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Carbohydrates pp 294–318Cite as

Chemistry of polysaccharide modification and degradation

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Abstract

Polysaccharides offer a vast array of primary structures and conformations. Their ubiquitous presence and diverse roles in biological systems bear testimony to the wide spectrum of functionalities. It has long been recognized that the characteristics and utility of native polysaccharides can be substantially extended by chemical modification. The alterations of parameters, such as primary structure, conformation, hydrophilicity, solubility, polyelectrolyte nature, rheology and stability may profoundly impact their biological, chemical and physical properties. Such modulations can therefore be employed to tailor functional properties. As a result, a wealth of synthetic technology has been established since the discovery by John Hyatt of the first glycan derivative, cellulose nitrate, in 1869.

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  1. Manssur Yalpani
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  1. Centre for Chemical Sciences, Royal Holloway, University of London, UK

    Paul Finch

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Yalpani, M. (1999). Chemistry of polysaccharide modification and degradation. In: Finch, P. (eds) Carbohydrates. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-9281-9_8

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