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Dielectric Properties of Aqueous Solutions

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Hydrogen Bond Networks

Part of the book series: NATO ASI Series ((ASIC,volume 435))

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Abstract

A short review on the main applications of dielectrometry to the study of aqueous solutions is presented. The results here reported go from “simple” water — alcohol solutions to complex systems as biological solutions; they evidence that Time Domain Dielectrometry can be usefully utilised to study the rotational dynamics related to the solute molecule reorientation, the brownian motion of the polymer side chains, the properties of the hydration water and the water-solute interactions.

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References

  1. Böttcher, C.J.F. and Bordewijk, P. (1978) Theory of Electric Polarization. Vol.11, Elsevier Scientific Publ. Co., Amsterdam.

    Google Scholar 

  2. Kaatze, U., and Giese, K. (1980) J. Phys. E Sci. Instrum. 13, 133–141.

    Article  ADS  Google Scholar 

  3. Cole, R.H. (1977) Ann. Rev. Phys. Chem. 28, 283–300; Gestblom, B. and Elmgren, H. (1982) Chem. Phys. Lett. 90, 412–416; Mashimo, S., Umehara, T., Ota, T., Kuwabara, T., Shinyashiky, N., and Yagihara, S. (1987) J. Mol. Liq. 36, 135–151; Bertolini, D., Cassettari, M., Salvetti, G., Tombari, E., and Veronesi, S. (1990) Rev. Sci. Instrum. 61, 450–456.

    ADS  Google Scholar 

  4. Kaatze, U., and Uhlendorf, V. (1981) Z. für Physik. Chemie N. F. 126, 151–165.

    Google Scholar 

  5. Cole, K.S., and Cole, R.H. (1941) J. Chem. Phys. 9, 341–351.

    Article  ADS  Google Scholar 

  6. Mason, P.R., Hasted, J.B., and Moore, L. (1974) Adv. in Mol. Relax. Processes 6, 217–232.

    Google Scholar 

  7. Bertolini, D., Cassettari, M., and Salvetti, G. (1982) J. Chem. Phys, 73, 3255–3290.

    Google Scholar 

  8. Salvetti, G. (1991) in Hydrogen-Bonded Liquids, Dore J.C. and Teixeira J. (Ed.), Kluver Acad. Publ., The Netherlands.

    Google Scholar 

  9. Stanley, H.E., and Teixeira, J. (1980) J. Chem. Phys. 73, 3404–3422.

    Article  ADS  MathSciNet  Google Scholar 

  10. Bertolini, D., Cassettari, M., Ferrano, M., Grigolini, P., Salvetti, G., and Tani, A. (1989) J. Chem. Phys, 91, 1179–1190.

    Article  ADS  Google Scholar 

  11. Bertolini, D., Cassettari, M., Salvetti, G., Tombari, E., Cryst. Solids 131–133, 1169–1173.

    Google Scholar 

  12. Mashimo, S., Kuwabara, S., Yagihara, S., and Higasi, 3292–3294.

    Google Scholar 

  13. Bertolini, D., Cassettari, M., and Salvetti, G. (1983) J. Chem. Phys, 78, 365–372.

    Article  ADS  Google Scholar 

  14. Bertolini, D., Cassettari, M., Ferrano, M., Grigolini, P., and Salvetti, G., (1985) in Memory Function Approaches to Stochastic Problems in Condensed Matter, Evans, M.W., Grigolini, P., and Pastori-Parravicini, G. (eds.), Wiley, New York.

    Google Scholar 

  15. Mashimo, S., Miura, N., and Umehara, T. (1992) J. Chem. Phys. 97, 6759–6765.

    Article  ADS  Google Scholar 

  16. Takashima,S. (1963) Biopolymers 1 171–187.

    Article  Google Scholar 

  17. Van del Touw, F., Mendel, M. (1974) Biophys. Chem. 2, 218–230.

    Article  Google Scholar 

  18. Mashimo, S., Ota, T., Shinyashiki, N., Tanaka, S., and Yagihara, S. (1989) Macromolecules 22, 1285–1288.

    Article  ADS  Google Scholar 

  19. Careri, G., Gratton, E., Yang, P.H., Rupley, J.A. (1980) Nature 284, 572–577.

    Article  ADS  Google Scholar 

  20. Umehara, T., Kuwabara, S., Mashimo, S., and Yagihara, S. (1990) Biopolymers 30, 649–656.

    Article  Google Scholar 

  21. Bertolini, D., Cassettari, M., Salvetti, G., Tombari, E., Veronesi, S., and Squadrito, G. (1992) Il Nuovo Cimento D 14, 199–205.

    Article  ADS  Google Scholar 

  22. Johari, G.P., (1983) in Relaxation in Complex Systems, Ngai, K.L., and Wright, G.B. (Ed.), National Technical Inforomation Service, U.S. Dpt. of Commerce, Springfield, VA 17–41.

    Google Scholar 

  23. Birge, N.O. (1986) Physical Review B 34, 1631–1642.

    Article  ADS  Google Scholar 

  24. Stein, D.L.(1987) in “Chance and Matter”, Les Houches Lectures 1986 Elsevier Science Publishers B.V., 577–610.

    Google Scholar 

  25. Frauenfelder, H., Steinbach, P.J., and Young, R.D. (1989) Chem. Scr. (UK) 29A, 145–150.

    Google Scholar 

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© 1994 Springer Science+Business Media Dordrecht

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Salvetti, G., Tombari, E. (1994). Dielectric Properties of Aqueous Solutions. In: Bellissent-Funel, MC., Dore, J.C. (eds) Hydrogen Bond Networks. NATO ASI Series, vol 435. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8332-9_21

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  • DOI: https://doi.org/10.1007/978-94-015-8332-9_21

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4412-9

  • Online ISBN: 978-94-015-8332-9

  • eBook Packages: Springer Book Archive

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