Skip to main content

Atomic Absorption and Plasma Atomic Emission Spectrometry

  • Chapter
Book cover Modern Methods of Food Analysis

Part of the book series: ift Basic Symposium Series ((IFTBSS))

Abstract

Observations in the mid-eighteenth and early nineteenth centuries by Melvill (1756), Herschel (1823), and Talbot (1826) regarding colors imparted to flames by salts and other materials, studies of the solar spectrum by Wollaston (1802) and Fraunhofer (1817), and studies of spark- and arc-excited spectra by Wheatstone in 1835 and Foucault in 1848, respectively (Schrenk 1975), were the early beginnings of atomic emission and absorption. It is, however, the investigations on emission in about 1860 by Kirchhoff and Bunsen (1860, 1861) that are generally regarded as the foundations of analytical spectrometry. Modern analytical flame emission spectrometry dates to the work reported by Lundegårdh (1934) on the determination of a number of metallic elements in biological samples using air-acetylene flame excitation, a prism spectrograph, and photographic recording. It is considered that quantitative (arc/spark) atomic emission spectrochemical analysis originated about 1882 with Hartley using a spark excitation source. Arc and spark emission spectrometry was the method of choice for simultaneous multielement determinations during the three decades (1930–1960) in many fields of analysis notably in metallurgy and geology. Flame emission spectrometry gained rapidly in popularity following the Introduction of commercial instruments in 1937–1945.

Contribution No. M-1397 from the Chemistry and Biology Research Institute

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Bibliography

  • ALKEMADE, C.T.J., and MILATZ, J.M.W. 1955. Double-beam method of spectral selection with flames. J. Opt. Soc. Am. 45, 583–584.

    Article  Google Scholar 

  • ALLEN, S.E., GRIMSHAW, H.M., PARKINSON, J.A., and QUARMBY, C. 1974. Chemical Analysis of Ecological Materials. Blackwell Scientific Publications, Oxford, UK.

    Google Scholar 

  • APPROVED METHODS COMMITTEE, W.C. Schaefer (Chairman), 1976. Approved Methods of the American Association of Cereal Chemists. Am. Assoc. of Cereal Chemists Inc., St. Paul, MN.

    Google Scholar 

  • BOCK, R. 1979. A Handbook of Decomposition Methods in Analytical Chemistry. John Wiley, New York. (English translation by I.L. Marr of 1972 German edition).

    Google Scholar 

  • BOUMANS, P.W.J.M. 1980. Line Coincidence Tables for Inductively Coupled Plasma Atomic Emission Spectrometry. Vols. I and II. Pergamon Press, Toronto, Ont.

    Google Scholar 

  • BOUMANS, P.W.J.M., and BOSVELD, M. 1979. A tentative listing of the sensitivities and detection limits of the most sensitive ICP lines as derived from the fitting of experimental data for an argon ICP to the intensities tabulated for the NBS copper arc. Spectrochim. Acta 34B, 59–72.

    CAS  Google Scholar 

  • BOUMANS, P.W.J.M., and de BOER, F.J. 1972. Studies of flame and plasma torch emission for simultaneous multi-element analysis — I. Preliminary investigations. Spectrochim. Acta 27B, 391–414.

    Google Scholar 

  • CANTLE, J.E. (Editor). 1982. Atomic Absorption Spectrometry. Elsevier Scientific Publishing Co., Amsterdam, Netherlands.

    Google Scholar 

  • CHRISTIAN, G.D., and FELDMAN, F.J. 1970. Atomic Absorption Spectroscopy-Applications in Agriculture, Biology and Medicine. Wiley (Interscience), New York.

    Google Scholar 

  • COMMUNITY BUREAU OF REFERENCE. 1982. Catalogue of BCR Reference Materials, Brussels.

    Google Scholar 

  • CROSBY, N.T. 1977. Determination of metals in foods. A review. Analyst 102, 225–268.

    CAS  Google Scholar 

  • DABEKA, R.W. 1979. Graphite furnace atomic absorption spectrometric determination of lead and cadmium in foods after solvent extraction and stripping. Anal. Chem. 51, 902–907.

    Article  CAS  Google Scholar 

  • DEAN, J.A., and RAINS, T.C. (Editors). Flame Emission and Atomic Absorption Spectrometry. 1969. Vol. 1, Theory; 1971. Vol. 2, Components and Techniques; 1975. Vol. 3, Elements and Matrices. Marcel Dekker, New York.

    Google Scholar 

  • DICKINSON, G.W., and FASSEL, V.A. 1969. Emission spectrometric detection of the elements at the nanogram per milliliter level using induction-coupled plasma excitation. Anal. Chem. 41, 1021–1024.

    Article  CAS  Google Scholar 

  • DOUGLAS, D. 1983. ICP/MS Technologies marry to produce better analysis. Can. Res. April (1983) 55-60.

    Google Scholar 

  • DUNLOP, E.C. 1961. Decomposition and dissolution of samples: organic. In Treatise on Analytical Chemistry Part I, Vol. 2, Chapter 25. I.M. Kolthoff and P.J. Elving (Editors). Wiley (Interscience), New York.

    Google Scholar 

  • DVOřAK, J., RUBEšKA, I., and Rezač, Z. Flame Photometry — Laboratory Practice (English translation edited by R.E. Hester). CRC Press, Chem. Rubber Co., Cleveland, OH.

    Google Scholar 

  • ELWELL, W.T., and GIDLEY, J.A.F. 1966. Atomic Absorption Spectrophotometry, 2nd Rev. ed. Pergamon Press, Oxford, UK.

    Google Scholar 

  • FASSEL, V.A. 1979. Simultaneous or sequential determination of the elements at all concentration levels — the renaissance of an old approach. Anal. Chem. 51, 1290A–1308A.

    Article  CAS  Google Scholar 

  • FRAUNHOFER, J. 1817. Determination of refractive and dispersive power of various glasses in relation to the production of achromatic telescopes. Ann. Physik (Gilbert’s Ann.) 26, 264–313 (German).

    Article  Google Scholar 

  • FULLER, C.W. 1977. Electrothermal Atomization for Atomic Absorption Spectrometry. The Chemical Society, London, UK.

    Google Scholar 

  • GILBERT, P.T. JR. 1959. Analytical flame photometry: new developments. In Symposium on Spectroscopy, ASTM STP No. 269, pp. 73-156. Am. Soc. Testing Mats., Philadelphia, PA.

    Google Scholar 

  • GORSUCH, T.T. 1970. The Destruction of Organic Matter. Pergamon, Toronto, Ont.

    Google Scholar 

  • GREENFIELD, S., JONES, I. L.L., and BERRY, C.T. 1964. High-pressure plasmas as spectroscopic emission sources. Analyst 89, 713–720.

    Article  CAS  Google Scholar 

  • HANSON, N.W. (Editor). 1973. Official, Standardized and Recommended Methods of Analysis, 2nd ed. The Society for Analytical Chemistry, London, UK.

    Google Scholar 

  • HARNLY, J.M., O’HAVER, T.C., GOLDEN, B., and WOLF, W.R. 1979. Background-corrected simultaneous multielement atomic absorption spectrometer. Anal. Chem. 51, 2007–2014.

    Article  CAS  Google Scholar 

  • HART, F.L., and FISHER, H.J. 1971. Modern Food Analysis. Springer-Verlag, New York.

    Book  Google Scholar 

  • HERSCHEL, J.F.W. 1823. On the absorption of light by coloured media, and on the colours of the prismatic spectrum exhibited by certain flames; with an account of a ready mode of determining the absolute dispersive power of any medium, by direct experiment. Trans. Roy. Soc (Edinburgh) 9, 445-460.

    Google Scholar 

  • HORWITZ, W. (Editor). 1980. Official Methods of Analysis of the Association of Offical Analytical Chemists, 13th ed. Association of Official Analytical Chemists, Washington, DC.

    Google Scholar 

  • IHNAT, M. 1976. Selenium in foods: evaluation of atomic absorption spectrometric techniques involving hydrogen selenide generation and carbon furnace atomization. J. Assoc. Offic. Anal. Chem. 59, 911–922.

    CAS  Google Scholar 

  • IHNAT, M. 1982. Application of atomic absorption spectrometry to the analysis of foodstuffs. In Atomic Absorption Spectrometry, Chapter 4d, pp. 139–220.

    Google Scholar 

  • J.E. CANTIE (Editor). Elsevier Scientific Publishing Co., Amsterdam, Netherlands.

    Google Scholar 

  • IHNAT, M., and MILLER, H.J. 1977. Analysis of foods for arsenic and selenium by acid digestion, hydride evolution atomic absorption spectrophotometry. J. Assoc. Offic. Anal. Chem. 60, 813–825.

    CAS  Google Scholar 

  • IHNAT, M., CLOUTIER, R.A., and WOLF, W.R. 1982. Preparation of a corn agricultural biological reference material. Abstracts 9th Annu. Meet. of the Fed. of Anal. Chem. and Spectroscopy Societies, Philadelphia, PA, Sept. 19–24, 1982. Abstract No. 459.

    Google Scholar 

  • THE INSTITUTE OF BREWING ANALYSIS COMMITTEE, P.A. Martin (Chairman). 1973. Determination of iron and copper in beer by atomic absorption spectroscopy. J. Inst. Brew. 79, 289-293.

    Google Scholar 

  • THE INSTITUTE OF BREWING ANALYSIS COMMITTEE, J. Weiner (Chairman). 1974. Determination of zinc in beer by atomic absorption spectroscopy. J. Inst. Brew. 80, 486-488.

    Google Scholar 

  • THE INSTITUTE OF BREWING ANALYSIS COMMITTEE, J. Weiner (Chairman). 1977. Determination of lead in beer by atomic absorption spectroscopy. J. Inst. Brew. 83, 82-84.

    Google Scholar 

  • JOSLYN, M.A. (Editor). 1970. Methods in Food Analysis, Physical, Chemical and Instrumental Methods of Analysis. 2nd ed. Academic Press, New York.

    Google Scholar 

  • KEIRS, C.D., and VICKERS, T.J. 1977. DC plasma arcs for elemental analysis. Appl. Spect. 31, 273–283.

    Article  CAS  Google Scholar 

  • KIRCHHOFF, G., and BUNSEN, R. 1860. Chemical analysis by spectrum observations. Phil. Mag. 20, 89–109.

    Google Scholar 

  • KIRCHHOFF, G., and BUNSEN, R. 1861. Chemical analysis founded on observations of spectra. Ann. Chim. Phys. 62, 452–486 (French).

    Google Scholar 

  • KIRKBRIGHT, G.F., and SARGENT, M. 1974. Atomic Absorption and Fluorescence Spectroscopy. Academic Press, New York.

    Google Scholar 

  • KOIRTYOHANN, S.R., and PICKETT, E.E. 1975. Agronomic applications (Chapter 15) and food analysis (Chapter 17). In Flame Emission and Atomic Absorption Spectrometry, Vol. 3, Elements and Matrices. J.A. Dean and T.C. Rains (Editors). Marcel Dekker, New York.

    Google Scholar 

  • LEES, R. 1975. Food Analysis: Analytical and Quality Control Methods for the Food Manufacturer and Buyer. 3rd ed. Leonard Hill Books, London, UK.

    Google Scholar 

  • LINK, W.E. (Editor). 1977. Official and Tentative Methods of the American Oil Chemists’ Society, 3rd ed. Am. Oil Chemists’ Society, Champaign, IL.

    Google Scholar 

  • LOVETT, R.J., WELCH, D.L., and PARSONS, M.L. 1975. On the importance of spectral interferences in atomic absorption spectroscopy. Appl. Spect. 29, 470–477.

    Article  CAS  Google Scholar 

  • LUNDEGåRDH, H. 1934. The Quantitative Spectral Analysis of the Elements, II. Gustav Fischer, Jena.

    Google Scholar 

  • MACLEOD, A.J. 1973. Instrumental Methods of Food Analysis. Elek Science, London, UK.

    Google Scholar 

  • MARGOSHES, M., and SCRIBNER, B.F. 1959. The plasma jet as a spectroscopic source. Spectrochim. Acta 15, 138–145.

    Article  Google Scholar 

  • MASSMANN, H. 1967. Determination of arsenic by atomic absorption. Fres. Zeit. Analyt. Chem. 225, 203–213 (German).

    Article  CAS  Google Scholar 

  • MASSMANN, H. 1968. Comparison of atomic absorption and atomic fluorescence in a graphite cuvette. Spectrochim. Acta 23B, 215–226 (German).

    Google Scholar 

  • MAVRODINEANU, R. (Editor). 1970. Analytical Flame Spectroscopy-Selected Topics. Springer-Verlag, New York.

    Google Scholar 

  • MCQUAKER, N.R., KLUCKNER, P.D., and CHANG, G.N. 1979. Calibration of an inductively coupled plasma-atomic emission spectrometer for the analysis of environmental materials. Anal. Chem. 51, 888–895.

    Article  CAS  Google Scholar 

  • MEGGERS, W.F., CORLISS, C.H., and SCRIBNER, B.F. 1975. Tables of Spectral Line Intensities, Part I — Arranged by Elements, Part II — Arranged by Wavelength. NBS Monograph 145, 2nd ed. National Bureau of Standards, Washington, DC.

    Google Scholar 

  • MELVILL, T. 1756. Observations on light and colours. Essays and Observations, Physical and Literary, Edinburgh 2, 12–90. (From J.A. Dean and T.C. Rains 1969.)

    Google Scholar 

  • MERCURY ANALYSIS WORKING PARTY OF THE BUREAU INTERNATIONAL TECHNIQUE DU CHLORE. 1976. Standardization of methods for the determination of traces of mercury. Part I. Determination of total mercury in materials containing organic matter. Anal. Chim. Acta 84, 231–257.

    Article  Google Scholar 

  • MILLER, J.D., and KOIZUMI, H. 1978. Analytical applications of polarized Zeeman AA. Am. Lab. Nov. (1978) 35–51.

    Google Scholar 

  • MINISTRY OF AGRICULTURE, FISHERIES AND FOOD. 1973. Technical Bull. 27. The Analysis of Agricultural Materials, A Manual of the Analytical Methods Used by the Agricultural Development and Advisory Service. Her Majesty’s Stationery Office, London, UK.

    Google Scholar 

  • MORRE, J. 1974. Pollution of milk by metals. Determination by atomic absorption spectrophotometry. Lait 54, 139–152. (French). [Chem. Abstr. 81 (1974), 103299f.]

    Article  CAS  Google Scholar 

  • MUNTAU, H. 1979. Five years of environmental candidate reference material production at the Joint Research Centre Ispra. In Production and Use of Reference Materials, Proc. of the Int. Symp. held at the Bundesanstalt für Materialprufung (BAM) Nov. 13-16, 1979.

    Google Scholar 

  • PARR, R.M. 1980. The reliability of trace element analysis as revealed by analytical reference materials. In Trace Element Analytical Chemistry in Medicine and Biology. P. Bratter and P. Schramel (Editors). Walter de Gruyter and Co., Berlin.

    Google Scholar 

  • PARSONS, M.L., SMITH, B.W., and BENTLEY, G.E. 1975. Handbook of Flame Spectroscopy. Plenum Press, New York.

    Google Scholar 

  • PEARSON, D. 1976. The Chemical Analysis of Foods. 7th Edition. Churchill Livingstone, Edinburgh, UK.

    Google Scholar 

  • PINTA, M. (Editor). 1975. Atomic Absorption Spectrometry. (Translated by K.M. Greenland and F. Lawson). Halstead Press, New York.

    Google Scholar 

  • POMERANZ, Y., and MELOAN, C.E. 1978. Food Analysis: Theory and Practice. Rev. ed. Avi Publishing Co. Inc., Westport, CT.

    Google Scholar 

  • PRICE, W.J. 1974. Analytical Atomic Absorption Spectrometry. Heyden and Son Ltd. London, UK.

    Google Scholar 

  • PRICE, W.J. 1979. Spectrochemical Analysis by Atomic Absorption. Heyden and Son Ltd. London, UK.

    Google Scholar 

  • RAMIREZ-MUNOZ, J. 1968. Atomic Absorption Spectroscopy and Analysis by Atomic Absorption Flame Photometry. Elsevier Scientific Publishing Co., Amsterdam, Netherlands.

    Google Scholar 

  • REYNOLDS, R.J. and Aldous, K. 1970. Atomic Absorption Spectroscopy — A Practical Guide. C. Griffin and Co., London, UK.

    Google Scholar 

  • ROBINSON, J.W. 1966. Atomic Absorption Spectroscopy. Marcel Dekker, New York.

    Google Scholar 

  • ROBINSON, J.W. (Editor). 1974. Handbook of Spectroscopy, Vol. I, Section D. CRC Press, Chem. Rubber Co., Cleveland, OH.

    Google Scholar 

  • RUBESKA, I., and MOLDAN, B. 1969. Atomic Absorption Spectrophotometry. Iliffe Books Ltd., London, UK.

    Google Scholar 

  • SAARLOOS, C.C. 1972. Atomic absorption spectrometry. III. Atomic absorption spectrometry applied to the food industry. Chem. Tech. (Amsterdam) 27(8), 205–209 (Neth.). [Chem. Abst. 77 (1972), 60115r.]

    CAS  Google Scholar 

  • SAKAI, K. 1975. Determination of heavy metals in foods by atomic absorption spectroscopy. Shokuhin Kogyo 18, 71–78. (Japan). [Chem. Abstr. 83 (1975) 204864h.]

    CAS  Google Scholar 

  • SALIN, E.D., and INGLE, J.D., Jr. 1978. Design and construction of a time multiplex multiple slit multielement flame atomic absorption spectrometer. Anal. Chem. 50, 1737–1744.

    Article  CAS  Google Scholar 

  • SCHRENK, W.G. 1975. Analytical Atomic Spectroscopy, Plenum Press, New York.

    Google Scholar 

  • SCHULLER, P.L., and COLES, L.E. 1979. The determination of copper in foodstuffs (International Union of Pure and Applied Chemistry, Applied Chemistry Division, Commission on Food Contaminants). Pure and Appl. Chem. 51, 385–392.

    Article  Google Scholar 

  • SCHULLER, P.L., and EGAN, H. 1976. Cadmium, Lead, Mercury and Methylmercury Compounds, A Review of Methods of Trace Analysis and Sampling with Special Reference to Food. FAO, Rome, Italy.

    Google Scholar 

  • SCOTT, R.H., FASSEL, V.A., KNISELEY, R.N., and NIXON, D.E. 1974. Inductively coupled plasma-optical emission analytical spectrometry, a compact facility for trace analysis of solutions. Anal. Chem. 46, 75–80.

    Article  CAS  Google Scholar 

  • SEILER, H. 1972. Methods for determination of metal ions in foods. Mitt. Geb. Lebensmitt Hyg. 63, 180–187 (German). [Chem. Abstr. 78 (1973) 2787w.]

    CAS  Google Scholar 

  • SLAVIN, W. 1968. Atomic Absorption Spectroscopy. Wiley Interscience Publishers, New York.

    Google Scholar 

  • SIMMONS, W.J. 1973. Determination of low concentrations of cobalt in plant material by atomic absorption spectrophotometry. Anal. Chem. 45, 1947–1949.

    Article  CAS  Google Scholar 

  • SIMMONS, W.J. 1975. Determination of low concentrations of cobalt in small samples of plant material by flameless atomic absorption spectrophotometry. Anal. Chem. 47, 2015–2018.

    Article  CAS  Google Scholar 

  • SUBCOMMITTEE ON PROCEDURES OF THE CHEMISTRY TASK FORCE OF THE NATIONAL SHELLFISH SANITATION PROGRAM. 1975. Collection, Preparation and Analysis of Trace Metals in Shellfish, Publ. No. (FDA) 76–2006, USDHEW, PHS, FDA.

    Google Scholar 

  • TALBOT, H.F. 1826. Some experiments on coloured flames. Edinburgh J. Sci. (Brewster’s) 5, 77–81.

    Google Scholar 

  • TEPER, I. 1977. Use of atomic absorption spectrophotometry in the feed industry. Krmivarstvi Sluzby 13(3), 63 (Czech.). [Chem. Abstr. 87 (1977) 100691r.]

    CAS  Google Scholar 

  • Van LOON, J.C. 1981. Review of methods for elemental speciation using atomic spectrometry detectors for chromatography. Can. J. Spect. 26, 22A–32A.

    Google Scholar 

  • VARIAN TECHTRON. 1972A. Hollow Cathode Lamp Data. Varian Techtron, Springvale, Australia.

    Google Scholar 

  • VARIAN TECHTRON. 1972B. Analytical Methods for Flame Spectroscopy. Varian Techtron, Springvale, Australia.

    Google Scholar 

  • VARJU, M. 1971. Atomic absorption spectrophotometry and its application in investigations in food chemistry. Elelmiszervizsgalati kozlemenyek 17 (1–2), 64–71 (Hung). [Chem. Abstr. 76 (1972) 71059f.]

    CAS  Google Scholar 

  • WALSH, A. 1955. The application of atomic absorption spectra to chemical analysis. Spectrochim. Acta 7, 108–117.

    Article  CAS  Google Scholar 

  • WENDT, R.H. and FASSEL, V.A. 1965. Induction-coupled plasma spectrometric excitation source. Anal. Chem. 37, 920–922.

    Article  CAS  Google Scholar 

  • WELZ, B. 1976. Atomic Absorption Spectroscopy. Verlag Chemie, New York.

    Google Scholar 

  • WINGE, R.K., PETERSON, V.J. and FASSEL, V.A. 1979. Inductively coupled plasmaatomic emission spectroscopy: prominent lines. Appl. Spect. 33, 206–219.

    Article  CAS  Google Scholar 

  • WOLF, W.R. and IHNAT, M. 1982. Evaluation of available reference materials for potential use in analysis of biological materials. Abstr. 9th Annu. Meet. of the Fed. of Anal. Chem. and Spectroscopy Societies, Phil. PA, Sept. 19-24, 1982. Abstract No. 108.

    Google Scholar 

  • WOLLASTON, W.H. 1802. A method of examining refractive and dispersive powers by prismatic reflection. Phil. Trans. 92, 365–380.

    Article  Google Scholar 

  • WOODRIFF, R. and RAMELOW, G. 1968. Atomic absorption spectroscopy with a high temperature furnace. Spectrochim. Acta 23B, 665–671.

    Google Scholar 

  • WOODRIFF, R., STONE, R.W., and HELD, A.M. 1968. Electrothermal atomization for atomic absorption analysis. Appl. Spect. 22, 408–411.

    Article  CAS  Google Scholar 

  • WOODSON, T.T. 1939. A new mercury vapor detector. Rev. Sci. Instr. 10, 308–311.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1984 The AVI Publishing Company, Inc.

About this chapter

Cite this chapter

Ihnat, M. (1984). Atomic Absorption and Plasma Atomic Emission Spectrometry. In: Stewart, K.K., Whitaker, J.R. (eds) Modern Methods of Food Analysis. ift Basic Symposium Series. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-7379-7_7

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-7379-7_7

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-011-7381-0

  • Online ISBN: 978-94-011-7379-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics