Abstract
The large variety and complexity of the exotic phases of ice is in clear contrast to the simplicity of the water molecule. The properties of these phases are crucially dependent on the nature of the hydrogen bond. Our observation of the existence of two H-bonds in ices [1] indicates that the true reason for the formation of the large number of ice structures is the existence of a mixture of the strong and weak H-bonds, resulting in a large internal stress in the system. Hence relaxation of the stress, reducing the stress energy, could result in different distorted ice structures, in metastable states. In a similar way, the two types of H-bond can stabilise the two phases which are often proposed in the various mixture models of water. The details of our model are discussed.
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References
Li, J-C. and Ross, D.K., Nature, 365, 327–329 (1993).
Eisenberg, D. and Kauzmann, W., in “The Structure and Properties of Water” (Oxford University Press, 1965 ).
Home, R.A., in “Water and Aqueous Solutions”, (a Division of John Wiley & Sons, Inc. 1972 ).
Frank, H.S., in WATER: A Comprehensive Treatise (eds. F. Franks, Plenum Press) Vol 1, 515–577 ( Plenum Press, New York–London, 1972 ).
Pople, J.A., Proc. Roy. Soc. A205, 163–171 (1957).
Frank, H.S. and Wen, W.-Y., Dics. Faraday Soc. 24, 133–148 (1957).
Claussen, W.F. J. Chem. Phys. 19 259, 662, 1425 (1951).
Geiger, A, Mausbach, P. and Schnitker, in “Water and Aqueous Solutions” (eds. G.W. Neilson and J.E. Enderby, Adam Hilger, Bristol and Boston, 1985 ) 15–39.
Stanley, H.E. and Teixeia, J., J. Chem. Phys. 73, 3404–3422 (1980).
Morokuma, K. and Pedersen, L., J. Chem. Phys. 48, 3275–3282 (1968).
Millot, C. and Stone, A.J., Molecular Physics. 77, 439–462 (1992).
Lee, C., Vanderbilt, D., Laasonen, K., Car, R. and Parrinello, M., Phys. Rev. Lett. 69, 462–465 (1992).
Li, J-C., Londono, D.L., Ross, D.K., Finney, J.L., Sherman, W.F. and Tomkinson, J.,. J. Chem. Phys., 94, 6770–6775 (1991).
Li, J-C. and Ross, D.K., Inter. Conf. on Physics and Chemistry of Ice (eds. N. Maeno and T. Hondoh) P27–49 (Hokkaido University Press, 1992 ).
Heggie, M. and Maynard, S., private communications.
Payne M.C. and Stone, A.J., private communications.
Kuhs, W.F. and Lehmann, M.S., in Water Science Review (ed. F. Franks) Vol 2, 1–65 (Cambridge University Press, 1985 ).
Kistenmacher, H., Popkie, H. and Clementi, E., J. Chem. Phys. 60, 4455–4465 (1972).
Howe, R. and Whitworth, R.W., J. Chem. Phys. 50, 963–968 (1989).
Steytler, D.C., Dore, J.C. and Wright, C.J., J. Phys. Chem. 87 2458–2459 (1983).
Chen, S-H., Proc. of the NATO Adv. Study Inst. on Hydrogen-Bonded Liquids, p289–295 (ed. J.C. Dore and J. Teixeira, Kluwer Academic Publishers, 1991 ).
Marechal, Y., J. Chem. Phys. 95, 5565–5573 (1991).
Li, J-C., Bennington, S.M., Benham, M.J., Ross, D.K. and Tomkinson, J., lOP Conference Series 101, 109–118 (J. W. Arrowsmith Ltd, Bristol, 1990 ).
Etzler, F.M. and Drost-Hanson, W., CROATICA CHEMICA ACTA 56, 563–592 (1983).
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© 1994 Springer Science+Business Media Dordrecht
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Li, J., Ross, D.K. (1994). The Role of H-Bond in the Formation of Ices. In: Bellissent-Funel, MC., Dore, J.C. (eds) Hydrogen Bond Networks. NATO ASI Series, vol 435. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8332-9_5
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DOI: https://doi.org/10.1007/978-94-015-8332-9_5
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