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Fundamentals of Solids Extraction by Supercritical Fluids

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Book cover Supercritical Fluids

Part of the book series: NATO ASI Series ((NSSE,volume 273))

Abstract

The theory and advantages of supercritical extraction are discussed and the applications of supercritical extraction from solid matrices are reviewed in detail. The thermodynamic equilibrium of supercritical extraction is examined and the adsorption/desorption phenomena in presence of supercritical fluids are explained. Various models, proposed in the literature, to interpret the extraction phenomena from solid matrices are reviewed. The importance of the fundamental parameters like adsorption equilibrium constants, mass transfer coefficients, axial dispersion coefficients and effective diffusivities of the solutes in the solid pore space are emphasised. The last section reviews the novel extraction processes proposed for the remediation of environmental matrices.

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Authors and Affiliations

  1. Chemical Engineering Department, Texas A & M University, College Station, TX, 77843, USA

    Aydin Akgerman & Giridhar Madras

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  1. Aydin Akgerman
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  2. Giridhar Madras
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Editors and Affiliations

  1. Department of Chemical Engineering, University of Maine, Orono, Maine, USA

    Erdogan Kiran

  2. Thermophysics Division, National Institute of Standards and Technology, Gaithersburg, Maryland, USA

    Johanna M. H. Levelt Sengers

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Akgerman, A., Madras, G. (1994). Fundamentals of Solids Extraction by Supercritical Fluids. In: Kiran, E., Sengers, J.M.H.L. (eds) Supercritical Fluids. NATO ASI Series, vol 273. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8295-7_29

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  • DOI: https://doi.org/10.1007/978-94-015-8295-7_29

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