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Controlled Interphases in Composite Materials pp 295–305Cite as

Use of Flow Microcalorimetry to Study the Adsorption of 3-(Trimethoxysilyl)Propyl Methacrylate onto Alumina Trihydrate under Near Anhydrous Conditions

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Abstract

A flow microcalorimeter has been used in series with two HPLC detectors to investigate the adsorption of 3-(trimethoxysilyl)propyl methacrylate onto alumina trihydrate under near anhydrous conditions. The thermal response measured by the flow microcalorimeter was unusually complex. This has been explored by investigating the effects of silane solution concentration, temperature, and pre-drying of the ATH, on the thermal and HPLC detector responses. It has been proposed that the adsorption progresses by a sequence of steps; hydrolysis of the silane; adsorption of the silanol; adsorption of methanol with desorption of silanol; desorption of water; desorption of methanol.

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Author information

Authors and Affiliations

  1. ICI Chemicals and Polymers Ltd., PO Box 8, The Heath, Runcorn, Cheshire, WA7 4QD, UK

    David P. Ashton & Roger N. Rothon

Authors
  1. David P. Ashton
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  2. Roger N. Rothon
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Editor information

Editors and Affiliations

  1. Department of Macromolecular Science, Case Western Reserve University, Cleveland, Ohio, USA

    Hatsuo Ishida Ph.D.

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© 1990 Elsevier Science Publishing Co., Inc.

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Ashton, D.P., Rothon, R.N. (1990). Use of Flow Microcalorimetry to Study the Adsorption of 3-(Trimethoxysilyl)Propyl Methacrylate onto Alumina Trihydrate under Near Anhydrous Conditions. In: Ishida, H. (eds) Controlled Interphases in Composite Materials. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-7816-7_29

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  • DOI: https://doi.org/10.1007/978-94-011-7816-7_29

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-011-7818-1

  • Online ISBN: 978-94-011-7816-7

  • eBook Packages: Springer Book Archive

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