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Natural and Anthropogenic Organic Compounds in the Global Atmosphere

  • Chapter
Global Atmospheric Chemical Change

Abstract

Recent advances in measurement science and technology have allowed scientists to probe the chemical composition of the earths atmosphere in increasingly greater detail and with greater precision than ever before possible. This is particularly true for studies of the organic chemical composition of the atmosphere. Measurements of organic chemicals have been made in a variety of atmospheric environments around the globe: from urban and rural sites on the continents to the most remote areas over the ocean, from ground level to the upper levels of the troposphere and into the stratosphere. Results of these studies over the last few decades have been illuminating and even surprising, and in some ways they have shaped the direction of atmospheric chemical research. For example, thesteady increase of tropospheric chlorofluorocarbons (CFCs) has been recognized as a critical factor in seasonal polar ozone depletion (see Chapter 2). The relationship between ozone and CFCs is now well documented, but it should be realized that CFCs are present in the atmosphere at mixing ratios below 1 ppbv (parts per billion by volume; billion = 109), and the chemical measurement technology which allows the sensitive, accurate and precise determination of these molecules has been available only in the last several decades. As discussed in other chapters of this volume, improved methods of chemical analysis, too, have revealed temporal trends in the concentration of a variety of different trace gases which can affect the radiation balance of the earth and may lead to the so-called `greenhouse warming effect. In addition to radiative effects, both theoretical and experimental studies demonstrate that a variety of organic chemicals are directly involved in the processes which control the formation and destruction of major tropospheric oxidants such as HO, HO2, RO2, NO3 and ozone.

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References

  1. Simoneit, B. R. T., Characterization of organic constituents in aerosols in relation to their origin and transport: A review. Intern. J. Environ. Anal. Chem.,23 (1986) 207–37.

    Article  CAS  Google Scholar 

  2. Simoneit, B. R. T. and Mazurek, M. A., Air pollution: the organic components. Critical Reviews in Environmental Control,11 (3) (1981) 219–76.

    Article  CAS  Google Scholar 

  3. Andreae, M. O., The ocean as a source of atmospheric sulfur compounds. In The Role of Air—Sea Exchange in Geochemical Cycling, ed. P. Buat Menard. D. Reidel, Dordrecht, 1986, pp. 331–62.

    Chapter  Google Scholar 

  4. Toon, O. B., Kasting, J. B., Turco, R. P. and Liu, S. M., The sulfur cycle in the marine atmosphere. J. Geophys. Res.,92 (1987) 943–64.

    Article  CAS  Google Scholar 

  5. Aneja, V. P., Natural sulfur emissions into the atmosphere. J. Air Waste Manage. Assoc.,40 (1990) 469–76.

    Article  Google Scholar 

  6. Gorzelska, K. and Galloway, J., Amine nitrogen in the atmospheric environment of the North Atlantic Ocean. Global Biogeochemical Cycles,4 (1990) 309–33.

    Article  CAS  Google Scholar 

  7. Chameides, W. L. and Cicerone, R. J., Effects of nonmethane hydrocarbons in the atmosphere. J. Geophys. Res.,83 (1978) 947–52.

    Article  CAS  Google Scholar 

  8. Ehhalt, D. H. and Rudolph, J., On the importance of light hydrocarbons in multiphase atmospheric systems. KFA Technical Report, 1984.

    Google Scholar 

  9. McKeen, S. A., Trainer, M., Hsie, E. Y., Tallamraju, R. K. and Liu, S. C., On the indirect determination of atmospheric OH radical concentrations from reactive hydrocarbon measurements. J. Geophys. Res.,95 (1990) 7493–500.

    Article  CAS  Google Scholar 

  10. Roberts, J. M., Fehsenfeld, F. C., Liu, S. C., Bollinger, M. J., Hahn, C., Albritton, D. L. and Sievers, R. E., Measurements of aromatic hydrocarbon ratios and NOx concentrations in the rural troposphere: Observation of air mass photochemical aging and NOx removal.Atmos. Environ.,18(1984) 2421–32.

    Article  CAS  Google Scholar 

  11. Ehhalt, D. H., Rudolph, J., Meixner, F. and Schmidt, U., Measurements of Selected C2–05 Hydrocarbons in the background troposphere: vertical and latitudinal variations. J. of Atmos. Chem.,3 (1) (1985) 29–52.

    Article  CAS  Google Scholar 

  12. Rudolph, J. and Khedim, A., Hydrocarbons in the non-urban atmosphere: analysis, ambient concentrations and impact of the chemistry of the atmosphere. Intern. J. Environ. Anal. Chem.,20 (1985) 265–82.

    Article  CAS  Google Scholar 

  13. Singh, H. S. and Zimmerman, P. R., Atmospheric distributions and sources of non-methane hydrocarbons. Adv. in Environ. Sci. and Technol., in press.

    Google Scholar 

  14. Duce, R. A., Mohnen, V.A., Zimmerman, P. R., Grosjean, D., Cautreels, W., Chatfield, R., Jaenicke, R., Ogren, J. A., Pellizzari, E. D. and Wallace, G. T., Organic material in the global troposphere. Rev. Geophys. Space Physics,21 (4) (1983) 921–52.

    Article  CAS  Google Scholar 

  15. Warneck, P., Chemistry of the Natural Atmosphere. Academic Press, San Diego, CA, 1988, pp. 223–77.

    Google Scholar 

  16. Sexton, K. and Westberg, H., Nonmethane hydrocarbon composition of urban and rural atmospheres.Atmos. Environ.,18 (6) (1984) 1125–32.

    Article  CAS  Google Scholar 

  17. Seila, R., Lonneman, W. and Meeks, S., Determination of C2–C12 ambient air hydrocarbons in 39 US cities, from 1984 through 1986. EPA/600/S389/058.

    Google Scholar 

  18. Greenberg, J. P. and Zimmerman, P. R., Nonmethane hydrocarbons in remote tropical, continental, and marine atmospheres. J. Geophys. Res.,89 (D3) (1984) 4767–78.

    Article  CAS  Google Scholar 

  19. Hov, 0., Schmidbauer, N. and Oehme, M., C2–05 hydrocarbons in rural south Norway. Atmos. Environ.,25A (1991) 1981–99.

    Article  Google Scholar 

  20. Singh, H. B. and Salas, L. J., Measurement of selected light hydrocarbons over the Pacific Ocean: latitudinal and seasonal variations. Geophys. Res. Lett.,9 (1982) 842–5.

    Article  CAS  Google Scholar 

  21. Bonsang, B. and Lambert, G., Nonmethane hydrocarbons in an oceanic atmosphere. J. of Atmos. Chem.,2 (3) (1985) 257–71.

    Article  CAS  Google Scholar 

  22. Greenberg, J. P., Zimmerman, P. R., Pollack, W. F., Lueb, R. A. and Heidt, L. E., Diurnal variability of atmospheric methane, non-methane hydrocarbons and carbon monoxide at Mauna Loa. J. Geophys. Res., (1991), in press.

    Google Scholar 

  23. Rudolph, J. and Ehhalt, D. H., Measurments of C2–05 hydrocarbons over the North Atlantic. J. Geophys. Res.,86 (C12) (1981) 11959–64.

    Article  CAS  Google Scholar 

  24. Lightman, P., Kallend, A. S., Marsh, A. R. W., Jones, B. M. R. and Penkett, S. A., Seasonal variation of hydrocarbons in the free troposphere at mid-latitudes. Tellus,42B (1990) 408–22.

    Article  Google Scholar 

  25. Altshuller, A. P., Review: natural volatile organic substances and their effect on air quality in the United States.Atmos. Environ.,17 (1983) 2131–65.

    Article  CAS  Google Scholar 

  26. Trainer, M., Hsie, E. Y., McKeen, S. A., Tallamraju, R., Parrish, D. D., Fehsenfeld, F. C. and Liu, S.C., Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote site. J. Geophys. Res.,92 (1987) 11879–94.

    Article  CAS  Google Scholar 

  27. Chameides, W. L., Lindsay, R. W., Richardson, J. and Kiang, C. S., The role of biogenic hydrocarbons in urban photochemical smog: Atlanta as a case study. Science,241 (1988) 1473

    CAS  Google Scholar 

  28. Isidorov, V. A., Zenkench, I. G. and Iofe, B. V., Volatile organic compounds in the atmosphere of forests. Atmos. Environ.,19 (1985) 1–8.

    Article  CAS  Google Scholar 

  29. Lamb, R., Guenther, A., Gay, D. and Westberg, H., A national inventory of biogenic hydrocarbon emissions. Atmos. Environ.,21 (8) (1987) 1695–705.

    Article  Google Scholar 

  30. Zimmerman, P. R., Chatfield, R. B., Fishman, J., Crutzen, P. J. and Hanst, P. L., Estimates on the production of CO and H2 from the oxidation of hydrocarbon emissions from vegetation. Geophys. Res. Letts.,5 (1978) 679–82.

    Article  CAS  Google Scholar 

  31. Killus, J. P. and Whitten, G. Z., Isoprene: a photochemical kinetic mechanism. Environ. Sci. Technol.,18(1984) 142–8.

    Article  CAS  Google Scholar 

  32. Gu, C., Rynard, C. M., Hendry, D. G. and Mill, T., Hydroxyl radical oxidation of isoprene. Environ. Sci. Technol.,19 (1985) 151–5.

    Article  CAS  Google Scholar 

  33. Atlas, E. and Giam, C. S., Air-sea exchange of high molecular weight organic compounds in the Pacific Ocean. In Chemical Oceanography, vol.10, ed. R. A. Duce. Academic Press, London, 1989, pp. 359–78.

    Google Scholar 

  34. Bonsang, B., Kanakidou, M., Lambert, G. and Monfray, P., The marine source of C2–C6 aliphatic hydrocarbons. J. of Atmos. Chem.,5(1987) 1–8.

    Google Scholar 

  35. Rudolph, J. and Ehhalt, D. H., Measurements of C2–05 hydrocarbons over the North Atlantic. J. Geophys. Res.,86 (C12) (1981) 11959–64.

    Article  CAS  Google Scholar 

  36. Rudolph, J. and Johnen, F. J., Measurement of light atmospheric hydrocarbons over the Atlantic in regions of low biological activity.J. Geophys. Res.,95 (1990) 20583–91.

    Article  CAS  Google Scholar 

  37. Greenberg, J. P., Zimmerman, P. R. and Haagenson, P., Tropospheric hydrocarbon and CO profiles over the U.S. West Coast and Alaska. J. Geophys. Res.,95(1990) 14015–26.

    Article  Google Scholar 

  38. Singh, H. B., Viezee, W., and Salas, L. J., Measurements of selected C2–05 hydrocarbons in the troposphere: Latitudinal, vertical and temporal variations. J. Geophys. Res.,93 (1988) 15861–78.

    Article  Google Scholar 

  39. Rudolph, J., The two dimensional distribution of light hydrocarbons, Results from the STRATOZ III Experiment. J. Geophys. Res.,93 (1987) 8367–77.

    Article  Google Scholar 

  40. Guicherit, R. and Schulting, F. L., The occurrence of organic chemicals in the atmosphere of the Netherlands. The Science of the Total Environment,43 (1985) 193–5.

    Article  CAS  Google Scholar 

  41. Keller, C. D. and Bidleman, T. F., Collection of airborne polycyclic aromatic hydrocarbons and other organics with a glass fiber-polyurethane foam system. Atmos. Environ., 18 (1984) 837–45.

    Article  CAS  Google Scholar 

  42. Doskey, P. V. and Andren, A. W., Particulate and vapor phase n-alkanes in the northern Wisconsin atmosphere. Atmos. Environ.,20(1986) 1735–44.

    Article  CAS  Google Scholar 

  43. Broddin, G., Cautreels, W. and Van Cauwenberghe, K., On the aliphatic and polyaromatic hydrocarbon levels in urban and background aerosols from Belgium and the Netherlands. Atmos. Environ.,14(1980) 895–910.

    Article  CAS  Google Scholar 

  44. Foreman, W. T. and Bidleman, T. F., Semivolatile organic compounds in the ambient air of Denver, Colorado. Atmos. Environ.,24A (1990) 2405–16.

    Article  Google Scholar 

  45. Duce, R. A., and Gagosian, R. B., The input of atmospheric n-C10 to n-C30 alkanes to the ocean. J. Geophys. Res.,87 (1982) 7192–200.

    Article  Google Scholar 

  46. Graedel, T. E., Hawkins, D. T. and Claxton, L. D., Atmospheric Chemical Compounds: Sources, Occurrence, and Bioassay. Academic Press, Orlando, FL, 1986.

    Google Scholar 

  47. Penkett, S. A., Non-methane organics in the remote troposphere. In Atmospheric Chemistry, ed. E. D. Goldberg. Springer-Verlag, New York, 1982, pp. 329–55.

    Chapter  Google Scholar 

  48. Nutmagual, W. and Cronn, D. R., Determination of selected atmospheric aromatic hydrocarbons at remote continental and oceanic locations using photoionization/flame-ionization detection. J. of Atmos. Chem.,2 (1985) 415–33.

    Article  Google Scholar 

  49. Pankow, J. F., Review and comparative analysis of the theories on partitioning between the gas and aerosol particulate phases in the atmosphere. Atmos. Environ., 21 (1987) 2275–83.

    Article  CAS  Google Scholar 

  50. Daisey, J. M., McCaffrey, R. J. and Gallagher, R. A., Polycyclic aromatic hydrocarbons and total extractable particulate organic matter in the arctic aerosol.Atmos. Environ., 15 (1981) 1355–63.

    Google Scholar 

  51. Sicre, M. A., Marty, J. C., Saliot, A., Aparicio, X., Grimait, J. and Albaiges, J., Aliphatic and aromatic hydrocarbons in the different sized aerosols over the Mediterranean Sea: occurrence and origin. Atmos. Environ.,12 (1987) 2247–59.

    Google Scholar 

  52. Masclet, P., Pistikopoulos, P., Beyne, S. and Mouvier, G., Long-range transport and gas/particle distribution of polycyclic aromatic hydrocarbons at a remote site in the Mediterranean Sea. Atmos. Environ.,22 (1988) 639–50.

    Article  CAS  Google Scholar 

  53. Patton, G. W., Walla, M. D., Bidleman, T. F. and Barrie, L. A., Polycyclic aromatic and organochlorine compounds in the atmosphere of northern Ellesmere Island, Canada.J. Geophys. Res., in press.

    Google Scholar 

  54. Atkinson, R., Gas-phase tropospheric chemistry of organic compounds: A review. Atmos. Environ.,24A (1990) 1–41.

    Google Scholar 

  55. Madronich, S. and Calvert, J. G., Theoretical study of the tropospheric oxidation of hydrocarbons: oxidant generation and organic product distribution. In Global and Regional Environmental Atmospheric Chemistry, ed. L. Newman, X. Wang and C. S. Kiang. Conference proceedings CONF-890525, Brookhaven National Laboratory, Upton, NY, 1990, pp. 391–7.

    Google Scholar 

  56. Knap, A. H. (ed.), The Long-Range Transport of Natural and Contaminant Substances. NATO ASI Series C:297, Kluwer Academic Publishers, Dordrecht, Netherlands, 1990, pp. 281–2.

    Google Scholar 

  57. Atkinson, R., Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions.Chem. Rev.,85 (1985) 69–201.

    Google Scholar 

  58. Atkinson, R. A., Structure-activity relationship for estimation of rate constants for the gas-phase reactions of OH radicals with organic compounds. Intern.Chem. Kinetics,19(1987) 799–828.

    Article  CAS  Google Scholar 

  59. Atkinson, R., Estimation of OH radical reaction rate constants and atmospheric lifetimes for polychlorobiphenyls, dibenzo-p-dioxins, and dibenzofurants. Environ. Sci. Technol.,21 (1987) 305–7.

    Article  CAS  Google Scholar 

  60. Atkinson, R., Estimation of gas-phase hydroxyl radical rate constants for organic chemicals. Environ. Toxicol. Chemistry,7(1988) 435–42.

    Article  CAS  Google Scholar 

  61. Luke, W. T. and Dickerson, R. R., Direct measurment of the photolysis rate coefficient of ethyl nitrate. Geophys. Res. Lett.,11 (1988) 1181–4.

    Article  Google Scholar 

  62. Roberts, J. M. and Fajer, R. W., UV absorption cross sections of organic nitrates of potential atmospheric importance and estimation of atmospheric lifetimes. Environ. Sci. and Technol.,23 (1989) 945–51.

    Article  CAS  Google Scholar 

  63. Finlayson-Pitts, J. N., Atmospheric Chemistry. John Wiley and Sons, New York, 1986.

    Google Scholar 

  64. Atkinson, R. and Carter, W. P. L., Kinetics and mechanisms of the gas-phase reactions of ozone with organic compounds under atmospheric conditions. Chem. Rev.,84 (1984) 437–70.

    Article  CAS  Google Scholar 

  65. Atkinson, R., Aschmann, S. M., Winer, A. M. and Pitts, J. N., Jr., Kinetics and atmospheric implications of gas-phase reactions of NO3 radicals with a series of monoterpenes and related organics at 294±2K. Environ. Sci. Technol.,19 (1985) 159–63.

    Article  CAS  Google Scholar 

  66. Atkinson, R., Plum, C. N., Carter, W. P. L., Winter, A. M. and Pitts, J. N., Jr., Rate constants for the gas-phase reactions of NO3 radicals with a series of organics in air at 298±1K. J. Phys. Chem.,88 (1984) 1210–15.

    Article  CAS  Google Scholar 

  67. Calvert, J. and Madronich, S., Theoretical study of the initial products of atmospheric oxidation of hydrocarbons. J. Geophys. Res.,92 (1987) 2211–20.

    Article  CAS  Google Scholar 

  68. Altshuller, A. P., Chemical reaction and transport of alkanes and their products in the troposphere. J. Atmos. Chem.,12 (1991) 19–62.

    Article  CAS  Google Scholar 

  69. White, C. M. (ed.), Nitrated Polycyclic Aromatic Hydrocarbons. Hüethig Publishing, Heidelberg, Germany, 1985.

    Google Scholar 

  70. Pitts, J. N., Sweetman, J. A. Zielinska, B., Atkinson, R., Winer, A. M. and Harger, W. P., Formation of nitroarenes from the reaction of polycyclic aromatic hydrocarbons with dinitrogen pentaoxide. Environ. Sci. Technol.,19 (1985) 1115–21.

    Article  CAS  Google Scholar 

  71. Zielinska, B., Arey, J., Atkinson, R. and McElroy, P., Formation of methylnitronaphthalenes from the gas-phase reactions of 1- and 2-methylnaphthalene with OH radicals and N205 and their occurrence in ambient air. Environ. Sci. Technol.,23 (1989) 723–9.

    Article  CAS  Google Scholar 

  72. Arey, J., Zielinska, B., Atkinson, R. and Winer, A. M., Polycyclic aromatic hydrocarbon and nitroarene concentrations in ambient air during a wintertime high-NO, episode in the Los Angeles Basin. Atmos. Environ.,21 (1987) 1437–44.

    CAS  Google Scholar 

  73. Nielsen, T., Seitz, B. and Ramdahl, T., Occurrence of nitro-PAH in the atmosphere in a rural area. Atmos. Environ.,18 (1984) 2159–65.

    Article  CAS  Google Scholar 

  74. Gibson, T. L., Korsog, P. E. and Wolff, G. T., Evidence for the transformation of polycyclic organic matter in the atmosphere. Atmos. Environ.,20 (8) (1986) 1575–8.

    Article  CAS  Google Scholar 

  75. Weisskoph, M., Toxic clouds can carry pollutants far and wide. Washington Post, 16 March 1988.

    Google Scholar 

  76. Subramanian, A., Tanabe, S., Tanaka, H., Hidaka, H. and Tatsukawa, R., Gain and loss rates and biological half-life of PCBs and DDE in the bodies of Adelie. penguins. Environ. Poll.,43 (1987) 39–46.

    Article  CAS  Google Scholar 

  77. Hargrave, B. T., Vas, W. P. Erickson, P. E. and Fowler, B. R., Supply of atmospheric organochlorines to food-webs in the Arctic Ocean. Sixth Int. August 1987.

    Google Scholar 

  78. Anon., Report of a new chemical hazard. New Scientist,32 (1966) 612.

    Google Scholar 

  79. Foreman, W. T. and Bidleman, T. F., Vapor pressure estimates of individual polychlorinated biphenyls and commercial fluids using gas chromatographic retention data. J. of Chrom.,330 (1985) 203–16.

    Article  CAS  Google Scholar 

  80. Tanabe, S., PCB problems in future: foresight from current knowledge. Environ. Poll.,50 (1988) 5–28.

    Article  CAS  Google Scholar 

  81. Tateya, S., Tanabe, S. and Tatsukawa, R., PCBs in the globe: possible trend of further levels in open ocean environment. In Toxic Contaminants in Large Lakes, vol. III, ed. N. W. Schmidke. Lewis Publishers, Chelsea, MI, 1988, pp. 237–81.

    Google Scholar 

  82. Swackhammer, D. L., McVeety, B. M. and Hites, R. A., Deposition and evaporation of polychlorobiphenyl congeners to and from Siskiwit Lake, Isle Royale, Lake Superior. Environ. Sci. and Technol.,22 (1988) 664–72.

    Article  Google Scholar 

  83. Lewis, R. G., Martin, B. E., Spontz, D. L. and Howes, J. E., Measurement of fugitive atmospheric emissions of polychlorinated biphenyls from hazardous waste and landfills. Environ. Sci. Technol.,19 (1985) 986–91.

    Article  CAS  Google Scholar 

  84. Hermanson, M. H. and Hites, R. A., Long-term measurements of atmospheric polychlorinated biphenyls in the vicinity of superfund dumps. Environ. Sci. and Technol.,23 (1989) 1253–8.

    Article  CAS  Google Scholar 

  85. Tanabe, S., Tatsukawa, R., Kawano, M. and Hidaka, H., Global distribution and atmospheric transport of chlorinated hydrocarbons: HCH (BHC) isomers and DDT compounds in the Western Pacific, Eastern Indian, and Antarctic Oceans. J. Oceanogr. Soc. Japan,38 (1982) 137–48.

    Article  CAS  Google Scholar 

  86. Standley, L. J. and Hites, R. A., Chlorinated organic contaminants in the atmosphere. In Organic Contaminants in the Environment, ed. K. C. Jones. Elsevier Science Publication Ltd, New York (1991).

    Google Scholar 

  87. Tanabe, S., Mori, T., Tatsukawa, R. and Miyazaki, N., Global pollution of marine mammals by PCBs, DDTs, and HCHs (BHCs). Chemosphere,12 (1983) 1269–75.

    Article  CAS  Google Scholar 

  88. Atlas, E., Bidleman, T. and Giam, C. S., Atmospheric transport of PCBs to the oceans. In PCBs and the Environment, ed. J. S. Waid. CRC Press, Boca Raton, FL, 1986, pp. 79–100.

    Google Scholar 

  89. Baker, J. E. and Eisenreich, S. J., Concentrations and fluxes of PAHs and PCBs across the air-water interface of Lake Superior. Environ. Sci. and Technol., 24 342–52.

    Google Scholar 

  90. Hoff, R. M., Muir, D. C. G. and Gritt, N. P., The annual cycle of PCBs and OCs in air in Southern Ontario I. Air concentration data. Environ. Sci. Technol.,26(19) 266–75.

    Google Scholar 

  91. Wade, T. L., Atlas, E. L., Brooks, J. M., Kennicutt II, M. C., Fox, R. G., Sericano, J., Garcia-Romero, B. and Defreitas, D., NOAA Gulf of Mexico Status and Trends Program: trace organic contaminant distribution in sediments and oysters. Estuaries,11 (1988) 171–8.

    Article  CAS  Google Scholar 

  92. Sericano, J., Wade, T. L., Atlas, E. L. and Brooks, J. M., Historical perspective on the environmental bioavailability of DDT and its derivatives to Gulf of Mexico oysters. Environ. Sci. and Technol.,24 (1990) 1541–8.

    Article  CAS  Google Scholar 

  93. Subramanian, A., Tanabe, S., Fujise, Y. and Tatsukawa, R., Organochlorine residues in Dalls and Trues porpoises collected from Northwestern Pacific and adjacent waters. Mem. Natl. Inst. Polar Res., Spec. Issue,44 (1986) 167–73.

    Google Scholar 

  94. Norstrom, R. J., Simon, M. and Muir, D. C. G., Organochlorine contaminants in arctic marine food chains: identification, geographical distribution, and temporal trends in polar bears. Environ. Sci. Technol.,22 (1988) 1063–71.

    Article  CAS  Google Scholar 

  95. Addison, R. F. and Zinck, M. E., PCBs have declined more than DDT-group residues in Arctic ringed seals (Phoca hispida) between 1972 and 1981. Environ. Sci. Technol.,20 (1986) 253–6.

    Article  CAS  Google Scholar 

  96. Olsson, M. and Reutergardh, L., DDT and PCB pollution trends in the Swedish aquatic environment. Ambio,15 (1986) 101–7.

    Google Scholar 

  97. Bidleman, T. F. and Leonard, R., Aerial transport of pesticides over the northern Indian Ocean and adjacent seas. Atmos. Environ.,16 (1982) 1099–107.

    Article  CAS  Google Scholar 

  98. Tanabe, S., Hidaka, H. and Tatsukawa, R., PCBs and chlorinated hydrocar-bon pesticides in Antarctic atmosphere and hydrosphere. Chemosphere,12 (1983) 277–88.

    Article  CAS  Google Scholar 

  99. Goldberg, E. D., Synthetic organohalides in the sea. Proc. R. Soc. London, 189 (1975) 2770–89.

    Article  Google Scholar 

  100. FAO. FAO Production Year Book. Food and Agriculture Organization, 32 Rome, (1979) p. 245.

    Google Scholar 

  101. Colson, J. G., Benzene hexachloride. In Encyclopedia of Chemical Technology, ed. R. E. Kirk and D. F. Othmer. Wiley-Interscience, New York, 1979, pp. 808–18.

    Google Scholar 

  102. Tanabe, S., Tatsukawa, R., Kawano, M. and Hidaka, H., Global distribution and atmospheric transport of chlorinated hydrocarbons: HCH (BHC) isomers and DDT compounds in the Western Pacific, Eastern Indian and Anatarctic Oceans. J. Oceanogr. Soc. Japan,38 (1982) 137–48.

    Article  CAS  Google Scholar 

  103. Ray; P. K., Prasad, A. K. and Nandan, R., Pesticides—major environmental problem. Science and Culture, 51 (1985) 363–71.

    Google Scholar 

  104. Metcalf, R. L., Organic Insecticides: Their Chemistry and Mode of Action. Interscience, New York, 1955, p. 214.

    Google Scholar 

  105. Patton, G. W., Hinckley, D. A., Walla, M. D. and Bidleman, T. F., Airborne organochlorines in the Canadian high arctic. Tellus,41B(1989) 243–55.

    Google Scholar 

  106. Wittlinger, R. and Ballschmiter, K., Global baseline pollution studies XI: Congener specific determination of polychlorinated biphenyls (PCB) and occurrence of a and y-hexachlorochlohexane (HCH), 4,4-DDE and 4,4-DDT in continental air. Chemosphere,16 (1987) 2497–513.

    Article  CAS  Google Scholar 

  107. Bumb, R. R., Crumett, W. B., Cutie, S. S., Gledhills, J. R., Hummel, R. H., Kagel, R. O., Lamparski, L. L., Luoma, E. V., Miller, D. I., Hestrick, J. J., Shadoff, L. A., Stehl, R. H. and Woods, J. A., Trace chemistries of fire: A source of chlorinated dioxins. Science,210 (1980) 385–90.

    Article  CAS  Google Scholar 

  108. Rappe, C., Marklund, S., Bergquist, P. A. and Hansson, M., Polychlorinated dibenzo-p-dioxins, dibenzofurans and other polynuclear aromatics formed during incineration and polychlorinate biphenyl fires. In Chlorinated Dioxins and Dibenzofurans in the Total Environment, ed. G. Choudry, L. H. Keith and C. Rappe. Butterworth Publishers, Stoneham, MA, 1983, pp. 99–235.

    Google Scholar 

  109. Czuczwa, J. M. and Hites, R. A., Environmental fate of combustion-generated polychlorinated dioxins and furans. Environ. Sci. and Technol.,18 (1984) 444–50.

    Article  CAS  Google Scholar 

  110. Ballschmiter, K., Buchert, H., Niemczyk, R., Munder, A. and Swerve, M., Autombile exhausts versus municipal-waste incineration as sources of the polychlorodibenzo-p-dioxins and -furans found in the environment. Chemosphere,15 (1986) 901–15.

    Article  CAS  Google Scholar 

  111. Clement, R. E., Tosine, H. M., Osborne, J., Ozvacic, V., Wong, G. and Thorndyke, S., Emissions of chlorinated organics from a municipal sewage sludge burning incinerator. Chemosphere, 16 (1987) 1895–900.

    Article  CAS  Google Scholar 

  112. Eitzer, B. D. and Hites, R. A., Polychlorinated dibenzo-p-dioxins and dibenzofurans in the ambient atmosphere of Bloomington, Indiana and atmospheric transport and deposition of polychlorinated dibenzo-p-dioxins and dibenzofurans. Environ. Sci. and Technol.,23 (1989) 1389–401.

    Article  CAS  Google Scholar 

  113. Bidleman, T. F. and Christensen, E. J., Atmospheric removal processes for high-molecular weight organochlorines. J. Geophys. Res.,84 (1979) 7857–68.

    Google Scholar 

  114. Billings, W. N. and Bidleman, T. F., High-volume collection of chlorinated hydrocarbons in urban air using three solid adsorbents. Atmos. Environ.,17 (1983) 383–91.

    Article  CAS  Google Scholar 

  115. Atlas, E. L., Madero, M. and Giam, C. S., Synthetic organic compounds in rural air and rainfall. Water, Air, and, Soil Pollution,38 (1988) 19–36.

    CAS  Google Scholar 

  116. Eisenreich, S. J., Looney, B. B. and Thornton, J. D., Airborne organic contaminants in the Great Lakes ecosystem. Environ. Sci. Technol.,15 (1981) 30–8.

    Article  CAS  Google Scholar 

  117. Bidelman, T. F., Wideqvist, U., Jansson, B. and Soderlund, R., Organochlorine pesticides and polychlorinated biphenyls in the atmosphere of southern Sweden. Atmos. Environ.,21 (1987) 641–54.

    Article  Google Scholar 

  118. Bobet, E., Bernard, M. F. and Dann, T., The measurement of PCDD and PCDF in ambient air in southwestern Ontario. Chemosphere,20 (1990) 1439–45.

    Article  CAS  Google Scholar 

  119. Smith, R. M., OKeefe, P. W., Aldous, K. and Connor, S., Continuing atmospheric studies of chlorinated dibenzofurans and dioxins in New York state. Chemosphere,20 (1990) 1447–53.

    Article  CAS  Google Scholar 

  120. Bidleman, T. F., Patton, G. W., Hinckley, D. A., Walla, M. D., Cotham, W. E. and Hargrave, B. T., Chlorinated pesticides and polychlorinated biphenyls in the atmosphere of the Canadian arctic. In Long Range Transport of Pesticides, ed. D. Kurtz. Lewis Publishers, Chelsea, Michigan, 1990, pp. 347–72.

    Google Scholar 

  121. Bidleman, T. F., Christensen, E. J., Billings, W. N. and Leonard, R., Atmospheric transport of organochlorines in the North Atlantic gyre. J. Mar. Res.,39 (1981) 443–64.

    CAS  Google Scholar 

  122. Atlas, E. and Giam, C. S., Global transport of organic pollutants: Ambient concentrations in the remote marine atmosphere. Science,211 (1981) 163–5.

    Article  CAS  Google Scholar 

  123. Tanabe, S., Hidaka, S. H. and Tatsukawa, R., PCBs and chlorinated hydrocarbon pesticides in the Antarctic atmosphere and hydrosphere. Chemo-sphere,12, (1983) 277–88.

    Article  CAS  Google Scholar 

  124. Hoff, R. M. and Chan, K. W., Atmospheric concentrations of chlordane at Mould Bay, N.W.T., Canada. Chemosphere,15 (4) (1986) 449–52.

    Article  CAS  Google Scholar 

  125. Dearth, M. A. and Hites, R. A., Complete analysis of technical chlordane using negative ionization mass spectrometry. Environ. Sci. Technol.,25 (1991) 245–54.

    Article  CAS  Google Scholar 

  126. Orth, R., Ritchie, C. and Hileman, F., Measurement of the photoinduced loss of vapor phase TCDD.Chemosphere, 18 (1989) 1275–82.

    Article  Google Scholar 

  127. Bidleman, T. F., Atmospheric processes. Environ. Sci. Technol.,22 (1988) 361–7.

    Article  CAS  Google Scholar 

  128. Foreman, W. T. and Bidleman, T. F., An experimental system for investigating vapor-particle partitioning of trace organic pollutants. Environ. Sci. Technol.,21 (1987) 869–75.

    Article  CAS  Google Scholar 

  129. Ligocki, M. P. and Pankow, J. F., Measurements of the gas/particle distribu-s of airborne polycyclic aromatic hydrocarbons. Environ. Sci. Technol.,16 (1982) 189–94.

    Article  Google Scholar 

  130. Ligocki, M. P., Leuenberger, C. and Pankow, J. F., Trace organic compounds in rain. II. Gas scavenging of neutral organic compounds. Atmos. Environ.,19 (1985) 1609–17.

    Article  CAS  Google Scholar 

  131. Ligocki, M. P., Leuenberger, C. and Pankow, J. F., Trace organic compounds in rain. III. Particle scavenging of neutral organic compounds.Atmos. Environ.,19 (1985) 1619–26.

    Article  CAS  Google Scholar 

  132. Mackay, D., Paterson, S. and Schroeder, W. H., Model describing the rates of transfer processes of organic chemicals between atmosphere and water. Environ. Sci. Technol., 20 (1986) 810–16.

    Article  CAS  Google Scholar 

  133. Duinker, J. C. and Bouchterall, F., On the distribution of atmospheric PCB congeners between vapour phase, aerosols, and rain. Environ. Sci. Technol.,23 (1989) 57–62.

    Article  CAS  Google Scholar 

  134. McVeety, B. D. and Hites, R. A., Atmospheric deposition of polycyclic aromatic hydrocarbons to water surfaces: a mass balance approach. Atmos. Environ.,22 (1988) 511–36.

    Article  CAS  Google Scholar 

  135. GESAMP-IMO/FAO/UNESCO/WMO/IAEA/UN/UNEP. Joint Group of experts on the Scientific Aspects of Marine Pollution. The atmospheric input of trace species to the world ocean. Rep. Stud. GESAMP (38), 1989.

    Google Scholar 

  136. Bunce, N. J., Landers, J. P., Langshaw, J. and Naka, J. S., An assessment of the importance of direct solar degradation of some simple chlorinated benzenes and biphenyls in the vapor phase. Environ. Sci. Technol.,23 (1989) 213–18.

    Article  CAS  Google Scholar 

  137. Czuczwa, J. M. and Hites, R. A., Airborne dioxins and dibenzofurans: Sources and fates. Environ. Sci. Technol.,20 (1986) 195–200.

    Article  CAS  Google Scholar 

  138. Likens, G. E., Edgerton, E. S. and Galloway, J. N., The composition and deposition of organic carbon in precipitation. Tellus,35b (1983) 16–24.

    Google Scholar 

  139. Norton, R. B., Measurements of formate and acetate in precipitation at Niwot ridge, and Boulder, Colorado. Geophys. Res.Leu.,11 (1985) 769–72.

    Article  Google Scholar 

  140. Andreae, M. O., Talbot, R. W. and Li, S.-M., Atmospheric measurements of pyruvic and formic acid. J. Geophys. Res.,92(1987) 6635–41.

    Article  CAS  Google Scholar 

  141. Andreae, M. O., Talbot, R. W., Andreae, T. W. and Harriss, R. C., Formicand acetic acid over the central Amazon region, Brazil, 1. dry season. JGeophys. Res.,93 (1988) 1616–24.

    CAS  Google Scholar 

  142. Talbot, R. W., Beecher, K. M., Harriss, R. C. and Cofer, W. R., III, Atmospheric geochemistry of formic and acetic acids at a mid-latitude temperate site. J. Geophys. Res.,93 (1988) 1638–52.

    Article  CAS  Google Scholar 

  143. Dawson, G. A. and Farmer, J. C., Soluble atmospheric trace gases in the southwestern United States, 2. Organic species HCHO, HCOOH, CH3COOH. J.Geophys.Res.,93 (1988) 5200–6.

    Article  CAS  Google Scholar 

  144. Li, S.-M. and Winchester, J. W., Geochemistry of organic and inorganic ions of late winter Arctic aerosols. Atmos. Environ.,23 (1989) 2401–15.

    Article  CAS  Google Scholar 

  145. Grosjean, D., Cauwenberghe, K. V., Schmid, J. P., Kelley, P. E. and Pitts, J. E., Jr., Identification of C3—C10 aliphatic dicarboxylic acids in airborne particulate matter. Environ. Sci.Technol.,12 (1978) 313–17.

    Article  CAS  Google Scholar 

  146. Chameides, W. L. and Davis, D. D., Aqueous-phase source of formic acid in clouds. Nature,304 (1983) 427–9.

    Article  CAS  Google Scholar 

  147. Jacob, D. J., The chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate. J.Geophys. Res.,91 (1986) 9807–26.

    Article  CAS  Google Scholar 

  148. Kawamura, K., Ng, L.-L. and Kaplan, I. R., Determination of organic acids (CI—C10) in the atmosphere, motor exhaust, and engine oils. Environ. Sci. Technol.,19 (1985) 2082–6.

    Article  Google Scholar 

  149. Jacob, D. J. and Wofsy, S. C., Photochemistry of biogenic emissions over the Amazon forest. J. Geophys. Res.,93 (1988) 1477–86.

    Article  CAS  Google Scholar 

  150. Weathers, K. C., Likens, G. E., Bormann, F. H., Eaton, J. S., Bowden, W. B., Anderson, J. L., Keene, W. C., Kimball, K. D., Huth, P. and Smiley, D., A regional acidic cloud/fog water event in the eastern United States. Nature,319 (1967) 657–8.

    Article  Google Scholar 

  151. Winiwarter, W., Puxbaum, H., Fuzzi, S., Facchini, M. C., Orsi, G., Beltz, N., Enderle, K. and Jaeschke, W., Organic acid gas and liquid-phase measurements in Po Valley fall—winter conditions in the presence of fog. Tellus,40b (1988) 346–57.

    Google Scholar 

  152. Grosjean, D., Aldehydes, carboxylic acids, and inorganic nitrate during NSMCS. Atmos. Environ.,22 (1988) 1637–48.

    Article  CAS  Google Scholar 

  153. Grosjean, D., Tuazon, E. C. and Fujita, E., Ambient formic acid in Southern California air: A comparison of two methods, Fourier transform infrared spectroscopy and alkaline trap liquid chromatography with u.v. detection. Environ. Sci. Technol.,24 (1990) 144–6.

    Article  CAS  Google Scholar 

  154. Galloway, J. N., Likens, G. E., Keene, W. C. and Miller, J. M., The composition of precipitation in remote areas of the world. J. Geophys. Res.,87 (1982) 8871–786.

    Article  Google Scholar 

  155. Keene, W. C., Galloway, J. N. and Holden, J. D., Measurement of weak organic acidity in precipitation from remote areas of the world.J. Geophys. Res.,88 (1983) 5122–30.

    Article  Google Scholar 

  156. Keene, W. C. and Galloway, J. N., The biogeochemical cycling of formic and acetic acids through the troposphere: an overview of current understanding. Tellus,40b (1988) 322–34.

    Google Scholar 

  157. Chapman, E. G., Sklarew, D. S. and Flickinger, J. S., Organic acids in springtime Wisconsin precipitation samples. Atmos. Environ.,20 (1986) 1717–25.

    Article  CAS  Google Scholar 

  158. Legrand, M. and Saigne, C., Formate, Acetate and methanesulfonate measurements in Antarctic ice: some geochemical implications.Atmos. Environ.,22 (1988) 1101–17.

    Google Scholar 

  159. Li, S.-M. and Andreae, M. O., unpublished data.

    Google Scholar 

  160. Keene, W. C., Talbot, R. W., Andreae, M. O., Beecher, K., Berresheim, H., Castro, M., Farmer, J. C., Galloway, J. N., Hoffmann, M. R., Li, S.-M., Maben, J. R., Munger, J. W., Norton, R. B., Pszenny, A. A. P., Puxbaum, H., Westberg, H. and Winiwarter, W., An intercomparison of measurementsystems for vapor and particulate phase concentrations of formic and acetic acids. J. Geophys. Res.,94 (1989) 6457–71.

    Article  CAS  Google Scholar 

  161. Arlander, D. W., Cronin, D. R., Farmer, J. C., Menzia, F. A. and Westberg, H. H., Gaseous oxygenated hydrocarbons in the remote marine troposphere. J.Geophys.Res.,95 (1990) 16391–404.

    Article  CAS  Google Scholar 

  162. Norton, R. B., Measurements of gas-phase formic and acetic acids at the Mauna Loa, Hawaii, Observatory. J. Geophys. Res., in press.

    Google Scholar 

  163. Nicholas, H. J., Miscellaneous volatile plant products. In Phytochemistry, vol. 2, ed. L. P. Miller. Van Nostrand Reinhold, New York, 1973, pp. 381–99.

    Google Scholar 

  164. Crutzen, P. J., The role of NO and NO2 in the chemistry of the troposphere and stratosphere. Ann Rev. Earth Planet. Sci.,7 (1979) 443–72.

    Article  CAS  Google Scholar 

  165. Pandis, S. N. and Seinfeld, J. H., Sensitivity analysis of a chemical mechanism for aqueous-phase atmospheric chemistry. J. Geophys. Res.,94 (1989) 1105–26.

    Article  CAS  Google Scholar 

  166. Madronich, S., Chatfield, R. B., Calvert, J. G., Moortgat, G. K., Veyret, B. and Lesclaux, R. A., Photochemical origin for acetic acid in the troposphere. Geophys. Res. Lett.,17 (1990) 2361–4.

    Article  CAS  Google Scholar 

  167. Chameides, W. L., The photochemistry of a remote marine stratiform cloud. J. Geophys. Res.,89 (1984) 4739–55.

    Article  CAS  Google Scholar 

  168. Rasmussen, R. A. and Khalil, M. A. K., Isoprene over the Amazon basin. J. Geophys. Res.,93 (1988) 1417–2].

    Google Scholar 

  169. Zimmerman, P. R., Greenberg, J. P. and Westburg, C. E., Measurements of atmospheric hydrocarbons and biogenic emission fluxes in the Amazon boundary layer. J. Geophys. Res.,93 (1988) 1407–16.

    Article  CAS  Google Scholar 

  170. Graedel, T. E. and Eisner, T., Atmospheric formic acid from formicine ants: a preliminary assessment. Tellus,40B (1988) 335–9.

    Google Scholar 

  171. Madronich, S. and Calvert, J. G., Permutation reactions of organic peroxy radicals in the troposphere. J.Geophys.Res.,95 (1990) 5697–715.

    Article  CAS  Google Scholar 

  172. Grosjean, D., Aerosols. In Ozone and Other Photochemical Oxidants. National Academy of Sciences-National Research Council, Committee on Medical and biological effects of environmental pollutants, Washington, DC, 1977, pp. 45–125.

    Google Scholar 

  173. Gregory, G. L., Harriss, R. C., Talbot, R. W., Rasmussen, R. A., Garstang, M., Andreae, M. O., Hinton, R. R., Browell, E. V., Bech, S. M., Khalil, M. A. K., Ferek, R. J. and Harris, S. V., Air chemistry over the tropical forest of Guyana. J. Geophys. Res.,91 (1986) 8603–12.

    Article  CAS  Google Scholar 

  174. Friedmann, E. I., Roth, W. C. and Turner, J. B., Calcium oxalate crystals in the aragonite producing green alga, Penicillus and related genera. Sciences,177 (1972) 891–3.

    Article  CAS  Google Scholar 

  175. Junge, C. E., Residence time and variability of tropospheric trace gases. Tellus, 26 (1974) 477–88.

    Article  CAS  Google Scholar 

  176. Calvert, J. G. and Pitts, J. N., Jr., Photochemistry. Wiley, New York, 1966, pp. 8–99.

    Google Scholar 

  177. Dawson, G. A., Farmer, J. C. and Moyers, J. L., Formic and acetic acids in the atmosphere of the southwest U.S.A. Geophys. Res.Letts.,7 (1980) 725–8.

    Article  CAS  Google Scholar 

  178. Altshuller, A. P., The role of nitrogen oxides in nonurban ozone formation in the planetary boundary layer over N. America, W. Europe and adjacent areas of ocean.Atmos. Environ.,20 (1986) 245–68.

    CAS  Google Scholar 

  179. Kasting, J. F. and Singh, H. B., Nonmethane hydrocarbon in the troposphere: Impact on the odd-hydrogen and odd-nitrogen chemistry. J. Geophys. Res.,91 (1986) 13239–56.

    Article  Google Scholar 

  180. Logan, J. A., Nitrogen oxides in the troposphere: global and regional budgets. J. Geophys. Res.,88 (1983) 10785–807.

    Article  CAS  Google Scholar 

  181. Logan, J. A., Prather, M. J., Wofsy, S. C. and McElroy, M. B., Tropospheric chemistry: a global perspective. J.Geophys.Res.,86 (1981) 7210–54.

    Article  CAS  Google Scholar 

  182. Singh, H. B., Reactive nitrogen in the troposphere. Environ. Sci. Technol., 21 (1987) 320–7.

    Article  CAS  Google Scholar 

  183. Dickerson, R. R., Reactive nitrogen compounds in the Arctic. J. Geophys. Res.,90 (1985) 10739–43.

    Article  Google Scholar 

  184. Fahey, D. W., Hübler, G., Parrish, D. D., Williams, E. J., Norton, R. B., Ridley, B. A., Singh, H. B., Liu, S. C. and Fehsenfeld, F. C., Reactive nitrogen species in the troposphere: Measurements of NO, NO2, HNO3, particulate nitrate, peroxyacetyl nitrate (PAN), 03, and total reactive odd nitrogen (NOr) at Niwot Ridge, Colorado. J. Geophys. Res., 91 (1986) 9781–93.

    Article  CAS  Google Scholar 

  185. Roberts, J. M., The atmospheric chemistry of organic nitrates.Atmos. Environ.,24 (1990) 243–87.

    Google Scholar 

  186. Singh, H. B. and Hanst, P. L., Peroxyacetyl nitrate (PAN) in the unpolluted atmosphere: an important reservoir for nitrogen oxides. Geophys.Res. Lett.,8 (1981) 941–4.

    Article  CAS  Google Scholar 

  187. Singh, H. B. and Salas, L. J., Peroxyacetyl nitrate in the free troposphere. Nature (London),302 (1983) 326–8.

    Article  CAS  Google Scholar 

  188. Buhr, M. P., Parrish, D. D., Norton, R. B., Fehsenfeld, F. C., Sievers, R. E. and Roberts, J. M., Contribution of organic nitrates to the total odd-nitrogen budget at a rural eastern US site. J. Geophys. Res.,95 (1990) 9809–16.

    Article  Google Scholar 

  189. Ridley, B. A., Shetter, J. D., Walega, J. G., Madronich, S., Elsworth, C. M. and Grahek, F., The behavior of some organic nitrates at Boulder and Niwot Ridge, Colorado. J. Geophys. Res.,9 (1990) 13949–62.

    Article  Google Scholar 

  190. Atherton, C. S. and Pennner, J. E., Nitrogen oxide transformation in a tropospheric model. Tellus,40B (1988) 380–92.

    Google Scholar 

  191. Atherton, C., Organic nitrates in remote marine environments: evidence for long-range transport. Geophys. Res. Lett.,16 (1989) 1289–92.

    Article  CAS  Google Scholar 

  192. Atherton, C. S. and Pennner, J. E., The effect of biogenic hydrocarbons on the transformation of nitrogen oxides in the troposphere.J.Geophys.Res.,95 (1990) 14027–38.

    Article  Google Scholar 

  193. Atkinson, R. and Lloyd, A. C., Evaluation of kinetic and mechanistic data for modeling of photochemical smog. J. Phys. Chem. Ref. Data,13(2) (1984) 315–444.

    Article  CAS  Google Scholar 

  194. Darnall, K. R., Carter, W. P. L., Winer, A. M., Lloyd, A. C. and Pitts, J. N., Jr., Importance of R02+NO in alkyl nitrate formation from C4–C6 alkane photooxidations under simulated atmospheric conditions. J.Phys.Chem.,80 (1976) 1948–50.

    Article  CAS  Google Scholar 

  195. Atkinson, R. A., Aschmann, S. M., Carter, W. P. L., Winer, A. M. and Pitts, J. N., Jr., Alkyl nitrate formation from the NO„-air photooxidation of C2–C8 alkanes. J. Phys. Chem.,86 (1982) 4563–9.

    Article  CAS  Google Scholar 

  196. Bandow, H., Okuda, M. and Akimoto, H., Mechanism of the gas-phase reactions of C3H6 and NO3 radicals. J. Phys.Chem.,84 (1980) 3604–8.

    Article  CAS  Google Scholar 

  197. Shepson, P. B., Edney, E. O., Kleindienst, T. E., Pittman, G. H., Namie, G. R. and Cupitt, L. T., The production of organic nitrates from hydroxyl and nitrate radical reaction with propylene. Environ. Sci. Technol.,19 (1985) 849–54.

    Article  CAS  Google Scholar 

  198. Brewer, D. A., Ogliaruso, M. A., Augustsson, T. R. and Levine, J. S., The oxidation of isoprene in the troposphere: Mechanism and model calculations. Atmos.Environ.,18 (1984) 2723–44.

    Article  CAS  Google Scholar 

  199. Lloyd, A. C., Atkinson, R., Lurmann, F. W. and Nitta, B., Modeling potential ozone impacts from natural hydrocarbons-I. Development and testing of a chemical mechanism for the NOx-air photooxidations of isoprene and a-pinene under ambient conditions. Atmos.Environ.,17 (1983) 1931–50.

    Article  CAS  Google Scholar 

  200. Grosjean, D., Distribution of atmospheric nitrogenous pollutants at a Los Angeles smog receptor site. Environ. Sci. Technol.,17 (1983) 13–17.

    Article  CAS  Google Scholar 

  201. Williams, I. H., Gas chromatographic techniques for the identification of low concentrations of atmospheric pollutants. Anal.Chem.,37 (1965) 1723–32.

    Article  CAS  Google Scholar 

  202. Jonsson, A., Sampling and gas chromatographic analysis of volatile organic pollutants. PhD thesis, University of Stockholm, Stockholm, Sweden, 1985 (cited in Ref. 186).

    Google Scholar 

  203. Juttner, F. A., Cryotrap technique for the quantitation of monoterpenes in humid and ozone-rich forest air.J.Chromatog.,442 (1988) 157–63.

    Article  Google Scholar 

  204. Atlas, E., Evidence for >_ C3 alkyl nitrates in rural and remote atmospheres. Nature,331 (1988) 426–8.

    Article  CAS  Google Scholar 

  205. Flocke, F., Volz-Thomas, A. and Kley, D., Measurements of alkyl nitrates in rural and polluted air masses. Atmos. Environ.,25A (1991) 1952–60.

    Google Scholar 

  206. Schuetzle, D., Cronn, D., Crittenden, A. L. and Charlson, R. J., Molecular composition of secondary aerosol and its possible origin. Environ. Sci. Technol.,9 (1975) 838–41.

    Article  CAS  Google Scholar 

  207. Cronn, D. R., Charlson, R. J., Knights, R. L., Crittneden, A. L. and Appel, B. R., A survey of the molecular nature of primary and secondary components of particles in urban air by high resolution mass spectrometry. Atmos. Environ.,11 (1977) 929.

    Article  CAS  Google Scholar 

  208. Guicherit, R., Ozone on an urban and regional scale: with special reference • to the situation in the Netherlands. In Proceedings of the NATO Advanced Research Workshop on Tropospheric Ozone, Lillehammer, Norway, 1–5 June 1987.

    Google Scholar 

  209. Glavas, S. and Schurath, U., Concentration and storage of peroxyacetylnitrate (PAN) for mobile field measurements in tropospheric air. Chimika Chronika,12 (1983) 89–97.

    CAS  Google Scholar 

  210. Singh, H. B. and Salas, L. J., Measurements of peroxyacetylnitrate (PAN) and peroxypropionyl nitrate (PPN) at selected urban, rural and remote sites. Atmos. Environ.,23 (1989) 231–8.

    Article  CAS  Google Scholar 

  211. Grosjean, D., Aldehydes, carboxylic acids and inorganic nitrate during NSMCS. Atmos. Environ.,22 (1988) 1637–48.

    Article  CAS  Google Scholar 

  212. Wunderli, S. and Gehrig, R., Influence of temperature on formation and stability of surface PAN and ozone. A two year field study in Switzerland. Atmos. Environ.,25A (1991) 1599–608.

    Article  Google Scholar 

  213. Singh, H. B., Salas, L. J., Shigeishi, H., Smith, A. J., Scribner, E. and Cavanagh, L. J., Atmospheric distributions, sources and sinks of selected halocarbons, hydrocarbons, SF6 and N20. EPA 600/3–79–107, Research Triangle Park, NC, 1979.

    Google Scholar 

  214. Bottenheim, J. W., Brice, K. A. and Anlauf, K., Discussion on a Lagrangian trajectory model describing long-range transport of oxides of nitrogen, the incorporation of PAN in the chemical mechanism, and supporting measurements of PAN and nitrate species at rural sites in Ontario, Canada. Atmos. Environ.18(1984) 2609–19.

    Article  CAS  Google Scholar 

  215. Bottenheim, J. W., Gallant, A. J. and Brice, K. A., Measurement of NOS, species and 03 at 82°N latitude. Geophys.Res.Letts.,13 (1986) 113–16.

    Article  CAS  Google Scholar 

  216. Williams, E. L., III and Grosjean, D., Peroxypropionyl nitrate at a southern California mountain forest site. Environ.Sci.Technol.,25 (1991) 653–9.

    Article  CAS  Google Scholar 

  217. Ridley, B. A., Shetter, J. D., Gandrud, B. W., Salas, I. J., Singh, H. B., Carroll, M. A., Hübler, G., Albritton, D. L., Hastie, D. R., Schiff, H. I., MacKay, G. I., Karechi, D. R., Davis, D. D., Bradshaw, J. D., Rodgers, M. O., Sandholm, S. T., Torres, A. L., Condon, E. P., Gregory, G. L. and Beck, S. M., Ratios of peroxyacetyl nitrate to active nitrogen observed during aircraft flights over the eastern Pacific ocean and continental United States. J. Geophys. Res.,95 (1990) 10179–92.

    Article  Google Scholar 

  218. Rudolph, J., Vierkorn-Rudolph, B. and Meixner, F. X., Large-scale distribution of peroxyacetyl nitrate. Results from the STRATOZ III flights. J.Geophys. Res.,92 (1987) 6653–61.

    Article  CAS  Google Scholar 

  219. Bottenheim, J. W. and Gallant, A. J., The occurrence of peroxyacetyl nitrate over the Atlantic Ocean east of North America during WATOX-86. Global Biogeochemical Cycles,1 (1987) 369–80.

    Article  CAS  Google Scholar 

  220. Walega, J. G., Ridley, B. A., Madronich, S., Grabek, F. E., Shetter, J. D., Sauvain, T. D., Hain, C. T., Merrill, J. T., Bodhaine, B. A. and Robinson, E., Observations of peroxyacetyl nitrate, peroxypropionyl nitrate, methyl nitrate, and ozone during MLOPEX. J.Geophys.Res.,97(1992), 10 311–30.

    Google Scholar 

  221. Gallagher, M. S., Carsey, T. P. and Farmer, M. L., Peroxyacetyl nitrate in the North Altantic marine boundary layer. Global Biogeochemical Cycles,4 (1990) 297–308.

    Article  CAS  Google Scholar 

  222. Singh, H. B., Condon, E., Vedder, J., OHara, D., Ridley, B. A., Gandrud, B. W., Shetter, J. D., Salas, L. J., Huebert, G., Hübler, G., Carroll, M. A., Albritton, D. L., Davis, D. D., Bradshaw, J. D., Sandholm, S. T., Rodgers, M. O., Beck, S. M., Gregory, G. L. and Lebel, P. J., PAN measurements during CITE 2: Atmospheric distribution and percursor relationship. J.Geophys.Res.,95(1990) 10163–78.

    Article  Google Scholar 

  223. Carroll, M. A., Hastie, D. R., Ridley, B. A., Rodgers, M. O., Torres, A. L., Davis, D. D., Bradshaw, J. D., Sandholm, S. T., Schiff, H. J., Karechi, D. R., Harris, G. W., MacKay, G. I., Gregory, G. L., Condon, E. P., Trainer, M., Hübler, G., Montzka, D. D., Madronich, S., Albritton, D. L., Singh, H. B., Beck, S. M., Shipham, M. C. and Bachmeier, A. S., Aircraftmeasurements of NO„ over the eastern Pacific and continental United States and implications for ozone production. J. Geophys. Res.,95 (1990) 10 205–33.

    Google Scholar 

  224. Ridley, B. A., Carroll, M. A., Dunlap, D. D., Trainer, M., Sachse, G. W., Gregory, G. L. and Condon, E. P., Measurements of NO„ over the eastern Pacific Ocean and southwestern United States during the spring 1984 NASA GTE aircraft program. J. Geophys. Res.,94(1989) 5043–67.

    Google Scholar 

  225. Ridley, B. A., Recent measurements of oxidized nitrogen compounds in the troposphere. Atmos. Environ.,25A(1991) 1905–26.

    Article  Google Scholar 

  226. Atlas, E., Schauffier, S. M., Merrill, J. T., Hahn, C. J., Ridley, B. A., Walega, J. G., Greenberg, J. P., Heidt, L. and Zimmerman, P. R., Alkyl nitrate and selected halocarbon measurements at Mauna Loa Observatory, Hawaii. J. Geophys. Res.,97(1992) 10, 331–48.

    Google Scholar 

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Atlas, E.L., Li, S.M., Standley, L.J., Hites, R.A. (1994). Natural and Anthropogenic Organic Compounds in the Global Atmosphere. In: Hewitt, C.N., Sturges, W.T. (eds) Global Atmospheric Chemical Change. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-3714-8_8

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