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Grafting of Polyolefins to Silane Treated Surfaces by Free-Radical Reactions

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Abstract

The effect of peroxide initiated grafting of polyethylene to silane treated glass surfaces has been studied. FT-IR has been used to study the reactions in a model system of hexadecane and silane treated Aerosil. DSC has been used to determine the melting point and the amount of grafted polyethylene to a silane treated glass surface. A series of glass fiber reinforced polyethylene composites has been characterized by mechanical testing and rheology testing. The fracture surfaces of the composites have also been examined by scanning electron microscopy.

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References

  1. E.P. Plueddemann, Silane Coupling Agents, Plenum Press, New York 1982.

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  2. W.C. Endestra, Crosslinking of Polymers by Peroxides, Akzo Research Centre, Düren 1981.

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  3. L.D. Tryson and J.L. Kardos, 36th Annual Conference, Reinforced Plastics/Composites Institute, The Society of the Plastics Industry, Feb 16–20, 1981, Session 2-E.

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  4. L.J. Bellamy, The Infra-red Spectra of Complex Molecules, pp 14, Chapman and Hall, London 1975.

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  5. M.J. Folkes, Short Fibre Reinforced Thermoplastics,John Wiley and Sons, pp 24–27, 1982.

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© 1990 Elsevier Science Publishing Co., Inc.

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Stori, A., Dahl, I.M. (1990). Grafting of Polyolefins to Silane Treated Surfaces by Free-Radical Reactions. In: Ishida, H. (eds) Controlled Interphases in Composite Materials. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-7816-7_31

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  • DOI: https://doi.org/10.1007/978-94-011-7816-7_31

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-011-7818-1

  • Online ISBN: 978-94-011-7816-7

  • eBook Packages: Springer Book Archive

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