Skip to main content

Part of the book series: NATO ASI Series ((NSSE,volume 304))

Abstract

The evolution of tricalcium silicate (C3S) microstructure with or without small inert grains during hydration is tri-dimensionally simulated based on an “Integrated Particle Kinetics Model.” The products of the reaction are calcium silicate hydrate (C-S-H) and calcium hydroxide (CH); the first is deposited on the hydrated particle and the second is nucleated in the pore space. The pore volume and the contact surfaces between the hydrated particles and the inert grains are calculated, and the microstructural developments is demonstrated at various degrees of hydration. Several examples of the C3S microstructure development with different size distributions, with or without small-size inert grains, are presented. The influences of the inert grains on the overall degree of hydration, the total contact surfaces, and on the setting time of the hydrated cement are shown. In these examples, the size of cement particles varies from 6 mm to 60 mm and the inert grains have a diameter of 4 mm.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Pommersheim, J. M. and Clifton, J. R. (1982) Mathematical modeling of tricalcium silicate hydration. II. Hydration sub-models and the effect of model parameters, CCR, 12, 765–772.

    Article  CAS  Google Scholar 

  2. Jennings, H. M. and Johnson, S. K. (1986) Simulation of microstructure development during the hydration of a cement compound, JACS, 69, 790–795.

    CAS  Google Scholar 

  3. Bentz, D. P. and Garboczi, E. J. (1991) Percolation of phases in a three-dimensional cement paste microstructural model, CCR, 21, 325–344.

    Article  CAS  Google Scholar 

  4. Breugel, K. van (1991) Simulation of hydration and formation of structure in hardening cement-based materials, Delft, Thesis.

    Google Scholar 

  5. Granju, J. L. and Maso, J. C. (1984-a) Hardened Portland cement pastes, modelisation of the microstructure and evolution laws of mechanical properties. I- Basic results, CCR, 14, 249–256.

    Article  CAS  Google Scholar 

  6. Granju, J. L. and Maso, J. C. (1984-b) Hardened Portland cement pastes, modelisation of the microstructure and evolution laws of mechanical properties. I- Compressive strength law, CCR, 14, 303–316.

    Article  Google Scholar 

  7. Older, I. (1991) Strength of cement (final report) Rilem, Materials and Structures, 24, 143–157.

    Article  Google Scholar 

  8. Goldman, A. and Bentur, A. (1993) The influence of microfillers on enhancement of concrete strength, CCR, 23, 962–972.

    Article  CAS  Google Scholar 

  9. Navi, P. and Pignat, Ch. (1993) Tri-dimensional simulation of microstructure development of cement paste during hydration, in C. Huet (ed.), Micromechanics of concrete and cementitious composites, PPUR, Switzerland, 146–158.

    Google Scholar 

  10. Bezjak, A. and Jelenic, I. (1980) On the determination of rate constants for hydration processes in cement pastes, CCR, 10, 553–563.

    Article  CAS  Google Scholar 

  11. Roelfstra, P. E. (1989) A numerical approach to investigate the properties of concrete numerical concrete, EPFL-Lausanne, Thesis.

    Google Scholar 

  12. Young, J. F. and Hansen, W. (1986) Volume relationships for C-S-H formation based on hydration stoichiometries, SMDDHC, Boston, MRS Proc., 85, 313–322.

    Article  Google Scholar 

  13. Jennings, H. M., Parrott, L. J. (1986) Microstructural analysis of hydrated alite paste, JMS, 21, 4053–4059.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Navi, P., Pignat, C. (1996). Simulation of Effects of Small Inert Grains on Cement Hydration and Its Contact Surfaces. In: Jennings, H., Kropp, J., Scrivener, K. (eds) The Modelling of Microstructure and its Potential for Studying Transport Properties and Durability. NATO ASI Series, vol 304. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8646-7_10

Download citation

  • DOI: https://doi.org/10.1007/978-94-015-8646-7_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4653-6

  • Online ISBN: 978-94-015-8646-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics