Abstract
Chemical functionalization of endohedral metallofullerenes is an important direction for creation of novel materials based on endohedral metallofullerenes. Recent progress in the experimental and theoretical studies of chemical properties of endohedral metallofullerenes and their ions is reviewed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
For reviews, see: (a) D. S. Bethune, R. D. Johnson, J. R. Salem, M. S. de Vries, and C. S. Yannoni, Nature 366, 123 (1993);
H. Shinohara, Rep. Prog. Phys. 63, 843 (2000);
c) H. Shinohara, in: Fullerenes: Chemistry, Physics and Technology; K. M. Kadish and R. S. Ruoff, Eds.; John Wiley and Sons; New York, 2000; p. 357.
For reviews, see: (a) S. Nagase, K. Kobayashi, and T. Akasaka, Bull. Chem. Soc. Jpn. 69, 2131 (1996);
S. Nagase, K. Kobayashi, and T. Akasaka, J. Mol. Struct. (Theochem) 398, 221 (1997);
S. Nagase, K. Kobayashi, and T. Akasaka, J. Comput. Chem. 19, 232 (1998);
S. Nagase, K. Kobayashi, and T. Akasaka, J. Mol. Struct. (Theochem) 1461–1462, 97 (1999);
e) S. Nagase, K. Kobayashi, T. Akasaka, and T. Wakahara, in: Fullerenes: Chemistry, Physics and Technology, K. M. Kadish and R. S. Ruoff, Eds., John Wiley and Sons; New York, 2000; p. 395.
S. Nagase and K. Kobayashi, Chem. Phys. Lett. 228, 106 (1994).
S. Nagase and K. Kobayashi, J. Chem. Soc., Chem. Commun. 1837 (1994).
K. Kikuchi, Y. Nakao, S. Suzuki, Y. Achiba, T. Suzuki, and Y. Maruyama, J. Am. Chem. Soc. 116, 9367 (1994).
T. Suzuki, Y. Maruyama, T. Kato, K. Kikuchi, and Y. Achiba, J. Am. Chem. Soc. 115, 11006 (1993).
K. Yamamoto, H. Funasaka, T. Takahashi, T. Akasaka, T. Suzuki, and Y. Maruyama, J. Phys. Chem. 98, 12831 (1994).
T. Suzuki, K. Kikuchi, F. Oguri, Y. Nakao, S. Suzuki, Y. Achiba, K. Yamamoto, H. Funasaka, and T. Takahashi, Tetrahedron 52, 4973 (1996).
T. Akasaka, S. Okubo, M. Kondo, Y. Maeda, T. Wakahara, T. Kato, T. Suzuki, K. Yamamoto, K. Kobayashi, and S. Nagase, Chem. Phys. Lett. 319, 153 (2000).
T. Akasaka, S. Nagase, K. Kobayashi, T. Suzuki, T. Kato, K. Yamamoto, H. Funasaka, and T. Takahashi, J. Chem. Soc., Chem. Commun. 1343 (1995).
S. Nagase and K. Kobayashi, Chem. Phys. Lett. 214, 57 (1993).
a) R. D. Johnson, M. S. de Vries, J. Salem, D. S. Bethune, C. S. Yannoni, Nature 355, 239 (1992);
S. Suzuki, S. Kawata, H. Shiromaru, K. Yamauchi, K. Kikuchi, T. Kato, and Y. Achiba, J. Phys. Chem. 96, 7159 (1992);
S. Bandow, H. Kitagawa, T. Mitani, H. Inokuchi, Y. Saito, H. Yamaguchi, N. Hayashi, H. Sato, and H. Shinohara, J. Phys. Chem. 96, 9609 (1992);
K. Kikuchi, S. Suzuki, Y. Nakao, H. Nakahara, T. Wakabayashi, H. Shiromaru, K. Saito, I. Ikemoto, and Y. Achiba, Chem. Phys. Lett. 216, 67 (1993);
K. Yamamoto, H. Funasaka, T. Takahashi, and T. Akasaka, J. Phys. Chem. 98, 208 (1994).
a) M. Inakuma, M. Ohno, and H. Shinohara, in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, K. M. Kadish and R. S. Ruoff, Eds., John Wiley and Sons; New York, 1995; Vol. 2, p. 330;
b) M. Hoinkis, C. S. Yannoni, D. S. Bethune
J. R. Salem, R. D. Johnson, M. S. Crowder, M. S de Vries, Chem. Phys. Lett. 198, 461 (1992).
M. Fujitsuka, O. Ito, K. Kobayashi, S. Nagase, K. Yamamoto, T. Kato, T. Wakahara, and T. Akasaka, Chem. Lett., 902 (2000).
K. Kikuchi, K. Sueki, K. Akiyama, K. Komada, H. Nakahara, I Ikemoto, and T. Akasaka, in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials
K. M. Kadish and R. S. Ruoff, Eds., The Electrochemical Society; Pennington, NJ, 1997; Vol. 4, p. 408.
For recent reviews, see: (a) A. Hirsch, The Chemistry of the Fullerenes; Thieme, New York, 1994;
The Chemistry of Fullerenes,R. Taylor, Ed., World Scientific; London, 1995;
Fullerenes and Related Structures,A. Hirsch, Ed., Springer; Berlin, 1999;
Fullerenes: Chemistry, Physics and Technology; K. M. Kadish and R. S. Ruoff, Eds., John Wiley and Sons; New York, 2000.
a) T. Akasaka, W. Ando, K. Kobayashi, and S. Nagase, J. Am. Chem. Soc. 115, 1605 (1993);
T. Akasaka, W. Ando, K. Kobayashi, and S. Nagase, J. Am. Chem. Soc. 115, 10366 (1993);
T. Akasaka, W. Ando, K. Kobayashi, and S. Nagase, J. Am. Chem. Soc. 116, 2627 (1994);
T. Suzuki, Y. Maruyama, T. Akasaka, W. Ando, K. Kobayashi, and S. Nagase, J. Am. Chem. Soc. 116, 1359 (1994);
T. Akasaka, W. Ando, K. Kobayashi, and S. Nagase, Trans. Mat. Res. Soc. Jpn. 14B, 1091 (1994);
T. Akasaka, W. Ando, K. Kobayashi, and S. Nagase, in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials; K. M.
Kadishand R. S. Ruoff, Eds., The Electrochemical Society; Pennington, NJ, 1994; Vol. 1, p. 723; 1995; Vol. 2, p. 1125;
T. Akasaka, E. Mitsuhida, W. Ando, K. Kobayashi, and S. Nagase, J. Chem. Soc., Chem. Commun., 1529 (1995);
T. Akasaka, Y. Maeda, T. Wakahara, T. Mizushima, W. Ando, M. Waelchli, T. Suzuki, K. Kobayashi, S. Nagase, M. Kako, Y. Nakadaira, M. Fujitsuka, O. Ito, Y. Sasaki, K. Yamamoto, T. Erata, Org. Lett. 2, 2671 (2000);
Y. Maeda, R. Sato, T. Wakahara, M. Okamura, T. Akasaka, M. Fujitsuka, O. Ito, K. Kobayashi, S. Nagase, M. Kako, Y. Nakadaira, and E. Horn, J. Organomet. Chem. 611, 414 (2000);
T. Wakahara, T. Kondo, M. Okamura, T. Akasaka, Y. Hamada, T. Suzuki, M. Kako, and Y. Nakadaira, J. Organomet. Chem. 611, 78 (2000);
Y. Maeda, S. Takahashi, T. Wakahara, T. Akasaka, Y. Sasaki, M. Fujitsuka, O. Ito, K. Kobayashi, S. Nagase, M. Kako, and Y. Nakadaira, ITE Letters on Batteries, New Technologies liuya Medicine 1, 408 (2000);
) T. Akasaka, T. Suzuki, Y. Maeda, M. Ara, T. Wakahara, K. Kobayashi, S. Nagase, M. Kako, Y. Nakadaira, M. Fujitsuka, and O. Ito, J. Org . Chem. 64, 566 (1999);
T. Akasaka, Y. Maeda, T. Wakahara, M. Okamura, M. Fujitsuka, O. Ito, K. Kobayashi, S. Nagase, M. Kako, Y. Nakadaira, and E. Horn, Org. Lett. 1, 1509 (1999).
T. Akasaka, T. Kato, K. Kobayashi, S. Nagase, K. Yamamoto, H. Funasaka, and T. Takahashi, Nature 374, 600 (1995).
T. Akasaka, S. Nagase, K. Kobayashi, T. Suzuki, T. Kato, K. Yamamoto, H. Funasaka, and T. Takahashi, J. Chem. Soc., Chem. Commun., 1343 (1995).
T. Akasaka, T. Kato, S. Nagase, K. Kobayashi, K. Yamamoto, H. Funasaka, and T. Takahashi, Tetrahedron 52, 5015 (1996).
T. Suzuki, Y. Maruyama, T. Kato, T. Akasaka, K. Kobayashi, S. Nagase, K. Yamamoto, H. Funasaka, and T. Takahashi, J. Am. Chem. Soc. 117, 9606 (1995).
T. Kato, T. Akasaka, K. Kobayashi, S. Nagase, K. Yamamoto, H. Funasaka, and T. Takahashi, Appl. Magnetic Resonance 11, 293 (1996).
T. Akasaka, S. Nagase, K. Kobayashi, T. Suzuki, T. Kato, K. Kikuchi, Y. Achiba, K. Yamamoto, H. Funasaka, and T. Takahashi, Angew. Chem., Int. Ed. Engl. 34, 2141 (1995).
K. Kobayashi, S. Nagase, and T. Akasaka, Chem. Phys. Lett. 245, 230 (1995).
T. Akasaka, Y. Maeda, T. Wakahara, K. Kobayashi, and S. Nagase, unpublished results.
S.-R. Zhang, D.-Y. Sun, X.-Y. Li, F.-K. Pei, S.-Y. Liu, Fuller. Sci. Technol. 5, 1635 (1997);
D.-Y. Sun, H.-J. Huang, S.-H. Yang, Z.-Y. Liu, S.-Y. Liu, Chem. Mater. 11, 1003 (1999).
H. Kato, K. Suenaga, M. Mikawa, M. Okumura, N. Miwa, A. Yashiro, H. Fujimura, A. Mizuno, Y. Nishida, K. Kobayashi, and H. Shinohara, Chem. Phys. Let. 324, 255 (2000).
a) M. Saunders, H. A. Jiminez-Vazquez, R. J. Cross, S. Mroczkowski, D. I.Freedberg, F. A. L.
Anet, Nature,367, 256 (1994); (b) M. Saunders and R. J. Cross, H. A. Jimenez-Vazquez, R. Shimshi, and A. Khong, Science 271 1693 (1996).
a) B. Nuber, and A. J. Hirsch, Chem. Soc. Chem. Commun., 1421 (1996);
K. Prassides, M. Keshavarz-K, J. C. Hummelen, W. Andreoni, P. Giannozzi, E. Beer, C. Bellavia, L. Cristofolini, R. Gonzalez, A. Lappas, Y. Murata, M. Malecki, V. Srdanov, and F. Wudl, Science 271, 1833 (1996);
c) C. Bellavia-Lund, M. Keshavarz-K, T. Collins, and F. Wudl, J. Am. Chem. Soc. 119, 8101 (1997);
A. Gruss, K.-P. Dinse, A. Hirsch, B. Nuber, and U. Reuther, J. Am. Chem. Soc. 119, 8728 (1997);
e) K. Hasharoni, C. Bellavia-Lund, M. Keshavarz-K., G. Srdanov, and F. Wudl, J. Am. Chem. Soc. 119, 11128 (1997);
M. Buehl, A. Curioni, and W. Andreoni, Chem. Phys. Lett. 274, 231 (1997);
g) T. Pichler, M. Knupfer, M. S. Golden, S. Haffner, R. Friedlein
J. Fink, W. Andreoni, A. Curioni, M. Keshavarz-K, C. Bellavia-Lund, A. Sastre, J.-C. Hummelen, and F. Wudl, Phys. Rev. Lett. 78, 4249 (1997).
T. Akasaka, S. Okubo, T. Wakahara, K. Kobayashi, S. Nagase, M. Kako, Y. Nakadaira, T. Kato
K. Yamamoto, H. Funasaka, and K. Matsuura, Chem. Lett., 945 (1999).
T. Akasaka, T. Wakahara, S. Nagase, K. Kobayashi, M. Waelchli, K. Yamamoto, M. Kondo, S. Shirakura, S. Okubo, Y. Maeda, T. Kato, M. Kako, Y. Nakadaira, R. Nagahata, X. Gao, E. Van Caemelbecke, and K. M. Kadish, J. Am. Chem. Soc. 122, 9316 (2000).
T. Akasaka, S. Nagase, K. Kobayashi, M. Waelchli, K. Yamamoto, H. Funasaka, M. Kato, T. Hoshino, and T. Erata, Angew. Chem. Int. Ed. Engl. 36, 1643 (1997).
P. W. Fowler and D. E. Manolopoulos, An Atlas of Fullerenes; Clarendon; Oxford, 1995.
K. Kobayashi and S. Nagase, Chem. Phys. Lett. 282, 325 (1998).
For the BLYP method, see: (a) A. D. Becke, Phys. Rev. A 38 3098 (1988);
C. Lee, W. Yang, and R. G. Parr, Phys. Rev. B 37, 785 (1988).
For the relativistic effective core potential on La, see: P. J. Hay, and W. R. Wadt, J. Chem. Phys. 82 299 (1985). The basis sets employed were (5s5p3d)/[4s4p3d1 for La and 3–21G for C. All calculations were carried out using the Gaussian 98 program.
M. Nomura, Y. Nakao, K. Kikuchi, and Y. Achiba, Physica B 208liuya209, 539 (1995).
M. Takata, E. Nishibori, B. Umeda, M. Sakata, M. Inakuma, and H. Shinohara, Chem. Phys. Lett. 298, 79 (1998).
K. Kobayashi and S. Nagase, Chem. Phys. Lett. 282, 325 (1998).
T. Akasaka, T. Wakahara, S. Nagase, K. Kobayashi, M. Waelchli, K. Yamamoto, M. Kondo, S. Shirakura, Y. Maeda, T. Kato, M. Kako, Y. Nakadaira, X. Gao, E. Van Caemelbecke, K. M. Kadish, J. Phys. Chem. B 105, 2971 (2001).
T. Wakahara, S. Okubo, M. Kondo, Y. Maeda, T. Akasaka, M. Waelchli, K. Kobayashi, S. Nagase, T. Kato, K. Yamamoto, M. Kako, X. Gao, E. Van Caemelbecke, K. M. Kadish, unpublished result.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Wakahara, T., Akasaka, T., Kobayashi, K., Nagase, S. (2002). Chemical Properties of Endohedral Metallo-Fullerene and Its Ions. In: Akasaka, T., Nagase, S. (eds) Endofullerenes. Developments in Fullerene Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-9938-2_11
Download citation
DOI: https://doi.org/10.1007/978-94-015-9938-2_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-6159-1
Online ISBN: 978-94-015-9938-2
eBook Packages: Springer Book Archive