Abstract
Thermal stresses in a fibre reinforced composite are determined by the interaction between the solidifying matrix and the fibre. In composites with a semicrystalline matrix solidification is associated with crystallisation. In semicrystalline thermoplastic matrix composites transcrystallisation often takes place. Transcrystallisation occurs when spherulities are heterogeneously nucleated on the fibre surface. As the spherulities impinge they grow radially from the fibre forming the transcrystalline interlayer.
For a brittle fibre in a polymer matrix, the resulting residual stresses may exceed the compressive strength of the fibre. The fragmentation of the fibre is dependent on the load transfer from the fibre to the matrix and the transcrystalline interlayer plays a dominant role in controlling the level of thermal residual stresses.
Polarised Raman microspectroscopy has been used to determine crystal orientation within the transcrystalline interlayer of a carbon/polypropylene matrix composite. From the Raman scattering on samples subjected to varied thermal history a model of the conformational states within the microstructure of the polypropylene was proposed. This model is comprised of three phases: a crystalline phase, an isomeric defect phase and an amorphous melt like phase. Effective properties of the polymer can be predicted from the derived local response in terms of the parameters characterising the crystalline microstructure.
Having established a valid model for the thermal stress evolution, it is possible to determine the thermal stress distribution after cooling of the composite. In semicrystalline matrix systems cooling rate was found to have a pronounced effect on thermal stresses due to the rate dependence of the crystallisation as well as stress relaxation in the matrix. Theoretical predictions were compared to experimental results of thermal stresses and a close agreement was obtained.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Nairn, J.A. and Zoller, P., Mater. Sci. 20 (1985), 355.
Nielsen, A.S. and Pyrz, R., Polym. Polym. Compos. 5 (1997), 245.
Nielsen, A.S. and Pyrz, R., Sci. Engng. Comp. Mater. 7 (1998), 1–22.
Bower, D.I. and Maddams, W.F.:TheVibrational Spectroscopy ofPolymers, cambridge University Press, Cambridge, 1992.
Tashiro, K., Kobayashi, M. and Tadokoro, H., Polymer Journal, 24 (1992), 899.
Isasi, J.R., Alamo, R.G. and mandelkem, L., J. Polym. Sci.: Polymer Physics, 35 (1997).
Nielsen, A.S., Pyrz, R. and Batchelder, D.N., submitted to J. Mater. Sci. (2001).
Ozawa, T., Polymer, 12 (1971).
Nielsen, A.S. and Pyrz, R., submitted to J. Polym. Sci.: Polymer Physics (2001).
Nielsen, A.S. Micromechanical Modelling of Thermal Stresses in Polymer Matrix Composites Based on Raman Microscopy, Ph. D. thesis, Special Report No. 43, Institute of Mechanical Engineering, Aalborg University (2000).
Schapery, R.A., J. Campos. Mater. 1 (1967), 228.
Markwort, L. and Kip, B., J. Appl. Polym. Sci. 61 (1996), 231–254.
Schadler, L.S. and Galiotis, C., Int. Mater. Reviews 40 (1995), 116–134.
Nielsen, A.S. and Pyrz, R., Composite Interfaces 6 (1999), 467–482.
Thomsen, J.S., and Pyrz. R., Comp. Sci. Technol., 59 (1999), 1375–1385.
Thomsen, J.S. and Pyrz, R., Comp. Sci. Technol. 60 (2000), 1791–1800.
Pyrz, R. (ed.), Sci. Engng. Comp Mater. 7 (1998), 1–204.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Nielsen, A.S., Pyrz, R. (2002). Fibre Failure due to Thermal Residual Stresses in Model Polymer Based Composites. In: Karihaloo, B.L. (eds) IUTAM Symposium on Analytical and Computational Fracture Mechanics of Non-Homogeneous Materials. Solid Mechanics and Its Applications, vol 97. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-0081-8_36
Download citation
DOI: https://doi.org/10.1007/978-94-017-0081-8_36
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-5977-2
Online ISBN: 978-94-017-0081-8
eBook Packages: Springer Book Archive