Abstract
In this chapter, we review the preparation, separation, and characterization of a new family of trimetallic nitride template (TNT) endohedral metallofullerenes AnB3−nN@C2x (n = 0–3, x = 34, 39, and 40) where A and B are metals (Group III and rare earths) that are formed in relatively high yields. The archetypal representative of this new class is the stable endohedral metallofullerene, Sc3N@C80 containing a triscandium nitride cluster encapsulated in an icosahedron (Ih), C80 cage. Other prominent TNT members are Sc3N@C68 and Sc3N@C78. The former Sc3N@C68 molecule represents an exception to the well known isolated pentagon rule (IPR).
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References
S. Shinohara, Rep. Prog. Phys. 63, 843–892 (2000).
S. Nagase, K. Kobayashi, and T. Akasaka, in The Chemistry and Physics of Fullerenes and Related Materials, K. M. Kadish and R. S. Ruoff, Ed., The Electrochemical Society, Inc., Pennington, 1995, pp. 747–776.
S. Nagase, K. Kobayashi, and T. Akasaka, Bull. Chem. Soc. Jpn. 69, 2131–2142 (1996).
Krätschmer, W., Fostiropoulos, K., and Huffman, D. R., Chem. Phys. Lett. 1990, 170, 167–170.
S. Stevenson, G. Rice, T. Glass, K. Harich, F. Cromer, M. R. Jordan, J. Craft, E. Hajdu, R. Bible, M. M. Olmstead, K. Maitra, A. J. Fischer, A. L. Balch, and H. C. Dorn, Nature 401, 55 (1999).
M. M. Olmstead, A. de Bettencourt-Dias, J. C. Duchamp, S. Stevenson, H. C. Dorn, and A. L. Balch, J. Am. Chem. Soc. 122, 12220–12226 (2000).
S. Stevenson, P. W. Fowler, T. Heine, J. C. Duchamp, G. Rice, T. Glass, K. Harich, E. Hajdu, R. Bible, and H. C. Dorn, Nature 408, 427–428 (2000).
M. H. Olmstead, A. de Bettencourt-Dias, J. C. Duchamp, S. Stevenson, D. Marciu, H.C. Dorn, and A. L. Balch, Angew. Chem. Int. Ed. 40, 1223–1227 (2001).
H. C. Dorn, S. Stevenson, J. Craft, F. Cromer, J. C. Duchamp G. Rice, T. Glass, K. Harich, P. W. Fowler, T. Heine, E. Hajdu, R. Bible, M. M. Olmstead, K. Maitra, A. J. Fischer, and A. L. Balch, Proc. IWEPNM2000 Conf. (Kirchberg, Austria), 135 (2000).
E. B. Iezzi, F. Cromer, and H. C. Dorn, Chem. Commun. submitted (2001).
A. Thess, R. Lee, P. Nikolaev, H. Dai, P. Petit, J. Robert, C. Xu, Y. H. Lee, S. G. Kim, A. G. Rinzler, D. T. Colbert, G. E. Scuseria, D. Tomanek, J. E. Fischer, and R. E. Smalley, Science, 273–483 (1996).
The relative yields for the Group III and representative rare-earths were obtained from graphite rods separately packed with a mixture consisting of a given metal oxide (A2O3), scandium oxide (Sc2O3), cobalt oxide CoO, and powdered graphite. In all cases, the rods contained 2% of scandium metal (by mass) and 3% metal A. For example, for the Sc/Y data the rods contained Y2O3 (1189 mg) Sc2O3 (484 mg) CoO (180 mg) and C graphite (1000 mg). The packed rods were subsequently vaporized in a Krätschmer-Huffman generator. The NI-DCI mass spectra for the carbon disulfide soluble extract was obtained and the yields were referenced relative to Sc3@C84 (Figure 2) or Sc3N@C68 (Figure 3).
T. Akasaka et al., Angew. Chem. Int. Ed. Engl. 36, 1643–1645 (1997).
H. Huang and S. J. Yang, Phys. Chem. 101, 10196 (1998).
D. Sun, Z. Liu, X. Guo, W. Xu, and S. Lin, J. Phys. Chem. B 101, 3927 (1997).
P. Strange, A. Suane, W. W. Temmeuman, Z. Szotet, and H. Winter, Nature 399, 756 (1999).
K. Kobayashi and S. Nagase, Chem. Phys. Lett. 262, 227–232 (1996).
K. Kobayashi, S. Nagase, and T. Akasaka, Chem. Phys. Lett. 261, 502–506 (1996).
K. Kobayashi and S. Nagase, Chem. Phys. Lett. 282, 325 (1998).
M. Takata, E. Nishibori, B. Umeda, M. Saketa, E. Yamatoto, and H. Shinohara, Phys. Rev. Lett. 78, 330 (1997).
M. Takata, E. Nishibori, M. Sakata, M. Inakuma, E. Yamamoto, and H. Shinohara, Physical Review Letters 83, 2214 (1999).
A. L. Balch and M. M. Olmstead, Chem. Rev. 98, 2123 (1998).
A. Aihara, Chem. Phys. Lett. 343, 465–469 (2001).
C. R. Wang T. Kai, T. Tomiyama, T. Yoshida, Y. Kobayashi, E. Nishibori, M. Takata, M. Sakata, and H. Shinohara, Nature 408, 426–427 (2000).
R. M. MacFarlane, D. S. Bethune, S. Stevenson, and H. C. Dorn, Chem. Phys. Lett. 343, 229–234 (2001).
P. Jakes and K. P. Dinse, J. Am. Chem. Soc. 123, 8854 (2001).
K. Kobayashi, Y. Sano, and S. Nagase, J. of Computational Chemistry 22, 1353 (2001).
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Dorn, H.C., Iezzi, E.B., Stevenson, S., Balch, A.L., Dunchamp, J.C. (2002). Trimetallic Nitride Template (TNT) Endohedral Metallofullerenes. In: Akasaka, T., Nagase, S. (eds) Endofullerenes. Developments in Fullerene Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-9938-2_5
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DOI: https://doi.org/10.1007/978-94-015-9938-2_5
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