Skip to main content
  • 1376 Accesses

Abstract

The word “rubber” immediately brings to mind materials that are highly flexible and will snap back to their original shape after being stretched. In this chapter a variety of materials are discussed that possess the characteristics describing this class of materials. Originally rubber meant the gum collected from a tree growing in Brazil. The term “rubber” was coined for this material by the English chemist Joseph Priestley, who noted that it was effective for removing pencil marks from paper. Today, in addition to Priestley’s natural product, many synthetic materials are made that possess these characteristics and many other properties. The common features of these materials are that they are made up of long polymer chains that are amorphous (not crystalline), they have a high degree of flexibility such that they do not stiffen until temperatures well below ambient are reached, and the chains can form a three-dimensional network in some manner.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 74.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Whitley, G. S., Davis, C. C., and Dunbrook, R. F. (Eds.), Synthetic Rubber, John Wiley & Sons, New York, 1954.

    Google Scholar 

  2. Blackely, D. C., Synthetic Rubber: Their Chemistry and Technology, Chapter 2, Applied Science Publishers, London, 1983.

    Book  Google Scholar 

  3. Worldwide Rubber Statistics 1990, International Inst, of Synthetic Rubber Producers, Inc., Houston, p. 6.

    Google Scholar 

  4. Fox, T. G., Grateh, S., and Loshaek, S., RheologyTheory and Applications, Vol. 1, Academic Press, New York, 1956.

    Google Scholar 

  5. Billmeyer, F. W., Jr., Textbook of Polymer Science, John Wiley & Sons, New York, 1984.

    Google Scholar 

  6. Odian, G., Principles of Polymerization, pp. 19–24, McGraw-Hill, New York, 1970.

    Google Scholar 

  7. Flory, P. J., Principles of Polymer Chemistry, Chapter 7, Cornell University Press, Ithaca, NY, 1953.

    Google Scholar 

  8. Rodriguez, F., Principles of Polymer Systems, pp. 138–142, McGraw-Hill, New York, 1982.

    Google Scholar 

  9. Rudin, A., The Elements of Polymer Science and Engineering, p. 126, Academic Press, New York, 1982.

    Google Scholar 

  10. Rudin, A., The Elements of Polymer Science and Engineering, Academic Press, New York, 1982. p. 402.

    Google Scholar 

  11. Krause, S., J. Macromol Sci., C7 (2), 251 (1972).

    Google Scholar 

  12. Morton, M., and Fetters, L. J., in Polymerization Processes, C. Schildknecht and I. Skeist, (Eds.), Chapter 9, John Wiley & Sons, New York, 1977.

    Google Scholar 

  13. Brandrup, J., and Immergut, E., Polymer Handbook, Vol. II, pp. 105–387, John Wiley & Sons, New York, 1975.

    Google Scholar 

  14. Flory, P. J., Principles of Polymer Chemistry, Chapter 7, Cornell University Press, Ithaca, NY, 1953, pp. 178–195.

    Google Scholar 

  15. Biesenberger, J. A., and Sebastian, D. H., Principles of Polymerization Engineering, Chapters 1 and 2, John Wiley & Sons, New York, 1983.

    Google Scholar 

  16. Flory, P. J., Principles of Polymer Chemistry, Cornell University Press, Ithaca, NY, 1953, Chapter 11.

    Google Scholar 

  17. Oberster, A. E., Bouton, T. C., and Valaitis, J. K., Die Angewandte Markomoleculare Chemie, 29/30, 91 (1973).

    Google Scholar 

  18. Florey, P. J., J. Chem. Phys., 17, 223 (1949).

    Article  Google Scholar 

  19. Natta, G., in Polymer Chemistry of Synthetic Elastomers, Part I, J. Kennedy and E. Tornqvist (Eds.), Chapter 7, John Wiley & Sons, New York, 1969.

    Google Scholar 

  20. Evans, C., Practical Rubber Compounding and Processing, Applied Science Rubbers, Englewood, NJ, 1981.

    Google Scholar 

  21. Semegen, S. T., and Cheong, S. F., Vanderbilt Rubber Handbook, pp. 18–41, R. T. Vanderbilt Company, Inc., 1978.

    Google Scholar 

  22. Morton, M., Rubber Technology, Van Nostrand Reinhold Co., New York, 1973.

    Google Scholar 

  23. Webster, C. C., and Baulkwill, W. J., Chapters 1 and 11, Rubber, John Wiley & Sons, New York, 1989.

    Google Scholar 

  24. Brandrup, J., and Immergut, E., Polymer Handbook, John Wiley & Sons, New York, 1975, Vol. III, p. 54.

    Google Scholar 

  25. Treloar, L., The Physics of Rubber Elasticity, Clarendon Press, Oxford, 1949.

    Google Scholar 

  26. Poh, W. N, Elastomers, p. 12 (1989).

    Google Scholar 

  27. Synthetic Rubber: The Story of an Industry, International Inst, of Synthetic Rubber Producers, New York, 1973.

    Google Scholar 

  28. Stavely, F. W., Ind. Eng. Chem., 48, 778 (1956), presented at Div. Rubber Chem., ACS, Philadelphia, PA, 1955.

    Article  Google Scholar 

  29. Eng. Patent 827365, to Goodrich-Gulf Chem., Dec. 1954, priority data.

    Google Scholar 

  30. Ref. 3, pp. 62–63.

    Google Scholar 

  31. Ref. 3, p. 77.

    Google Scholar 

  32. Ref. 3, p. 19.

    Google Scholar 

  33. Renninger, T. J., presentation to International Rubber Study Group, Ottawa, Sept. 1990.

    Google Scholar 

  34. Faith, W. L., et al., Industrial Chemicals, p. 731, John Wiley & Sons, New York, 1957.

    Google Scholar 

  35. Semegen, S. T., and Cheong, S. F., Vanderbilt Rubber Handbook, R. T. Vanderbilt Company, Inc., 1978, p. 53.

    Google Scholar 

  36. Dunbrook, R. F., India Rubber World, 117, 203–207 (1947).

    Google Scholar 

  37. Gardon, J. L., Rubber Chemistry and Technology, 43, 74–94 (1970).

    Article  Google Scholar 

  38. Storey, E. B., Rubber Chemistry and Technology, 34, 1402 (1961).

    Article  Google Scholar 

  39. Kuntz, I., J. Poly. Sci., 54, 569 (1969).

    Article  Google Scholar 

  40. Bouton, T., and Futamura, S., Rubber Age, 3, p. 33 (1974).

    Google Scholar 

  41. Mostert, S., and Van Amergongen, G., British Patent 1,136,189, 1968.

    Google Scholar 

  42. Natta, G., in Polymer Chemistry of Synthetic Elastomers, Part I, J. Kennedy and E. Tornqvist (Eds.), John Wiley & Sons, New York, 1969, Chapter 6.

    Google Scholar 

  43. Day, G., and Moore, D., paper at 26th Annual Meeting, IISRP, May 1985.

    Google Scholar 

  44. Oshima, N., Salcacobore, M., and Tsutsumi, F., paper at 27th Annual Meeting, IISRP, May 1986.

    Google Scholar 

  45. Ref. 3, p. 9.

    Google Scholar 

  46. Ponder, T., Hydrocarbon Processing, 55 (10), 119–121 (1976).

    Google Scholar 

  47. Womeldorph, D., Am. Petrol. Inst. (May 14, 1958).

    Google Scholar 

  48. Welch, M., Hydrocarbon Processing, 57 (11), 131–136 (1978).

    Google Scholar 

  49. Adams, H., Farhat, K., and Johnson, B., Ind. Eng. Chem., Prod. Res. Dev., 5 (2), 127 (1966).

    Article  Google Scholar 

  50. Halasa, A., Schulz, D., Tate, D., and Mochel, V., in Advances in Organometallic Chemistry, F. Stone and R. West (Eds.), Vol. 18, Academic Press, New York, 1980.

    Google Scholar 

  51. Tate, D., and Bethea, T., Encyclopedia of Polymer Science and Engineering, Vol. 2, pp. 568–72, John Wiley & Sons, New York, 1985.

    Google Scholar 

  52. Lauretti, F., and Gargani, L., 27th Annual Meeting, IISRP, June 1987.

    Google Scholar 

  53. DeChirico, A., Lamzani, P., Eaggi, E., and Bruzzone, M., Makromol. Che., 175, 2029 (1974).

    Article  Google Scholar 

  54. Buckeneil, C., “Toughened Plastics,” Applied Science, London (1977).

    Google Scholar 

  55. Natta, G., J. Poly. Sci., 51, 411 (1961).

    Article  Google Scholar 

  56. Lukach, C., and Spurlin, H., Copolymerization, G. Ham (Ed.), Interscience, New York, 1964.

    Google Scholar 

  57. Crespi, G., and DiDrusco, G., Hydrocarbon Processing, 48, 103–107 (Feb. 1969).

    Google Scholar 

  58. Vandenberg, E., and Repka, B., in Polymerization Processes, C. Schildknecht and I. Skeist, (Eds.), John Wiley & Sons, New York, 1977, Chapter 11.

    Google Scholar 

  59. Scagliotti, F., Milani, F., and Galli, P., paper at 26th Annual Meeting, IISRP, May 1985.

    Google Scholar 

  60. Miles, D., and Briston, J., Polymer Technology, p. 299, Chemical Publishing Company, New York, 1963.

    Google Scholar 

  61. Kennedy, J., in Polymer Chemistry of Synthetic Elastomers, Part I, J. Kennedy and I. Tornqvist (Eds.), Chapter 5, John Wiley & Sons, New York, 1969.

    Google Scholar 

  62. “Butyl Rubber Reaches 50 Year Mark,” Elastomerics, pp. 30–31 (Mar. 1988).

    Google Scholar 

  63. Konrad, E., and Tschunkur, E., U.S. Patent 1,973,000 to I. G. Farbenindustrie, 1934.

    Google Scholar 

  64. Ref. 3, p. 9.

    Google Scholar 

  65. McKenzie, G., paper at 27th Annual Meeting, IISRP, May 1986.

    Google Scholar 

  66. Hashimoto, K., et al., paper at 26th Annual Meeting, IISRP, May 1985.

    Google Scholar 

  67. Whitley, G. S., Davis, C. C., and Dunbrook, R. F. (Eds.), Synthetic Rubber, John Wiley & Sons, New York, 1954, p. 770.

    Google Scholar 

  68. Hofmann, W., Polymer Technology, p. 299, Chemical Publishing Company, New York, 1963, Chapter 4.

    Google Scholar 

  69. Blackely, D. C., Synthetic Rubber: Their Chemistry and Technology, Chapter 2, Applied Science Publishers, London, 1983, pp. 175–194.

    Book  Google Scholar 

  70. Brodrecht, L., Chemical Economics Handbook, SRI International, 1989.

    Google Scholar 

  71. Polmateer, K., Rubber Chemistry and Technology, 16 (3), 470 (1988).

    Article  Google Scholar 

  72. Noble, M., Vanderbilt Rubber Handbook, R. T. Vanderbilt Company, Inc., 1978, pp. 216–232.

    Google Scholar 

  73. Saunders, J., in Polymer Chemistry of Synthetic Elastomers, Part I, J. Kennedy and E. Tornqvist (Eds.), John Wiley & Sons, New York, 1969, Chapter 8.

    Google Scholar 

  74. Bakus, J., in Polymerization Processes, C. Schildknecht and I. Skeist, (Eds.), John Wiley & Sons, New York, 1977, Chapter 17.

    Google Scholar 

  75. Handbook of Elastomers, pp. 643–659, Marcel Dekker, Inc., New York, 1988.

    Google Scholar 

  76. Penn, W., PVC Technology, Applied Science Publishers, London, 1971.

    Google Scholar 

  77. Blackely, D. C., Synthetic Rubber: Their Chemistry and Technology, Applied Science Publishers, London, 1983, Chapter 8.

    Book  Google Scholar 

  78. Broadrecht, L., Mulach, R., and Tauchiya, K., in Chemical Economics Handbook, Elastomers, SRI International, Menlo Park, CA, 1989.

    Google Scholar 

  79. Johnson, J., Vanderbilt Rubber Handbook, R. T. Vanderbilt Company, Inc., 1978, pp. 295–307.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

James A. Kent Ph.D.

Rights and permissions

Reprints and permissions

Copyright information

© 1992 Van Nostrand Reinhold

About this chapter

Cite this chapter

Bouton, T.C. (1992). Rubber. In: Kent, J.A. (eds) Riegel’s Handbook of Industrial Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-7691-0_18

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-7691-0_18

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-011-7693-4

  • Online ISBN: 978-94-011-7691-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics