Abstract
A general discussion of sector, chirality, and helicity rules is given. Using qualitative MO-theory the sign of a CD-band can be predicted relatively easily for inherently chiral chromophores. Application to inherently (locally) achiral chromophores which are chirally perturbed by their surroundings is possible by applying qualitatively perturbation theory. A generalization of sector rules is proposed.
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Snatzke, G. (1979). Chiroptical Properties of Organic Compounds: Chirality and Sector Rules. In: Mason, S.F. (eds) Optical Activity and Chiral Discrimination. NATO Advanced Study Institutes Series, vol 48. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-7644-4_2
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DOI: https://doi.org/10.1007/978-94-015-7644-4_2
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