Abstract
Equations are developed to extract in-solution solute-solute virial coefficients from gas-liquid phase equilibrium data. Experimental data for the solubility of helium, neon and hydrogen in liquid argon are analyzed and second virial coefficients for these solutes, B *2 , in liquid argon are determined over the entire liquid range of argon from 84° to 148°K. The values of B *2 are negative at the lowest temperature and approach zero or positive values as the critical temperature of argon is approached. The magnitude and temperature dependence of the virial coefficients are considered in terms of the reversible work of cavity formation and an effective local density.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
H. Reiss, H. L. Frisch and J. L. Lebowitz, J. Chem. Phys., 31, 369 (1979).
H. L. Frisch, Adv. Chem. Phys., 6, 229 (1963).
H. Reiss, Adv. Chem. Phys., 9, 1 (1966).
J. A. Barker and D. Henderson, J. Chem. Phys., 47, 4714 (1967).
P. J. Leonard, D. Henderson, and J. A. Barker, Trans. Faraday Soc., 66, 2439 (1979).
J. D. Weeks, D. Chandler, and H. C. Anderson, J. Chem. Phys., 54, 5237 (1971).
R. A. Pierotti, Chem. Rev., 76, 717 (1976).
R. O. Neff and D. A. McQuarrie, J. Phys. Chem., 77, 413 (1973).
S. Goldman, Acc. Chem. Res., 11, 409 (1979).
F. H. Stillinger, J. Solution Chem., 2, 141 (1973).
R. A. Pierotti, J. Phys. Chem., 69, 281 (1965).
A. Ben-Nairn, Water and Aqueous Solutions, Plenum Press, New York, 1974.
M. Lucus, J. Phys. Chem., 76, 4030 (1972).
S. Marcelja, D. J. Mitchell, B. W. Ninham, and M. J. Sculley, J. Chem. Soc. Faraday Trans. 2, 73, 630 (1977).
A. H. Clark, F. Franks, M. D. Pedley, and D. S. Reid, J. Chem. Soc. Faraday Trans. 1, 73, 290 (1977).
L. R. Pratt and D. Chandler, J. Chem. Phys., 67, 3683 (1977)
L. R. Pratt and D. Chandler, J. Solution Chem., 9, 1 (1980).
A. Ben-Nairn, Hydrophobic Interactions, Plenum Press, New York, 1980.
M. Lucas, J. Phys. Chem., 80, 999 (1976).
E. Wilhelm and R. Battino, J. Chem. Phys., 56, 563 (1972).
A. Ben-Nairn, J. Chem. Phys., 54, 1387 (1971).
W. G. McMillan and J. E. Mayer, J. Chem. Phys., 13, 276 (1954).
T. L. Hill, Statistical Mechanics, McGraw-Hill, New York, 1956.
T. L. Hill, Introduction to Statistical Thermodynamics, Addison-Wesley, Reading, Mass., 1960.
T. L. Hill, J. Am. Chem. Soc., 79, 4885 (1957).
W. B. Brown, Mol. Phys., 1, 68 (1958)
R. A. Sack, Mol. Phys., 2, 8 (1959).
A. Ben-Nairn, J. Chem. Phys., 59, 6535 (1973).
J. C. Mullins and W. T. Zigler, Tech. Report #3, Contract No. CST-1154, National Standard Reference Data Program, National Bureau of Standards, Washington, D. C. (1965).
J. E. Sinor and F. Kurata, J. Chem. Eng. Data, 11 537 (1966).
W. B. Streett, J. Chem. Phys. 42, 500 (1965).
H. Volk and G. D. Halsey, Jr., J. Chem. Phys., 33, 1132 (1960).
S. J. Harris and D. M. Tully-Smith, J. Chem. Phys., 55, 1104 (1971).
H. Reiss and R. V. Casberq, J. Chem. Phys., 61, 1107 (1974).
T. L. Hill, J. Chem. Phys., 30, 1521 (1959).
E. Helfand and F. H. Stillinger, Jr., J. Chem. Phys., 37, 2646 (1962).
L. R. Pratt and D. Chandler, J. Chem. Phys., 73, 3434 (1980).
C. Pangali, M. Rao, and B. J. Berne, J. Chem. Phys., 71, 2975; 2982 (1979).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1981 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Pierotti, R.A., Parrott, S.L., Tallent, M.A. (1981). Solute-Solute Interactions in Dilute Solutions of Gases in Liquids. In: Pullman, B. (eds) Intermolecular Forces. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 14. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-7658-1_12
Download citation
DOI: https://doi.org/10.1007/978-94-015-7658-1_12
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-8368-5
Online ISBN: 978-94-015-7658-1
eBook Packages: Springer Book Archive