhi Post Graduate Institute of Medical Sciences, Lucknow, India

    C. L. Khetrapal & G. A. Nagana Gowda

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  1. C. L. Khetrapal
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Editors and Affiliations

  1. University of British Columbia, Canada

    E. Elliott Burnell

  2. University of Amsterdam, The Netherlands

    Cornelis A. de Lange

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Khetrapal, C.L., Gowda, G.A.N. (2003). NMR of Partially Ordered Solutes with Emphasis on Structure Determination. In: Burnell, E.E., de Lange, C.A. (eds) NMR of Ordered Liquids. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0221-8_7

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