Skip to main content

Metamorphism of Marbles: Role of Feedbacks between Reaction, Fluid Flow, Pore Pressure and Creep

  • Chapter
Growth, Dissolution and Pattern Formation in Geosystems

Abstract

In many applications of chemical transport modelling to geological problems, it is very important to take into account the changes to the transport properties of the porous medium that will result from chemical reactions driven by the component fluxes which are being modelled. This is particularly true where the reactions involve breakdowr of carbonate minerals, because they produce very large changes in solid volume, but there are many other fluid-rock reactions, involving both precipitation and dissolution, that are capable of perturbing the pattern of flow that originally triggered the reaction. This paper is concerned with the growth of calc-silicate minerals replacing marbles in metamorphism, which we model through the simplest possible metamorphic reaction:

$$ Cal + Qtz \rightleftharpoons Wo + C{O_2} $$
((17.1))

However, our approach is equally appliable a wide range of skarn-forming reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Balashov, V.N. and Lebedeva, M.I., 1991, Macrokinetic model of origin and development of a monomineralic bimetasomatic zone, in L. Perchuk (ed.), Progress in Metamorphic and Magmatic Petrology, Cambridge University Press, Cambridge, pp. 167–195.

    Chapter  Google Scholar 

  • Balashov, V.N. and Lebedeva, M.I., 1998, On self-consistent model of chemical transport at metamorphism of rocks, Doklady of Russian Academy of Sciences 363(1), 97–103.

    Google Scholar 

  • Balashov, V.N. and Yardley, B.W.D., 1998, Modeling metamorphic fluid flow with reaction-permeability feedbacks and at a range of effective stress, American Journal of Sciences 298, 441–470.

    Google Scholar 

  • Baumgartner, L.P., Gerdes, M.L., Person, M.A. and Roselle, G.T., 1996, Porosity and permeability of carbonate rocks during contact metamorphism, in B. Jamtveit and B.W.D. Yardley (eds.), Fluid Flow and Transport in Rocks, Chapman and Hall, London, pp. 83–98.

    Google Scholar 

  • Korzhinskii, D.S., 1970, Theory of Metasomatic Zoning, Clarendon Press, Oxford, 162 pp.

    Google Scholar 

  • Labotka, T.C., 1991, Chemical and physical properties of fluids, Reviews in Minerology 26, 43–104.

    Google Scholar 

  • Lasaga, A.C., 1986, Metamorphic reaction laws and development of isograds, Mineralogical Magazine 50, 359–373.

    Article  Google Scholar 

  • Lichtner, P.C., 1988, The quasi-stationary state approximation to coupled mass transport and fluid-rock interaction in a porous media, Geochimica et Cosmochimica Acta 52, 143–165.

    Article  Google Scholar 

  • Lichtner, P.C., Oelkers, E.H. and Helgeson, H.C., 1986, Interdiffusion with multiple precipitation/dissolution reactions: Transient model and the steady-state limit, Geochimica et Cosmochimica Acta 50, 1951–1966.

    Article  Google Scholar 

  • MacCormack, R.W., 1981, A numerical method for solving the equations of compressible viscous flow, American Institute of Aeronautics and Aerospace Paper 81–0110.

    Google Scholar 

  • Press, W.H., Flannery, B.P., Teukolsky, S.A. and Vetterling, W.T., 1992, Numerical Recipes, Cambridge University Press, Cambridge.

    Google Scholar 

  • Rumble, D., Feny, J.H., Hoering, T.C. and Boucot, A.J., 1982, Fluid flow during metamorphism at the Beaver Brook fossil locality, New Hampshire, American Journal of Science 282, 886–919.

    Article  Google Scholar 

  • Samarsky, A.A., 1977, Theory ofDifference Schemes, Nauka, Moscow.

    Google Scholar 

  • Steefel, C.I. and Lichtner, P.C., 1994, Diffusion and reaction in rock matrix bordering a hyperalkaline fluidfilled fracture, Geochimica et Cosmochimica Acta 58, 3595–3612.

    Article  Google Scholar 

  • Tanner, S.B., Kerrick, D.M. and Lasaga, A.C., 1985, Experimental kinetic study of the reaction: calcite + quartz = wollastonite + carbon dioxide, from 1 to 3 kilobars and 500° to 850° , American Journal of Science 285, 577–620.

    Article  Google Scholar 

  • Walker, A.N., Rutter, E.H. and Brodie, K.H., 1990, Experimental study of grain-size sensitive flow of synthetic, hot-pressed calcite rocks, in R.J. Knipe and E.H. Rutter (eds.), Deformation Mechanisms: Rheology and Tectonics, Geol. Soc. London Special Publ. 54, pp. 259–282.

    Google Scholar 

  • Yardley, B.W.D. and Lloyd, G.E., 1989, An application of cathodoluminescence microscopy to the study of textures and reactions in high-grade marbles from Connemara, Ireland, Geological Magazine 126, 333–337.

    Article  Google Scholar 

  • Yardley, B.W.D. and Lloyd, G.E., 1995, Why metasomatic fronts are really metasomatic sides, Geology 23, 53–56.

    Article  Google Scholar 

  • Zaraisky, G.P., 1989, Zoning and Formation Conditions of Metasomatic Rocks, Nauka, Moscow.

    Google Scholar 

  • Zaraisky, G.P. and Balashov, V.N., 1995, Thermal decompaction of rocks, in K.I. Shmulovich, B.W.D. Yardley and G.G. Gonchar (eds.), Fluids in the Crust, Chapman and Hall, London, pp. 253–284.

    Google Scholar 

  • Zaraisky, G.P., Zharikov, V.A., Stoyanovskaya, F.M. and Balashov, V.N., 1986, Experimental Investigation of Skarn Formation, Nauka, Moscow, 380 pp.

    Google Scholar 

  • Zhang, S., Paterson, M. S. and Cox, S.F., 1994, Porosity and permeability evolution during hot isostatic pressing of calcite aggregates, Journal of Geophysical Research 99, 15741–15760.

    Article  Google Scholar 

  • Zharikov, V.A. and Zaraisky, G.P., 1991, Experimental modelling of wall-rock metasomatism, in L. Perchuk (ed.), Progress in Metamorphic and Magmatic Petrology, Cambridge University Press, Cambridge, pp. 197–245.

    Chapter  Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1999 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Balashov, V.N., Yardley, B.W.D., Lebedeva, M. (1999). Metamorphism of Marbles: Role of Feedbacks between Reaction, Fluid Flow, Pore Pressure and Creep. In: Jamtveit, B., Meakin, P. (eds) Growth, Dissolution and Pattern Formation in Geosystems. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-9179-9_17

Download citation

  • DOI: https://doi.org/10.1007/978-94-015-9179-9_17

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4030-5

  • Online ISBN: 978-94-015-9179-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics