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Abstract

‘Ceramic Steel?’1 is the title of the first scientific paper to highlight the possibilities offered by the ‘transformation toughening’ mechanism which occurs in certain zirconia ceramics. Since the publication of this seminal work in 1975, considerable research, development, and marketing effort has been expended on this single material which offers the traditional ceramic benefits of hardness, wear resistance and corrosion resistance, without the characteristic ceramic property of absolute brittleness. The aim of this review is to select some of the more significant milestones which have measured the progress and problems of this fascinating material throughout its development as a structural ceramic. Particular emphasis has been placed on tetragonal zirconia polycrystals (TZPs), which represent (in terms of the number of producers) the most common form of zirconia in engineering applications.

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References

  1. Garvie, R. C., Hannik, R. H. J. and Pascoe, R. T., Ceramic steel?, Nature (London), 258 (1975) 5537.

    Article  Google Scholar 

  2. Stevens, R., An introduction to zirconia, 2nd edn, Magnesium Elecktron Publication No. 113, Magnesium Elecktron Inc., New Jersey, 1986.

    Google Scholar 

  3. Heuer, A A. and Hobbs, L. W., Advances in ceramics, Vol. 3, Science and technology of zirconia, The American Ceramic Society, Ohio, 1981.

    Google Scholar 

  4. Claussen, N., Rühle, M. and Heuer, A A., Advances in ceramics, Vol. 12, Science and technology of zirconia II, The American Ceramic Society, Ohio, 1983.

    Google Scholar 

  5. Somiya, S., Yamamoto, N. and Hanagida, H., Advances in Ceramics, Vol. 24, Science and technology of zirconia III, The American Ceramic Society, Ohio, 1988.

    Google Scholar 

  6. Lange, F. F., Transformation toughening: Parts 1–4, J Mater. Sci., 17 (1982) 225–54.

    Article  CAS  Google Scholar 

  7. Tosoh Manufacturing Co., Tokyo, Technical Bulletin TZ3Y Ceramics.

    Google Scholar 

  8. Blackburn, S., Kerridge, C. R. and Senhenn, P. G., Toughened zirconia ceramics from electro-refined PSZ powders, Unitec Ceramics, Technical Publication, 1987, Stafford, UK.

    Google Scholar 

  9. Dransfield, G. P., Fothergill, K. A. and Egerton T. A., The use of plasma synthesis and pigment coating technology to produce an yttria stabilised zirconia having superior properties. Presented at the European Ceramic Society Conference, Maastricht, 1989.

    Google Scholar 

  10. Rhone-Poulenc Ltd, Technical Literature.

    Google Scholar 

  11. Allen, T. M., Birkby, I. and Stevens, R., `Nature and effect of defects introduced during the fabrication of zirconia engineering ceramics, Powder Metallurgy, 31 (1) (1988) 23.

    Google Scholar 

  12. Tsukuma, K., Ueda, K. and Shiomi, M., Mechanical properties of isostatically hot-pressed zirconia (yttria)/alumina composites. Presented at the 38th Annual Pacific Coast Regional Meeting of American Ceramic Society, Irvine California, 1985.

    Google Scholar 

  13. Swain, M. V. and Rose, L. R. F., Strength limitations of transformation toughened zirconia alloys, J Am. Ceram. Soc., 69 (7) (1986) 511.

    Article  CAS  Google Scholar 

  14. Tsukuma, K., Kubota, Y. and Tsukidate, T., Thermal and mechanical properties of yttria-stabilised tetragonal zirconia polycrystals, Advances in ceramics., Vol. 12, The American Ceramic Society, Ohio, 1983.

    Google Scholar 

  15. Swab, J. J., Katz, R. N. and Starita, C. J., Effects of oxygen nonstoichemetry on the high temperature performance of an yttria tetragonal zirconia polycrystal material, Advanced Ceramic Materials, Vol. 3, No. 3, American Ceramic Society, Ohio, 1988.

    Google Scholar 

  16. Manabe, Y., Fujikawa, T., Ueda, M. and Inoue, Y., Effect of oxygen HIP for oxide ceramics. Presented at the 1st European Ceramic Society Conference, held at Maastricht, Netherlands, June 18–23, 1989.

    Google Scholar 

  17. Sato, T. and Shimada, M., Transformation of yttria doped tetragonal zirconia polycrystals by annealing in water,.. Am. Ceram. Soc., 68 (1985) 356.

    Article  CAS  Google Scholar 

  18. Lange, F. F., Dunlop, G. L. and Davis, B. I., Degradation during aging of transformation-toughened Zr02-Y203 materials at 250°C. J Am. Ceram. Soc., 69 (1986) 237.

    Article  CAS  Google Scholar 

  19. Masaki, T., Mechanical properties of yttria partially stabilised zirconia after aging at low temperatures, Int. J. High Tech. Ceram., 2 (1986).

    Google Scholar 

  20. Wang, J. and Stevens, R., Surface toughening of TZP ceramics by low temperature ageing, Ceram. Int., 15 (1989) 15.

    Article  Google Scholar 

  21. Birkby, I., Harrison, P. and Stevens, R., The effect of surface transformations on the wear behaviour of zirconia TZP ceramics, J Europ. Ceram. Soc., 5 (1989).

    Google Scholar 

  22. Rainforth, W. M., Stevens, R. and Nutting, J., Observations on the sliding wear of transformation toughened ceramics. Presented at the 1st European Ceramic Society Conference held at Maastricht, Netherlands, June 18–23, 1989.

    Google Scholar 

  23. Iwasa, M. and Kinoshita, M., Friction and wear of bearing steel sliding on ceramics measured by ball on disc method, J. Ceram. Soc. Japan, 95 (9) (1987) 899.

    Google Scholar 

  24. Becker, P. C., Libsch, T. A. and Rhee, S. K., Wear mechanisms of toughened zirconias, Ceramic Engineering and Science Procs, Conf. on Automotive Materials, American Ceramic Society, 1985.

    Google Scholar 

  25. Kingon, A. J., Erosive wear of some zirconia based ceramics, Procs 6th Cimtec Conf. on High Tech Ceramics, Milan, Italy, 1986.

    Google Scholar 

  26. Wada, S. and Watanabe, N., Erosion rate of zirconia ceramics, J. Ceram. Soc. Japan, 96 (5) (1988) 599.

    Article  CAS  Google Scholar 

  27. Wakai, F., Sakaguchi, S. and Yosoo, M., Superplasticity of TZP’s,Advanced Ceramic Materials, 1 (3) (1986) 259.

    CAS  Google Scholar 

  28. Materials Matter,Dept of Trade and Industry Technical Publication, HMSO, 1989.

    Google Scholar 

  29. The CARE Consortium, Department of Trade and Industry Technical Publication, HMSO, 1988.

    Google Scholar 

  30. Fingerle, D., Gundel, W. and Olapinski, H., Friction and wear reduction by ceramic components, Proc. 2nd Int. Conf on Ceramic Materials and Components for Engines, Lubeck-Travemunde, 1986.

    Google Scholar 

  31. Claussen, N., Strengthening strategies for zirconia toughened ceramics (ZTC) at high temperatures, Mater. Sci. Engng, 71 (23) (1985).

    Google Scholar 

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© 1991 Elsevier Applied Science Publishers Ltd

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Birkby, I., Hodgson, H. (1991). Progress with Zirconia Ceramics. In: Riley, F.L. (eds) 3rd European Symposium on Engineering Ceramics. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-7990-4_12

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  • DOI: https://doi.org/10.1007/978-94-011-7990-4_12

  • Publisher Name: Springer, Dordrecht

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