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Quantum Theory of Chemical Reactions pp 35–53Cite as

Chemisorptive Properties of Transition Metal Clusters

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Part of the book series: Quantum Theory Chemical Reactions ((QTCR,volume 3))

Abstract

Chemisorptive properties of simple gases on transition metal clusters are shown to be closely related to their electronic properties. These properties depend on the size and roughness of the cluster. Striking modification of the electronic properties from the bulk appear for atomic sites having a low coordination number. Spin orbit coupling play an important role for the third series, and induce differences in chemisorptive properties between Ni and Pt. Trends and order of magnitude of binding energies of simple gases, such as hydrogen, oxygen, sulphur are calculated.

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Author information

Authors and Affiliations

  1. Groupe des Transitions de Phases, C.N.R.S., B.P. 166, 38042, Grenoble Cedex, France

    F. Cyrot-Lackmann

Authors
  1. F. Cyrot-Lackmann
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Editor information

Editors and Affiliations

  1. Centre de Mécanique Ondulatoire Appliquée, CNRS, Paris, France

    Raymond Daudel

  2. Institut de Biologie Physico-Chimique, CNRS, Paris, France

    Alberte Pullman

  3. CNRS, Laboratoire de Chimie Théorique, Université de Paris Sud, Orsay, France

    Lionel Salem

  4. CNRS, Université Louis Pasteur, Strasbourg, France

    Alain Veillard

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© 1982 Springer Science+Business Media Dordrecht

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Cyrot-Lackmann, F. (1982). Chemisorptive Properties of Transition Metal Clusters. In: Daudel, R., Pullman, A., Salem, L., Veillard, A. (eds) Quantum Theory of Chemical Reactions. Quantum Theory Chemical Reactions, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-6918-7_3

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  • DOI: https://doi.org/10.1007/978-94-015-6918-7_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-015-6920-0

  • Online ISBN: 978-94-015-6918-7

  • eBook Packages: Springer Book Archive

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