Skip to main content

Kinetics of Metamorphic Reactions

  • Chapter
Book cover Metamorphic Processes

Abstract

Metamorphic rocks exposed at the earth’s surface are metastable, with respect to P-T-X conditions in the atmosphere. This is because of the extremely slow rate of reaction between the rocks and the atmosphere, and between the minerals of the rocks themselves, under these low-temperature conditions. If this were not so, the rocks would contain only low P-T assemblages, and we would have no evidence of metamorphism ever having occurred at depth.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Anderson, D. E. and Buckley, G. R. (1973). Zoning in garnets—diffusion models. Contribs. Mineralogy & Petrology, 40, 87–104.

    Article  Google Scholar 

  2. Bischoff, J. L. and Fyfe, W. S. (1968). Catalysis, inhibition, and the calcite-aragonite problem. I. The aragonite-calcite transformation. Amer. J. Science, 266, 65–79.

    Article  Google Scholar 

  3. Brophy, J. H., Rose, R. M. and Wulff, J. (1964). The Structure and Properties of Materials. Vol. II. Thermodynamics of Structure, 62–111. New York: J. Wiley & Sons, Inc.

    Google Scholar 

  4. Brown, W. H., Fyfe, W. S. and Turner, F. J. (1962). Aragonite in California glaucophane schists, and the kinetics of the aragonite-calcite transformation.J. Petrology, 3, 566–82.

    Google Scholar 

  5. Clemm, P. J. and Fisher, J. C. (1954). The influence of grain boundaries on the nucleation of secondary phases. Acta Metallurgica, 3, 70–3.

    Article  Google Scholar 

  6. Fyfe, W. S. (1964). Geochemistry of Solids. An Introduction, 151–69; 178–92. New York: McGraw-Hill Book Co. Inc.

    Google Scholar 

  7. Fyfe, W. S., Turner, F. J. and Verhoogen, J. (1958). Metamorphic reactions and metamorphic facies. Geol. Soc. America Memoir, 73, 53–103.

    Google Scholar 

  8. Giletti, B. J. and Anderson, T. F. (1972). Diffusion of oxygen in phlogo-pite. Geol. Soc. America Abstracts, 4, 517.

    Google Scholar 

  9. Green, H. W. (1972). Metastable growth of coesite in highly strained quartz.J. Geophys. Research, 77, 2478–82.

    Article  Google Scholar 

  10. Greenwood, H. J. (1963). The synthesis and stability of anthophyllite.J. Petrology, 4, 317–51.

    Google Scholar 

  11. Hobbs, B. E. (1968). Recrystallization of single crystals of quartz. Tectono-physics, 6, 353–401.

    Article  Google Scholar 

  12. Jensen, M. L. (1965). The rational and geological aspects of solid diffusion. Canadian Mineralogist, 8, 271–90.

    Google Scholar 

  13. Kingery, W. D. (1960). Introduction to Ceramics. 161–78; 217–43; 286–99; 316–40. New York: J. Wiley & Sons, Inc.

    Google Scholar 

  14. Kridelbaugh, S. J. (1973). The kinetics of the reaction: calcite +quartz = wollastonite+carbon dioxide at elevated temperatures and pressures. Amer. J. Science, 273, 757–77.

    Article  Google Scholar 

  15. Kunzler, R. H. and Goodell, H. G. (1970). The aragonite-calcite transformation: a problem in the kinetics of a solid-solid reaction. Amer. J. Science, 269, 360–91.

    Article  Google Scholar 

  16. Lin, T. H. and Yund, R. A. (1972). Potassium and sodium self-diffusion in alkali feldspar. Contribs. Mineralogy & Petrology, 34, 177–84.

    Article  Google Scholar 

  17. Moffatt, W. G., Pearsall, G. W. and Wulff, J. (1964). The Structure and Properties of Materials. Vol. I. Structure, 16–1. New York: J. Wiley & Sons, Inc.

    Google Scholar 

  18. Newton, R. C., Goldsmith, J. R. and Smith, J. V. (1969). Aragonite crystallization from strained calcite at reduced pressures and its bearing on aragonite in low-grade metamorphism. Contribs. Mineralogy & Petrology, 22, 335–48.

    Article  Google Scholar 

  19. Petrovič, R. (1974). Diffusion of alkali ions in alkali feldspars. In The Feldspars, Ed. MacKenzie, W. S. and Zussman, J. 174–82. Manchester University Press.

    Google Scholar 

  20. Shewmon, P. G. (1963). Dißusion in Solids. New York: McGraw-Hill Book Co.

    Google Scholar 

  21. Sippel, R. F. (1963). Sodium self diffusion in minerals, Geochim. et Cosmochim. Acta, 27, 107–20.

    Article  Google Scholar 

  22. Turner, F. J. (1968). Metamorphic Petrology. Mineralogical and Field Aspects. New York: McGraw-Hill Book Co.

    Google Scholar 

  23. Vance, J. A. (1968). Metamorphic aragonite in the prehnite-pumpellyite facies, northwest Washington. Amer. J. Science, 266, 299–315.

    Article  Google Scholar 

  24. Vernon, R. H. (1969). The Willyama Complex, Broken Hill area.J. Geol. Soc. Australia, 16, 20–55.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1976 R. H. Vernon

About this chapter

Cite this chapter

Vernon, R.H. (1976). Kinetics of Metamorphic Reactions. In: Metamorphic Processes. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-1109-4_3

Download citation

  • DOI: https://doi.org/10.1007/978-94-015-1109-4_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-04-552020-6

  • Online ISBN: 978-94-015-1109-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics