Abstract
The nature of the oxide site responsible for the oxidative coupling of methane has been the subject of much speculation with respect to the reaction mechanism. Under methane coupling conditions, various oxygen species may be present on a catalyst surface and thus the potential oxidants for methane and the intermediates formed from methane.
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References
Agarwal, S.K. 1990. Oxidative coupling of methane: Catalytic studies over metal oxides. Ph.D. Dissertation, University of Pittsburgh.
Bielanski, A., and J. Haber. 1979. Oxygen in catalysis on transition metal oxides. Catal. Rev.-Sci. Eng. 19: 1–41.
Biloen, P. 1983. Transient kinetic methods. J. Mol. Catal. 21: 17–24.
Biloen, P., J.N. Helle, F.G.A. van den Berg, and W.M.H. Sachtler. 1983. On the activity of Fischer-Tropsch and methanation catalysts: A study utilizing isotopic transients. J. Catal. 81: 450–63.
Boudart, M. 1968. Kinetics of Chemical Processes. Englewood Cliffs, NJ: Prentice-Hall.
Brown, I.B., and W.R. Patterson. 1983. Reactivity of tin oxide and some antimony-tin oxide catalysts for the oxidation of methane and the isotopic exchange of oxygen: An examination of the role of adsorbed and lattice oxygen in catalytic oxidation. J. Chem. Soc. , Faraday Trans. 1 79: 1431.
Carslaw, H.S., and J.C. Jaeger. 1959. Conduction of Heat in Solids. New York: Oxford University Press.
Cromer, D.T. 1957, The crystal structure of monoclinic Sm2O3. J. Chem. Soc. , Chem. Commun. 61: 753–5.
Dean, J.A., ed. 1985. Lange’s Handbook of Chemistry, pp. 3–121. New York: McGraw-Hill.
Furusawa, T., M. Suzuki, and J.M. Smith. 1976. Rate parameters in heterogeneous catalysis by pulse techniques. Catal. Rev.-Sci. Eng. 13 (1): 43–76.
Happel, J. 1986. Isotopic Assessment of Heterogeneous Catalysis. New York: Academic Press.
Kofstad, P. 1972. Nonstoichiometry, Diffusion, and Electronic Conductivity in Binary Metal Oxides. New York: Wiley-Interscience.
Maatman, R.W. 1980. Site density and entropy criteria in identifying rate-determining steps in solid-catalyzed reactions. Adv. Catal. 29: 97–148.
Oishi, Y., and K. Ando. 1984. Oxygen diffusion in MgO and Al2O3. In Structure and Properties of MgO and Al2O3 Ceramics, ed. Oishi, Y., and K. Ando, pp. 379–93. American Ceramic Society.
Oishi, Y., and W.D. Kingery. 1960. Oxygen diffusion in periclase crystals. J. Chem. Phys. 33: 905–6.
O’Keeffe, M., and W.J. Moore. 1961. Diffusion of oxygen in single crystals of nickel oxide. J. Chem. Soc. , Chem. Commun. 65: 1438–9.
Otsuka, K., A.A. Said, K. Jinno, and T. Komatsu. 1987. Peroxide anions as possible active species in the oxidative coupling of methane. Chem. Lett. 77–8.
Parker, I.B., and W.R. Patterson. 1983. Oxidation of methane with oxygen-18: A method for the quantitative investigation of the activities of adsorbed and lattice oxygen in metal oxide catalysts. J. Chem. Soc, Faraday Trans. 1 79: 1421–30.
Peil, K.P. 1990. Elucidation of reaction pathways and identification of active sites in the oxidative coupling of methane. Ph.D. Dissertation, University of Pittsburgh.
Peil, K.P., J.G. Goodwin, Jr., and G. Marcelin. 1989. An examination of the oxygen pathway during methane oxidation over a Li/MgO catalyst. J. Phys. Chem. 93: 5977–9.
Peil, K.P., J.G. Goodwin, Jr., and G. Marcelin. 1991a. Surface phenomena during the oxidative coupling of methane over Li/MgO. J. Cat. 131: 143
Peil, K.P., J.G. Goodwin, Jr., and G. Marcelin. 1991b. Steady-state vs. non-steadystate transient kinetic analysis of surface coverages during the oxidative coupling of methane. J. Cat. In press.
Soong, Y., K. Krishna, and P. Biloen. 1986. Catalyst aging studied with isotopic transients: Methanation over Raney nickel. J. Catal. 97: 330–43.
Stephanopoulos, G. 1984. Chemical Process Control: An Introduction to Theory and Practice, p. 180. Englewood Cliffs, NJ.: Prentice-Hall.
Stone, G.D., G.R. Weber, and L. Eyring. 1968. Self-diffusion of oxygen in neodymium and samarium sesquioxide. In Mass Transport in Oxides, ed. J.B. Wachtman, Jr., and A.D. Franklin, pp. 179–86. National Bureau of Standards Special Publication 296. Washington, DC: US Government Printing Office.
Tamaru, K. 1978. Dynamic Heterogeneous Catalysis. New York: Academic Press.
Templeton, D.H., and C.H. Dauben. 1954. Lattice parameters of some rare earth compounds and a set of crystal radii. J. Chem. Soc., Chem. Commun. 5237–9.
Wang, J.-X., and J.H. Lunsford. 1986. Characterization of [Li +O-] centers in lithium doped MgO catalysts. J. Phys. Chem. 90: 5883–7.
Yang, C.-H., Y. Soong, and P. Biloen. 1984. Abundancy and reactivity of surface intermediates in methanation, determined with transient kinetic methods. In Proceedings of the 8th International Congress in Catalysis, vol. 2, pp. 3–14.
Yang, C.-H., Y. Soong, and P. Biloen. 1985 A comparison of nickel-and platinum-catalyzed methanation utilizing transient-kinetic methods. J. Catal. 94: 306–9.
Zhang, X., and P. Biloen. 1986. A transient kinetic observation of chain growth in the Fischer-Tropsch synthesis. J. Catal. 98: 468–76.
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Peil, K.P., Marcelin, G., Goodwin, J.G. (1992). The Role of Lattice Oxygen in the Oxidative Coupling of Methane. In: Wolf, E.E. (eds) Methane Conversion by Oxidative Processes. Van Nostrand Reinhold Catalysis Series. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-7449-5_5
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DOI: https://doi.org/10.1007/978-94-015-7449-5_5
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