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Multiple Quantum NMR Spectroscopy in Orientationally Ordered Fluids

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NMR of Ordered Liquids

Abstract

Most compounds that form a liquid crystalline phase are able to dissolve a small amount of solute compound without destroying the structure of the mesophase. Since the first reports of using liquid crystals as solvents for NMR spectroscopy, high resolution NMR in liquid crystalline solution has developed into an important area [ 1]. The amount of solute that can be dissolved in a nematic mesophase depends on the mesophase and the solute, but solute concentrations of 5% w/ w are common and concentrations of 10 – 15% w/ w or higher are sometimes achievable without disrupting the liquid crystalline properties of the solvent.

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Field, L.D. (2003). Multiple Quantum NMR Spectroscopy in Orientationally Ordered Fluids. In: Burnell, E.E., de Lange, C.A. (eds) NMR of Ordered Liquids. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0221-8_4

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  • DOI: https://doi.org/10.1007/978-94-017-0221-8_4

  • Publisher Name: Springer, Dordrecht

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