Abstract
Aromatic polycarbonates were first disclosed by A. Einhorn in 1898. He reacted pyridine solutions of hydroquinone, resorcinol and catechol with phosgene to produce respectively (1) an insoluble and intractible hydroquinone polycarbonate, (2) a glassy resorcinol polycarbonate melting at about 200°C and (3) a simple cyclic catechol carbonate. Four years later C. Bischoff and A. von Hedenstrom produced and reported the same products employing transesterification. And then the subject of aromatic polycarbonates was apparently forgotten.
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References
A. Einhorn, Liebig’s Ann. Chem. 300, 135 (1898).
C. Bischoff and a. von Hedenstrom, Ber. 35, 3431 (1902).
H. Schnell, Ang. Chem. 68, 633 (1956).
D. Fox and W. Christopher, “Polycarbonates”, Reinhold Publishing Corp., New York, 1962, p. 31.
H. Schnell, “Chemistry and Physics of Polycarbonates”, Wiley-Interscience, New York, 1964, pp. 44–51.
D. Fox in Encyclopedia of Chemical Technology, Volume 18, Third Ed., 1982, John Wiley & Sons, Inc., p. 479–494.
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© 1986 Elsevier Science Publishing Co., Inc.
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Fox, D.W. (1986). History. In: Seymour, R.B., Kirshenbaum, G.S. (eds) High Performance Polymers: Their Origin and Development. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-7073-4_6
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DOI: https://doi.org/10.1007/978-94-011-7073-4_6
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