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H-bond-state and Solubility in Aqueous Systems

A Working Hypothesis

  • Chapter
Intermolecular Forces

Part of the book series: The Jerusalem Symposia on Quantum Chemistry and Biochemistry ((JSQC,volume 14))

Abstract

The infrared spectra of H2O in the region of the H2O-combination band (ν3 +ν2) are investigated in the saturated organic and aqueous phase of binary mixtures H2O-organic liquids (B). In agreement with the available heat of vapourization data the H2O-spectra correlate with the H-bond energy of H2O. The solubility of H2O in organic liquids as well as that of the organic molecules in water increases with decreasing molar volume of B, its H-bond acceptor strength and the amount of H-bonds of H2O, which is actually formed; the latter seems to depend on the stereochemical environment of the H-bond acceptor group.

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Authors and Affiliations

  1. Department of Physical Chemistry, University of Marburg, Germany

    H. Kleeberg

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  1. H. Kleeberg
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Editors and Affiliations

  1. Institut de Biologie Physico-Chimique (Fondation Edmond de Rothschild), Université Pierre et Marie Curie (Paris VI), Paris, France

    Bernard Pullman

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Kleeberg, H. (1981). H-bond-state and Solubility in Aqueous Systems. In: Pullman, B. (eds) Intermolecular Forces. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 14. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-7658-1_29

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  • DOI: https://doi.org/10.1007/978-94-015-7658-1_29

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-8368-5

  • Online ISBN: 978-94-015-7658-1

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