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Metals And Alloys: Phase Separation and Defect Agglomeration

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Modern Aspects of Small-Angle Scattering

Part of the book series: Nato ASI Series ((ASIC,volume 451))

Abstract

Small-angle scattering provides the spatial and temporal resolution necessary to study the kinetics and morphology of phase separation from very early to rather advanced stages. Some characteristic results on the decomposition of alloys, e.g. Au-Pt, Ni-Al, Ni-Ti, Ni-Al-Mo, are discussed in the light of current theoretical concepts of nucleation and growth, spinodal decomposition, power law scattering and scaling, and elastic interaction of precipitates. Vacancy agglomerates introduced by quenching or plastic deformation may also be revealed, as illustrated by measurements on quenched NiAl and fatigued Cu single crystals.

Note: This paper is a slightly reduced version of the paper Phase separation and defects studied by scattering techniques, Physica Scripta 48, 1993, copyright Royal Swedish Academy of Sciences.

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References

  1. Barrett, C.S., Massalski, T.B., “Structure of Metals” (Pergamon Press, Oxford, 1980)

    Google Scholar 

  2. Schwartz, L.H., and Cohen, J.B., “Diffraction from Materials”, 2nd ed. (Springer, Berlin, 1987).

    Book  Google Scholar 

  3. Kostorz, G., “Physical Metallurgy”, 3rd ed. (Edited by R.W. Calm and P. Haasen) (Elsevier, Amsterdam, 1983), p. 793.

    Google Scholar 

  4. Kostorz, G., J. Appl. Cryst. 24, 444 (1991).

    Article  CAS  Google Scholar 

  5. Binder, K., “Phase Transformations in Materials” (Edited by P. Haasen) (VCH, Cambridge, UK, 1992), p. 405.

    Google Scholar 

  6. Wagner, R., and Kampmann, R., ibid., p. 213.

    Google Scholar 

  7. Guinier, A., and Fournet, G., “Small-Angle Scattering of X-Rays”, (transl. by C.B. Walker) (Wiley, New York, 1955).

    Google Scholar 

  8. Glatter, O., and Kratky, O., eds., “Small Angle X-Ray Scattering” (Academic Press, London, 1982).

    Google Scholar 

  9. Kostorz, G., “Neutron Scattering” (Edited by G. Kostorz) (Academic Press, New York, 1979), p. 227.

    Google Scholar 

  10. Kostorz, G., Hyperfine Interaction 45, 91 (1989)

    Article  Google Scholar 

  11. Osamura, K., Okuda, H., Tanaka, M., Nagao, M., and Amemya, Y., “Kinetics of Ordering Transformations in Metals”, (TMS Symposium, Warrendale, Ohio, 1992), to be published.

    Google Scholar 

  12. Calm, J.W., Acta Metall. 9, 795 (1961).

    Article  Google Scholar 

  13. Cahn, J.W., and Hilliard, J.E., J. Chem. Phys. 28, 258 (1958), 31, 688 (1959).

    Article  CAS  Google Scholar 

  14. Binder, K. “Stochastic Nonlinear Systems in Physics, Chemistry and Biology” (Edited by L. Arnold and R. Lefever) (Springer, Berlin, 1981), p.62.

    Chapter  Google Scholar 

  15. Binder, K., and Stauffer, D., Adv. Phys. 25, 343 (1976).

    Article  CAS  Google Scholar 

  16. Langer, J.S., and Baron, M., Phys. Rev. A11, 1417 (1975).

    Google Scholar 

  17. Milchev, A., Heermann, D.W., and Binder, K., Acta Metall. 36, 377 (1988).

    Article  Google Scholar 

  18. Singhai, S.P., Herman, H., and Kostorz, G., J. Appl. Cryst. 11, 572 (1978).

    Article  Google Scholar 

  19. Singhai, S.P., Ph.D. Thesis (State University of New York at Stony Brook, 1981).

    Google Scholar 

  20. Glas, R., Blaschko, O., and Rosta, L., Phys. Rev. B46, 5972 (1992).

    Google Scholar 

  21. Lifshitz, I.M., and Slyosov, J., Phys. Chem. Solids 19, 35 (1961).

    Article  Google Scholar 

  22. Wagner, C., Z. Elektrochem. 65, 581 (1961).

    CAS  Google Scholar 

  23. Binder, K., and Stauffer, D., Phys. Rev. Lett. 33, 1006 (1974).

    Article  Google Scholar 

  24. Furukawa, H., Phys. Rev. A23, 1535 (1981).

    Google Scholar 

  25. Fratzl, P., Lebowitz, J.L., Marro, J., and Kalos, M.H., Acta Metall. 31, 1849 (1983).

    Article  CAS  Google Scholar 

  26. Fratzl, P., and Lebowitz, J.L., Acta Metall. 37, 3245 (1989).

    Article  CAS  Google Scholar 

  27. Furukawa, H., Physica 123A, 497 (1984).

    Google Scholar 

  28. Yaldram, K., and Binder, K., Z. Phys. B — Condensed Matter 82, 405 (1991).

    Article  CAS  Google Scholar 

  29. Khachaturyan, A.G., “Theory of Structural Transformations in Solids” (Wiley, New York, 1983).

    Google Scholar 

  30. Beddoe, R.E., Haasen, P., and Kostorz, G., “Decomposition of Alloys: the early stages” (Edited by P. Haasen, V. Gerold, R. Wagner, M.F. Ashby) (Pergamon Press, Oxford, 1984) p. 233.

    Google Scholar 

  31. Calderon, H., and Kostorz, G., “Neutron Scattering for Materials Science” (Edited by S.M. Shapiro, S.C. Moss, J.D. Jorgensen) (MRS Symp. Proc. No. 166, Mat. Res. Soc., Pittsburgh, 1990) p. 255.

    Google Scholar 

  32. Cerri, A., Schönfeld, B., and Kostorz, G., Phys. Rev. B42, 958 (1990).

    Google Scholar 

  33. Haasen, P., and Wagner, R., Met. Trans. 23A, 1901 (1992).

    CAS  Google Scholar 

  34. Guinier, A., Nature (London) 142, 569 (1938).

    Article  CAS  Google Scholar 

  35. Sato, T., Murakami, T., Amemya, Y., Hashizume, H., and Taskahashi, T., Acta Metall. 36, 1335 (1988).

    Article  CAS  Google Scholar 

  36. Dubey, Ph.A., Schönfeld, B., and Kostorz, G., Acta Metall. Mater. 39, 1161 (1991).

    Article  CAS  Google Scholar 

  37. Hennion, M., Guyot, P., and Ronzaud, D., Acta Metall. 30, 599 (1982).

    Article  CAS  Google Scholar 

  38. Kostorz, G., “Small Angle X-Ray Scattering” (Edited by O. Glatter and O. Kratky) (Academic Press, London, 1982), p. 467; Makromol. Chem., Macromol. Symp. 15, 131 (1988).

    Google Scholar 

  39. Lyon, O., and Simon, J.P., J. Phys.: Condens. Matter 5 (1993), to be published.

    Google Scholar 

  40. Simon, J.P., Guyot, P., and Ghirladucci de Silva, J.P., Philos Mag. A49, 151 (1984).

    Google Scholar 

  41. Miyazaki, T., Imamura, H., and Kozakai, T., J. Mater. Sci. Eng. 54, 9 (1982).

    CAS  Google Scholar 

  42. Johnson, W.C., Acta Metall. 32, 465 (1984).

    Article  CAS  Google Scholar 

  43. Ardell, A.J., and Nicholson, R.B., Acta Metall. 14, 1295 (1966).

    Article  CAS  Google Scholar 

  44. Miyazaki, T., Seki, K., Doi, M., and Kozakai, T., Mater. Sci. Eng. A77, 125 (1986).

    Google Scholar 

  45. Doi, M., and Miyzaki, T., J. Mater. Sci. 27, 6291 (1992).

    Article  CAS  Google Scholar 

  46. Sequeira, A.D., Calderon, H.A., Skov Pedersen, J., and Kostorz, G., to be published.

    Google Scholar 

  47. Morrison, J.D., Corcoran, J.D., and Lewis, K.E., J. Appl. Cryst. 25, 504 (1992).

    Article  Google Scholar 

  48. Skov Pedersen, J., Phys. Rev. B47, 657 (1993).

    Google Scholar 

  49. Triolo, R., Caponetti, E., Spooner, S., and Boschetti, F., Philos. Mag. A60, 401 (1989).

    Google Scholar 

  50. Khachaturyan, A.G., Lindsey, T.L., and Morris, J.W., Jr., Met. Trans. 19A, 249 (1988).

    CAS  Google Scholar 

  51. Chen, L.-Q., Khachaturyan, A.G., Scripta Met. Mater. 25, 61 (1991).

    Article  CAS  Google Scholar 

  52. Cerri, A., Schmelczer, R., Schwander, P., Kostorz, G., and Wright, A.F., “Characterization of Defects in Materials” (Edited by R.W. Siegel, J.R. Weertman, R. Sinclair) (MRS Symp. Proc. No. 82, Mat. Res. Soc, Pittsburgh, 1987), p. 169.

    Google Scholar 

  53. Vyskocil, P., Doctoral dissertation, ETH Zürich (1993).

    Google Scholar 

  54. Kostorz, G., “Industrial and Technological Applications of Neutrons” (Edited by M. Fontana, F. Rusticelli, R. Coppola) (CXIV Corso Enrico Fermi, Elsevier, Amsterdam, 1992), p. 85.

    Google Scholar 

  55. Bauer, G. “Neutron Scattering” (Edited by G. Kostorz) (Academic Press, New York, 1979), p. 227.

    Google Scholar 

  56. Epperson, J.E., Gerstenberg, K.W., Berner, D., Kostorz, G., and Ortiz, C, Philos. Mag. A38, 529 (1978).

    Google Scholar 

  57. Atkinson, H.H., and Hirsch, P.B., Philos. Mag. 3, 213 (1958).

    Article  CAS  Google Scholar 

  58. Seeger, A., and Kröner, E., Z. Naturforsch. A14, 74 (1959).

    Google Scholar 

  59. Kronmüller, H., Seeger, A., and Wilkens, M., Z. Phys. 171, 291 (1963).

    Article  Google Scholar 

  60. Schmatz, W., Riv. Nuovo Omento 5, 398 (1975).

    Article  CAS  Google Scholar 

  61. Kettunen, P., Lepistö, T., Kostorz, G., and Göltz, G., Acta Metall. 29, 969 (1981).

    Article  CAS  Google Scholar 

  62. Lepistö, T.K., Kostorz, G., Kuokkala, V.-T., and Kettunen, P., Mater. Sci. Eng. A131, 171 (1991).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Institut für Angewandte Physik, ETH Zürich, CH-8093, Zürich, Switzerland

    G. Kostorz

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  1. G. Kostorz
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Editors and Affiliations

  1. Department of Chemistry, Syracuse University, Syracuse, New York, USA

    H. Brumberger

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Kostorz, G. (1995). Metals And Alloys: Phase Separation and Defect Agglomeration. In: Brumberger, H. (eds) Modern Aspects of Small-Angle Scattering. Nato ASI Series, vol 451. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8457-9_8

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  • DOI: https://doi.org/10.1007/978-94-015-8457-9_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4499-0

  • Online ISBN: 978-94-015-8457-9

  • eBook Packages: Springer Book Archive

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